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Competition of concatenated and thermally activated medium reorganization in photoinduced electron transfer reactions

  • Photochemistry
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Abstract

Two mechanisms of photoinduced electron-transfer reactions, the classical mechanism of the preliminary thermally activated reorganization of a medium and reactants (at relatively weak electronic interaction between reactant molecules) and the mechanism of intermediate formation of exciplexes by concatenated medium reorganization correlated with charge displacement (at relatively strong electronic interaction between the reactants) are compared.

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Authors and Affiliations

  1. Moscow State University, Leninskie gory, Moscow, 119992, Russia

    M. G. Kuzmin, I. V. Soboleva & E. V. Dolotova

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  1. M. G. Kuzmin
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  2. I. V. Soboleva
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  3. E. V. Dolotova
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Original Russian Text © M.G. Kuzmin, I.V. Soboleva, E.V. Dolotova, 2006, published in Khimiya Vysokikh Energii, 2006, Vol. 40, No. 4, pp. 276–290.

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Kuzmin, M.G., Soboleva, I.V. & Dolotova, E.V. Competition of concatenated and thermally activated medium reorganization in photoinduced electron transfer reactions. High Energy Chem 40, 234–247 (2006). https://doi.org/10.1134/S0018143906040072

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  • DOI: https://doi.org/10.1134/S0018143906040072

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