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Effect of the surface condition of silicas with grafted monofunctional polyfluoroalkylsilanes on the adsorption of polar molecules

  • Physical Chemistry of Surface Phenomena
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Abstract

Lyophobized silicas containing relatively small numbers of grafted perfluorohexyl (1.1 nm−2) and perfluorobutyl (1.7 nm−2) groups are studied by means of gas chromatography, adsorption under static conditions, and IR spectroscopy. The results are compared to those obtained by us previously for a series of samples with dense polyfluoroalkyl monolayers (≥2.0 nm−2). Effects related to the influence of the grafting density and the size of fluorine-containing groups on the adsorption of polar compounds and the hydrophobicity of the surface are discussed.

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Authors and Affiliations

  1. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    T. M. Roshchina, N. K. Shoniya, O. Ya. Tayakina & L. M. Kustov

  2. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. P. Tkachenko & L. M. Kustov

Authors
  1. T. M. Roshchina
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  2. N. K. Shoniya
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  3. O. Ya. Tayakina
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  4. O. P. Tkachenko
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  5. L. M. Kustov
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Correspondence to T. M. Roshchina.

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Original Russian Text © T.M. Roshchina, N.K. Shoniya, O.Ya. Tayakina, O.P. Tkachenko, L.M. Kustov, 2013, published in Zhurnal Fizicheskoi Khimii, 2013, Vol. 87, No. 8, pp. 1371–1378.

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Roshchina, T.M., Shoniya, N.K., Tayakina, O.Y. et al. Effect of the surface condition of silicas with grafted monofunctional polyfluoroalkylsilanes on the adsorption of polar molecules. Russ. J. Phys. Chem. 87, 1367–1373 (2013). https://doi.org/10.1134/S0036024413080190

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  • DOI: https://doi.org/10.1134/S0036024413080190

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