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Synthesis and investigation of the new phosphates K2 LnZr(PO4)3 (Ln = Ce-Yb, Y) with langbeinite Structure

  • Structure of Inorganic Compounds
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Abstract

New orthophosphates of potassium, zirconium, and rare earth elements K2 LnZr(PO4)3 (Ln = Ce-Yb, Y) that crystallize in a langbeinite structure (cubic system, sp. gr. P213, Z = 4) were prepared and investigated by X-ray diffraction and IR spectroscopy. The structure of the K2PrZr(PO4)3 phosphate was refined by the Rietveld method using neutron powder diffraction data (DN-2 time-of-flight diffractometer, Joint Institute for Nuclear Research, Dubna). This structure is characterized by a mixed framework [PrZr(PO4)3] with large cavities in which potassium cations are located. Pr3+ and Zr4+ cations are distributed in order over two independent crystallographic positions. The limits of the incorporation of lanthanide cations into the anionic framework in phosphates with sodium-zirconium phosphate and langbeinite structures are considered.

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References

  1. A. A. Voronov, V. V. Ilyukhin, and N. V. Belov, Kristallografiya 20(3), 556 (1975) [Sov. Phys. Crystallogr. 20, 340 (1975)].

    Google Scholar 

  2. H. Wulff, U. Guth, and B. Loescher, Powder Diffr. 7, 103 (1992).

    Google Scholar 

  3. E. R. Losilla, S. Bruque, M. A. G. Aranda, et al., Solid State Ionics 112, 53 (1998).

    Article  Google Scholar 

  4. R. Masse, A. Durif, J. C. Guitel, and I. Tordjman, Bull. Soc. Fr. Mineral. Crystallogr. 95, 47 (1972).

    Google Scholar 

  5. A. Leclaire, A. Benmoussa, M. M. Borel, et al., J. Solid State Chem. 78, 227 (1989).

    ADS  Google Scholar 

  6. E. S. Lunezheva, B. A. Maksimov, O. K. Mel’nikov, and L. A. Muradyan, Kristallografiya 34(3), 611 (1989) [Sov. Phys. Crystallogr. 34, 363 (1989)].

    Google Scholar 

  7. J. Isasi and A. Daidouh, Solid State Ionics 133, 303 (2000).

    Article  Google Scholar 

  8. P. D. Battle, A. K. Cheetham, W. T. A. Harrison, and G. J. Long, J. Solid State Chem. 62, 16 (1986).

    Article  ADS  Google Scholar 

  9. P. D. Battle, T. C. Gibb, S. Nixon, and W. T. A. Harrison, J. Solid State Chem. 75, 21 (1988).

    Article  ADS  Google Scholar 

  10. Y. Miyajima, T. Miyoshi, J. Tamaki, et al., Solid State Ionics 124, 201 (1999).

    Article  Google Scholar 

  11. V. B. Zlokazov and V. V. Chernyshev, J. Appl. Crystallogr. 25, 447 (1992).

    Google Scholar 

Download references

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Authors and Affiliations

  1. Nizhni Novgorod State University, pr. Gagarina 23, Nizhni Novgorod, 630950, Russia

    I. G. Trubach, A. I. Orlova & V. A. Orlova

  2. Joint Institute for Nuclear Research, Dubna, Moscow oblast, 141980, Russia

    A. I. Beskrovnyi

  3. Moscow State University, Vorob’evy gory, Moscow, 119899, Russia

    V. S. Kurazhkovskaya

Authors
  1. I. G. Trubach
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  2. A. I. Beskrovnyi
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  3. A. I. Orlova
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  4. V. A. Orlova
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  5. V. S. Kurazhkovskaya
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Translated from Kristallografiya, Vol. 49, No. 4, 2004, pp. 692–696.

Original Russian Text Copyright © 2004 by Trubach, Beskrovny\(\overset{\lower0.5em\hbox{$\smash{\scriptscriptstyle\smile}$}}{l}\), A. Orlova, V. Orlova, Kurazhkovskaya.

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Trubach, I.G., Beskrovnyi, A.I., Orlova, A.I. et al. Synthesis and investigation of the new phosphates K2 LnZr(PO4)3 (Ln = Ce-Yb, Y) with langbeinite Structure. Crystallogr. Rep. 49, 614–618 (2004). https://doi.org/10.1134/1.1780625

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  • DOI: https://doi.org/10.1134/1.1780625

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