Skip to main content
SpringerLink
Log in

Molecular and crystal structures of 3-methyl-3-[1,7-dicarba-closo-dodecaborane(12)-1-oyl-peroxy]-but-1-yne

  • Structure of Organic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The crystal and molecular structures of 3-methyl-3-[1,7-dicarba-closo-dodecaborane(12)-1-oylperoxy]-but-1-yne (I) are determined by X-ray diffraction analysis (Nicolet R3m automated diffractometer, MoK α radiation, θ/2θ scan mode). It is found that the compound crystallizes in the orthorhombic crystal system, space group P212121. The unit cell parameters are as follows: a = 7.355(2) Å, b = 9.773(3) Å, c = 21.938(7) Å, and Z = 4. The structure is solved by the direct method and refined to R = 0.0658. The structural features of the molecule and the C-H⋯O contacts in the structure are discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Yu. A. Ol’dekop, S. F. Naumova, L. A. Churkina, et al., USSR Inventor’s Certificate No. 681068 (1977), Byull. Izobret., No. 31 (1979).

  2. L. A. Churkina, S. F. Naumova, T. D. Zvereva, et al., Vestsi Akad. Navuk BSSR, Ser. Khim. Navuk, No. 3, 125 (1981).

  3. L. A. Churkina, S. F. Naumova, T. D. Zvereva, et al., Vestsi Akad. Navuk BSSR, Ser. Khim. Navuk, No. 3, 108 (1982).

  4. A. P. Yuvchenko, A. Ya. Markina, N. R. Prokopchuk, et al., Zh. Prikl. Khim. (St. Petersburg) 71(3), 472 (1998).

    Google Scholar 

  5. R. Grimes, Carboranes (Academic, New York, 1970; Mir, Moscow, 1974).

    Google Scholar 

  6. T. D. Zvereva, A. P. Yuvchenko, and N. A. Zhukovskaya, Zh. Obshch. Khim. 62(4), 855 (1992).

    Google Scholar 

  7. A. Altomare, M. C. Burla, M. Camalli, et al., J. Appl. Crystallogr. 32, 115 (1999).

    Google Scholar 

  8. G. M. Sheldrick, SHELX97: Program for the Solution and Refinement of Crystal Structures (Univ. of Göttingen, Göttingen, Germany, 1997).

    Google Scholar 

  9. L. J. Farrugia, J. Appl. Crystallogr. 30, 565 (1997).

    Article  Google Scholar 

  10. F. H. Allen and O. Kennard, Chem. Des. Autom. News 8(1), 31 (1993).

    Google Scholar 

  11. G. R. Desiraju and T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology (Oxford Univ. Press, Oxford, 1999).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Research Institute of Physicochemical Problems, Belarussian State University, Leningradskaya ul. 14, Minsk, 220080, Belarus

    A. S. Lyakhov, L. S. Ivashkevich, A. A. Govorova & Yu. I. Petrusevich

  2. Institute of Chemistry of New Materials, National Academy of Sciences of Belarus, ul. Kuprevicha 16, Minsk, 220141, Belarus

    A. P. Yuvchenko & T. D. Zvereva

Authors
  1. A. S. Lyakhov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. S. Ivashkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. P. Yuvchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. D. Zvereva
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. A. Govorova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yu. I. Petrusevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Kristallografiya, Vol. 46, No. 6, 2001, pp. 1054–1056.

Original Russian Text Copyright © 2001 by Lyakhov, Ivashkevich, Yuvchenko, Zvereva, Govorova, Petrusevich.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Lyakhov, A.S., Ivashkevich, L.S., Yuvchenko, A.P. et al. Molecular and crystal structures of 3-methyl-3-[1,7-dicarba-closo-dodecaborane(12)-1-oyl-peroxy]-but-1-yne. Crystallogr. Rep. 46, 971–973 (2001). https://doi.org/10.1134/1.1420829

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/1.1420829

Keywords

Search

Navigation