Singlet delta oxygen production in self-sustained and non-self-sustained slab discharges

Andrey A. Ionin; Michail P. Frolov; Vladimir N. Ochkin; Yurii P. Podmar'kov; Sergey Yu. Savinov; Leonid V. Seleznev; Dmitrii V. Sinitsyn; Nikolai P. Vagin; Nikolai N. Yuryshev; Igor V. Kochetov; Anatoly P. Napartovich; Oleg A. Rulev

doi:10.1117/12.644104

23 February 2006 Singlet delta oxygen production in self-sustained and non-self-sustained slab discharges

Andrey A. Ionin, Michail P. Frolov, Vladimir N. Ochkin, Yurii P. Podmar'kov, Sergey Yu. Savinov, Leonid V. Seleznev, Dmitrii V. Sinitsyn, Nikolai P. Vagin, Nikolai N. Yuryshev, Igor V. Kochetov, Anatoly P. Napartovich, Oleg A. Rulev

Author Affiliations +

Proceedings Volume 6101, Laser Beam Control and Applications; 61011X (2006) https://doi.org/10.1117/12.644104
Event: Lasers and Applications in Science and Engineering, 2006, San Jose, California, United States

Abstract

Singlet delta oxygen O₂(a¹Δg) (SDO) production in a slab discharges ignited in oxygen gas mixtures was experimentally studied. An influence of gas mixture content and input electric power on SDO yield was analyzed. In self-sustained RF slab discharge SDO yield of 10±5% was measured by comparison luminescence intensity of SDO going from a chemical generator and SDO generated in electric discharge. SDO yield of 7.2% was measured by intracavity laser spectroscopy method. It was demonstrated that the choice of electrodes material is very important. Experiments on SDO production in slab non-self-sustained discharge with external ionization by repeating high-voltage pulses were carried out. SDO concentration was measured by the method of intracavity laser spectroscopy. The measured concentration of SDO was about 1.5 10¹⁶ cm^-3, with SDO yield of ~10.6%. A development of electric discharge oxygen-iodine laser with SDO production in long electrodes slab discharge is discussed.

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Andrey A. Ionin, Michail P. Frolov, Vladimir N. Ochkin, Yurii P. Podmar'kov, Sergey Yu. Savinov, Leonid V. Seleznev, Dmitrii V. Sinitsyn, Nikolai P. Vagin, Nikolai N. Yuryshev, Igor V. Kochetov, Anatoly P. Napartovich, and Oleg A. Rulev "Singlet delta oxygen production in self-sustained and non-self-sustained slab discharges", Proc. SPIE 6101, Laser Beam Control and Applications, 61011X (23 February 2006); https://doi.org/10.1117/12.644104

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