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Synthesis and structural study of Rb2FeZr(PO4)3 phosphate with langbeinite structure

  • Structure of Inorganic Compounds
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Abstract

A new orthophosphate of rubidium, iron, and zirconium, crystallizing in the langbeinite structure (cubic system, sp. gr. P213, Z = 4), was synthesized and investigated by X-ray powder diffraction and IR spectroscopy. The structure of the Rb2FeZr(PO4)3 phosphate was refined by the Rietveld method using the neutron powder diffraction data (DN-2 time-of-flight diffractometer; Joint Institute for Nuclear Research, Dubna). This structure is characterized by a mixed framework [FeZr(PO4)3] with Rb atoms located in large cavities. Fe3+ and Zr4+ cations are distributed statistically over two independent crystallographic positions.

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 603950, Russia

    I. G. Trubach, A. I. Orlova & V. A. Orlova

  2. Joint Institute for Nuclear Research, Dubna, Moscow oblast, 141980, Russia

    A. I. Beskrovnyi

  3. Moscow State University, Vorob’evy gory, Moscow, 119992, Russia

    V. S. Kurazhkovskaya

Authors
  1. I. G. Trubach
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  2. A. I. Beskrovnyi
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  3. A. I. Orlova
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  4. V. A. Orlova
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  5. V. S. Kurazhkovskaya
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__________

Translated from Kristallografiya, Vol. 49, No. 6, 2004, pp. 991–994.

Original Russian Text Copyright © 2004 by Trubach, Beskrovny\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l} \), A. Orlova, V. Orlova, Kurazhkovskaya.

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Trubach, I.G., Beskrovnyi, A.I., Orlova, A.I. et al. Synthesis and structural study of Rb2FeZr(PO4)3 phosphate with langbeinite structure. Crystallogr. Rep. 49, 895–898 (2004). https://doi.org/10.1134/1.1828132

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  • DOI: https://doi.org/10.1134/1.1828132

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