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Formation and CO2/N2 Switchable Ability of a Novel Copolymer Poly(N,N-Diethylaminoethyl Methacrylate-co-Sodium Vinylsulfonate)

  • Functional Polymers
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Abstract

A novel copolymer surfactant has been prepared via a free radical copolymerization of CO2-switchable monomer N,N-diethylaminoethyl methacrylate and the hydrophilic monomer sodium vinyl-sulfonate and characterized. The results of conductivity, dynamic light scattering and cryogenic transmission electron microscopy study showed the change of the microstructure of copolymer in water by adding or removing of CO2. The copolymer aqueous solution was found to exhibit reversible switchability by the bubbling of CO2/N2.

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References

  1. F. Leal-Calderon, J. Bibette, and V. Schmitt, Emulsion Science: Basic Principles (Springer-Verlag GmbH, Berlin; Heidelberg, 2007).

    Google Scholar 

  2. K. Tsuchiya, Y. Orihara, Y. Kondo, N. Yoshino, T. Ohkubo, H. Sakai, and M. Abe, J. Am. Chem. Soc. 126, 12282 (2005).

    Article  CAS  Google Scholar 

  3. Y. Feng and Z. Chu, Soft Matter 11, 4614 (2015).

    Article  CAS  PubMed  Google Scholar 

  4. Z. Jiang, X. Li, G. Yang, L. Cheng, B. Cai, Y. Yang, and J. Dong, Langmuir 28, 7174 (2012).

    Article  CAS  PubMed  Google Scholar 

  5. Y. Takahashi, K. Fukuyasu, T. Horiuchi, Y. Kondo, and P. Stroeve, Langmuir 30, 41 (2013).

    Article  CAS  PubMed  Google Scholar 

  6. P. Brown, C. P. Butts, and J. Eastoe, Soft Matter 9, 2365 (2013).

    Article  CAS  Google Scholar 

  7. M. F. Cunningham and P. G. Jessop, Eur. Polym. J. 76, 208 (2016).

    Article  CAS  Google Scholar 

  8. A. K. Alshamrani, J. R. Vanderveen, and P. G. Jessop, Phys. Chem. Chem. Phys. 18 (28), 19276 (2016).

    Article  CAS  PubMed  Google Scholar 

  9. Y. Liu, P. G. Jessop, M. Cunningham, C. A. Eckert, and C. L. Liotta, Science 313, 958 (2006).

    Article  CAS  PubMed  Google Scholar 

  10. H. Yin, Z. Zhou, J. Huang, R. Zheng, and Y. Zhang, Angew. Chem., Int. Ed. 42, 2188 (2003).

    Article  CAS  Google Scholar 

  11. P. G. Jessop, D. J. Heldebrant, X. Li, C. A. Eckert, and C. L. Liotta, Nature 436, 1102 (2005).

    Article  CAS  PubMed  Google Scholar 

  12. Q. Zhang, W. J. Wang, Y. Lu, B. G. Li, and S. Zhu, Macromolecules 44, 6539 (2011).

    Article  CAS  Google Scholar 

  13. C. A. Seipp, N. J. Williams, M. K. Kidder, and R. Custelcean, Angew. Chem. 56 (4), 1042 (2017).

    Article  CAS  Google Scholar 

  14. P. Koech, J. Zhang, I. Kutnyakov, L. Cosimbescu, S. J. Lee, M. Bowden, T. Smurthwaite, and D. Heldebrant, RSC Adv. 3, 566 (2012).

    Article  Google Scholar 

  15. P. Liu, W. Lu, W. J. Wang, B. G. Li, and S. Zhu, Langmuir 30, 10248 (2014).

    Article  CAS  PubMed  Google Scholar 

  16. D. Han, X. Tong, O. Boissiere, and Y. Zhao, ACS Macro. Lett. 1, 57 (2013).

    Article  CAS  Google Scholar 

  17. Z. Lei, J. Qian, and Y. Fan, RSC Adv. 5, 62229 (2015).

    Article  CAS  Google Scholar 

  18. H. Lu, Z. Zhou, and J. F. Jiang, J. Appl. Polym. Sci. 132, 41307 (2014).

    Google Scholar 

  19. P. G. Jessop, L. N. Phan, A. J. Carrier, R. Resendes, and D. Wechsler, Green Chem. 12, 809 (2010).

    Article  CAS  Google Scholar 

  20. P. G. Jessop, L. Kozycz, Z. G. Rahami, D. Schoenmakers, A. R. Boyd, D. Wechsler, and A. M. Holland, Green Chem. 13, 619 (2011).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Zeng Guofan School, Loudi, 417707, China

    Jinjing Wang

  2. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, China

    Huifeng Wang & Yan Li

  3. School of Materials Science and Engineering, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers, Hunan University of Science and Technology, Xiangtan, 411201, China

    Li Tian, Shanmin Chen, Qiang Liu & Zhen Guo

Authors
  1. Jinjing Wang
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  2. Huifeng Wang
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  3. Yan Li
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  4. Li Tian
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  5. Shanmin Chen
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  6. Qiang Liu
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  7. Zhen Guo
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Correspondence to Li Tian.

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Wang, J., Wang, H., Li, Y. et al. Formation and CO2/N2 Switchable Ability of a Novel Copolymer Poly(N,N-Diethylaminoethyl Methacrylate-co-Sodium Vinylsulfonate). Polym. Sci. Ser. A 60, 612–617 (2018). https://doi.org/10.1134/S0965545X18050139

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  • DOI: https://doi.org/10.1134/S0965545X18050139

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