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New complexes of 4-[(4-fluorophenyl)amino]-4-oxobut-2-enoic acid with selected transition metal ions: Synthesis, thermal, and magnetic properties

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Abstract

Complexes of 4-[(4-fluorophenyl)amino]-4-oxobut-2-enoic acid, HL, with Mn(II), Co(II), Ni(II), Cu(II), Nd(III), Gd(III), and Er(III) were synthesized and characterized by various physico-chemical methods: elemental analysis, FT-IR, TG, DTG, DSC, TG/FT-IR, XRF, XRD, and magnetic measurements using the Gouy’s method and a SQUID-VSM magnetometer. The complexes were found to be hydrates (except Er(III) complex) containing 1 to 4 molecules of water. The carboxylate groups acted as bidentate ligands.

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Authors and Affiliations

  1. Faculty of Chemistry, Department of General and Coordination Chemistry, Maria Curie-Skłodowska University, Lublin, 20031, Poland

    W. Ferenc, P. Sadowski, B. Tarasiuk, B. Cristóvão & D. Osypiuk

  2. Institute of Physics, Maria Curie-Skłodowska University, Lublin, 20031, Poland

    J. Sarzyński

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  1. W. Ferenc
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  2. P. Sadowski
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  3. B. Tarasiuk
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  4. B. Cristóvão
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  5. D. Osypiuk
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  6. J. Sarzyński
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Correspondence to W. Ferenc.

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Ferenc, W., Sadowski, P., Tarasiuk, B. et al. New complexes of 4-[(4-fluorophenyl)amino]-4-oxobut-2-enoic acid with selected transition metal ions: Synthesis, thermal, and magnetic properties. Russ J Gen Chem 87, 2719–2727 (2017). https://doi.org/10.1134/S1070363217110305

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  • DOI: https://doi.org/10.1134/S1070363217110305

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