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Synthesis, structure, and electrical and acoustic properties of Cs2Cd2(MoO4)3

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Abstract

We have studied the physicochemical and physical properties of a langbeinite-structure cesium cadmium molybdate (sp. gr. P213, Z = 4, a = 11.239(1) Å). It has very low thermal expansion and possesses piezoelectric properties. We have constructed the section of the longitudinal piezoelectric surface for Cs2Cd2(MoO4)3 by a plane containing a threefold axis (body diagonal), along which the piezoelectric modulus has the highest value: 5.8 × 10−12 C/N.

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References

  1. Tsyrenova, G.D., Bazarova, Zh.G., and Mokhosoev, M.V., Phase Equilibria in the Cs2O-MeO-MoO3 (Me = Mg, Mn, Zn) Systems, Zh. Neorg. Khim., 1986, vol. 31, no. 12, pp. 3120–3123.

    CAS  Google Scholar 

  2. Tsyrenova, G.D., Bazarova, Zh.G., and Mokhosoev, M.V., Double Molybdates of Cesium and Divalent Elements, Dokl. Akad. Nauk SSSR, 1987, vol. 294, no. 2, pp. 387–389.

    CAS  Google Scholar 

  3. Solodovnikov, S.F., Klevtsova, R.F., Kim, V.G., and Klevtsov, P.V., Cs2 R 2+2 (MoO4)3 (R = Ni, Co, Mg, Mn, Cd) Double Molybdates and the Crystal Structure of Cs2Co2(MoO4)3, Zh. Strukt. Khim., 1986, vol. 27, no. 6, pp. 100–106.

    CAS  Google Scholar 

  4. Muller, M., Hildmann, B.O., and Haha, Th., Kristallchemie der Molybdan-Langbeinite M I2 M II2 (MoO4)3, Z. Kristallogr., 1986, vol. 174, nos. 1–4, pp. 152–153.

    Google Scholar 

  5. Solodovnikov, S.F., Klevtsova, R.F., and Klevtsov, P.V., Correlation between the Structure and Physical Properties of Double Molybdates (Tungstates) of Mono- and Divalent Metals, Zh. Strukt. Khim., 1994, vol. 35, no. 6, pp. 145–158.

    CAS  Google Scholar 

  6. Zemann, A. and Zemann, J., Die Kristallstructur von Langbeinit, K2Mg2(SO4)3, Acta Crystallogr., 1957, vol. 10, no. 6, pp. 409–413.

    Article  CAS  Google Scholar 

  7. Orlova, A.I., Orlova, V.A., Bichurin, A.V., et al., Cesium and Its Analogs (Rubidium and Potassium) in Rhombohedral [NaZr2(PO4)3 Type] and Cubic (Langbeinite Type) Phosphates: 1. Crystal-Chemical Characterization, Radiokhimiya, 2005, vol. 47, no. 3, pp. 203–212.

    Google Scholar 

  8. Speer, D. and Salje, E., Phase Transitions in Langbeinites: I. Crystal Chemistry and Structures of K-Double Sulfates of the Langbeinite, Type M ++2 K2(SO4)3 (M ++ = Mg, Ni, Co, Zn, Ca), Phys. Chem. Miner., 1986, no. 13, pp. 17–24.

  9. Tsyrenova, G.D., Chemical Interaction of Rubidium and Cesium Molybdates with Divalent Element Molybdates, Extended Abstract of Cand. Sci. (Chem.) Dissertation, Moscow, 1989.

  10. Crystal Morphology Editor&Viewer. 1.04, JCrystal. JCrystalSoft 2003: www.jcrystal.com.

  11. Khazheeva, Z.I., Tsyrenova, G.D., and Mokhosoev, M.V., Crystal Structure of the Double Molybdate Cs2Cd2(MoO4)3, Dokl. Akad. Nauk SSSR, 1988, vol. 303, no. 6, pp. 1417–1420.

    CAS  Google Scholar 

  12. W.A. Wooster, Tensors and Group Theory for the Physical Properties of Crystals, Oxford: Clarendon, 1973.

    Google Scholar 

  13. Smagin, A.G. and Yaroslavskii, M.I., P’ezoelektrichestvo kvartsa i kvartsevye rezonatory (Quartz Piezoelectricity and Resonators), Moscow: Energiya, 1970.

    Google Scholar 

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Correspondence to G. D. Tsyrenova.

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Original Russian Text © G.D. Tsyrenova, N.N. Pavlova, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 7, pp. 872–876.

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Tsyrenova, G.D., Pavlova, N.N. Synthesis, structure, and electrical and acoustic properties of Cs2Cd2(MoO4)3 . Inorg Mater 47, 786–790 (2011). https://doi.org/10.1134/S0020168511070235

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