Abstract
A new imidazolium-based poly(ionic liquid) has been synthesized and used as a robust heterogeneous catalyst for the preparation of phenacyl derivatives by an SN2 reaction of different phenacyl bromides with a broad range of nucleophiles. The products are obtained in high yields under mild conditions. The catalyst can be recycled efficiently.
Similar content being viewed by others
References
Eftekhari, A. and Saito, T., Eur. Polym. J., 2017, vol. 90, p. 245. doi https://doi.org/10.1016/j.eurpolymj.2017.03.033
Qian, W., Texter, J., Yan, F. Chem. Soc. Rev., 2017, vol. 46, p. 1124. doi https://doi.org/10.1039/C6CS00620E
Yuan, J., Mecerreyes, D., and Antonietti, M., Prog. Polym. Sci., 2013, vol. 38, p. 1009. doi https://doi.org/10.1016/j.progpolymsci.2013.04.002
Yuan, J. and Antonietti, M., Polymer, 2011, vol. 52, p. 1469. doi https://doi.org/10.1016/j.polymer.2011.01.043
Nellepalli, P., Tomé, L.C., Vijayakrishna, K., and Marrucho, I.M., Ind. Eng. Chem. Res., 2019, vol. 58, p. 2017. doi https://doi.org/10.1021/acs.iecr.8b05093
Azaroon, M. and Kiasat, A.R., Materials Science and Engineering: C, 2018, vol. 92, p. 356. doi https://doi.org/10.1016/j.msec.2018.07.009
Jiang, Q., Sheng, W., and Guo, C., Green Chem., 2013, vol. 15, p. 2175. doi https://doi.org/10.1039/C3GC40515J
Reddy, C.N., Sathish, M., Adhikary, S., Nanubolu, J.B., Alarifi, A., Maurya, R.A., ad Kamal, A., Org. Biomol. Chem., 2017, vol. 15, p. 2730. doi https://doi.org/10.1039/C7OB00299H
Gorjizadeh, M. and Sayyahi, S., Russ. J. Gen. Chem., 2018, vol. 88, p. 1899. doi https://doi.org/10.1134/S1070363218090220
Deilami, K. and Sayyahi, S., Russ. J. Gen. Chem., 2017, vol. 87, p. 1085. doi https://doi.org/10.1134/S1070363217050310
Saghanezhad, S.J. and Sayyahi, S., Res. Chem. Intermed., 2017, vol. 43, 2491. doi https://doi.org/10.1007/s11164-016-2775-5
Zhang, P., Qiao, Z.-A., Jiang, X., Veith, G.M., and Dai, S., Nano Lett., 2015, vol. 15, p. 823. doi https://doi.org/10.1021/nl504780j
Kakesh, N., Sayyahi, S., and Badri, R., C. R. Chim., 2018, vol. 21, p. 1023. doi https://doi.org/10.1016/j.crci.2018.09.009
Kiasat, A.R. and Sayyahi, S., Mol. Diversity, 2010, vol. 14, p. 155. doi https://doi.org/10.1007/s11030-009-9191-3
Sayyahi, S. and Saghanezhad, J., Chin. Chem. Lett., 2011, vol. 22, p. 300. doi https://doi.org/10.1016/j.cclet.2010.10.009
Amini, A., Sayyahi, S., Saghanezhad, S.J., and Taheri, N., Catal. Commun., 2016, vol. 78, p. 11. doi https://doi.org/10.1016/j.catcom.2016.01.036
Ayashi, N., Fallah-Mehrjardi, M., and Kiasat, A.R., Org. Chem. Res., 2017, vol. 3, p. 25. doi https://doi.org/10.22036/org.chem.2017.41101
Author information
Authors and Affiliations
Corresponding author
Additional information
Conflict of Interest
No conflict of interest was declared by the authors.
Rights and permissions
About this article
Cite this article
Kakesh, N., Sayyahi, S., Badri, R. et al. Imidazolium-Based Ionic Network as a Robust Heterogeneous Catalyst in Synthesis of Phenacyl Derivatives. Russ J Gen Chem 89, 1218–1220 (2019). https://doi.org/10.1134/S1070363219060185
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363219060185