Towards a revisitation of vesuvianite-group nomenclature: the crystal structure of Ti-rich vesuvianite from Alchuri, Shigar Valley

Aksenov, S.M.; Chukanov, N.V.; Rusakov, V.S.; Panikorovskii, T.L.; Rastsvetaeva, R.K.; Gainov, R.R.; Vagizov, F.G.; Lyssenko, K.A.; Belakovskiy, D.I.

doi:10.1107/S2052520616010246

Towards a revisitation of vesuvianite-group nomenclature: the crystal structure of Ti-rich vesuvianite from Alchuri, Shigar Valley

S. M. Aksenov, N. V. Chukanov, V. S. Rusakov, T. L. Panikorovskii, R. K. Rastsvetaeva, R. R. Gainov, F. G. Vagizov, K. A. Lyssenko and D. I. Belakovskiy

Vesuvianite containing 5.85 wt% TiO₂ from an Alpine-cleft-type assemblage outcropped near Alchuri, Shigar Valley, Northern Areas, has been investigated by means of electron microprobe analyses, gas-chromatographic analysis of H₂O, X-ray powder diffraction, single-crystal X-ray structure refinement, ²⁷Al NMR, ⁵⁷Fe Mössbauer spectroscopy, IR spectroscopy and optical measurements. Tetragonal unit-cell parameters are: a = 15.5326 (2), c = 11.8040 (2) Å, space group P4/nnc. The structure was refined to final R₁ = 0.031, wR₂ = 0.057 for 11247 I > 2σ(I). A general crystal-chemical formula of studied sample can be written as follows (Z = 2): ^[8–9](Ca_17.1Na_0.9) ^[8]Ca_1.0 ^[5](Fe²⁺_0.44Fe³⁺_0.34Mg_0.22) ^[6](Al_3.59Mg_0.41) ^[6](Al_4.03Ti_2.20Fe³⁺_1.37Fe²⁺_0.40) (Si₁₈O₆₈) [(OH)_5.84O_2.83F_1.33]. The octahedral site Y2 is Al-dominant and does not contain transition elements. Another octahedral site Y3 is also Al-dominant and contains Fe²⁺, Fe³⁺ and Ti. The site Y1 is split into Y1a and Y1b predominantly occupied by Fe²⁺ and Fe³⁺, respectively. The role of the Y1 site in the diversity of vesuvianite-group minerals is discussed.

Keywords: vesuvianite; crystal chemistry; ²⁷Al NMR NMR spectroscopy; Mössbauer spectroscopy; IR spectroscopy.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S2052520616010246/bp5089sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S2052520616010246/bp5089Isup2.hkl Contains datablock I
	Portable Document Format (PDF) file https://doi.org/10.1107/S2052520616010246/bp5089sup3.pdf Supporting tables

CCDC reference: 1487410

Computing details top

(I) top

Crystal data top

Al_7.62Ca_18.1Fe_2.55Mg_0.63Na_0.9O₇₈Si₁₈Ti_2.2	Z = 2
M_r = 2968.3	F(000) = 2938
Tetragonal, P4/nnc	D_x = 3.460 Mg m⁻³
Hall symbol: -P 4a;-2bc	Mo Kα radiation, λ = 0.71069 Å
a = 15.5326 (2) Å	µ = 3.26 mm⁻¹
c = 11.8040 (2) Å	T = 293 K
V = 2847.85 Å³	0.25 × 0.18 × 0.13 mm

Data collection top

Radiation source: X-ray tube	θ_max = 62.8°, θ_min = 1.9°
498719 measured reflections	h = −38→38
11247 independent reflections	k = −38→38
10270 reflections with I > 2σ(I)	l = −29→29
R_int = 0.058

Refinement top

Refinement on F	30 constraints
R[F² > 2σ(F²)] = 0.031	Weighting scheme based on measured s.u.'s w = 1/(σ²(F) + 0.002116F²)
wR(F²) = 0.057	(Δ/σ)_max = 0.048
S = 1.02	Δρ_max = 1.33 e Å⁻³
11247 reflections	Δρ_min = −0.89 e Å⁻³
156 parameters	Extinction correction: B-C type 1 Gaussian isotropic (Becker & Coppens, 1974)
0 restraints	Extinction coefficient: 96E2 (9)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ca_x1	0.75	0.25	0.25	0.00382 (4)	0.552 (8)
Na_x1	0.75	0.25	0.25	0.00382 (4)	0.448 (6)
Ca_x2	0.810820 (10)	0.044930 (10)	0.379290 (10)	0.00439 (2)
Ca_x3	0.898955 (8)	0.820364 (8)	0.886577 (13)	0.00817 (2)
Ca_x4	0.75	0.75	0.14320 (4)	0.00523 (5)	0.5
Al_y2	0	0	0	0.00264 (4)	0.898 (8)
Mg_y2	0	0	0	0.00264 (4)	0.102 (4)
Al_y3	−0.110510 (10)	0.120290 (10)	0.128290 (10)	0.00635 (2)	0.503 (6)
Ti_y3	−0.110510 (10)	0.120290 (10)	0.128290 (10)	0.00635 (2)	0.274 (7)
Fe_y3	−0.110510 (10)	0.120290 (10)	0.128290 (10)	0.00635 (2)	0.223 (4)
Si_z1	0.75	0.25	0	0.00334 (4)
Si_z2	0.819234 (12)	0.039105 (12)	0.871641 (14)	0.00334 (3)
Si_z3	0.916428 (13)	0.849330 (11)	0.364516 (15)	0.00415 (3)
O1	0.71974 (3)	0.32788 (3)	0.08497 (3)	0.00502 (6)
O2	0.84042 (3)	0.11539 (3)	0.77938 (4)	0.00565 (6)
O3	0.72184 (3)	0.04851 (3)	0.92452 (3)	0.00453 (5)
O4	0.89344 (3)	0.06089 (3)	0.97016 (3)	0.00473 (5)
O5	1.01464 (3)	0.82977 (3)	0.32077 (4)	0.00663 (6)
O6	0.88118 (4)	0.77158 (3)	0.44152 (4)	0.00887 (8)
O7	0.82485 (3)	−0.05745 (3)	0.82244 (4)	0.00579 (6)
O8	0.90897 (3)	0.93965 (3)	0.43275 (3)	0.00463 (5)
O9	0.85490 (3)	0.85490 (3)	0.25	0.00628 (6)
O10	0.75	0.75	−0.13402 (13)	0.01226 (18)
O11	0.00440 (3)	−0.06290 (3)	−0.13546 (3)	0.00528 (6)
Fe_y1a	0.75	0.75	0.06618 (12)	0.00405 (12)	0.151 (9)
Fe_y1b	0.75	0.75	0.03388 (6)	0.00165 (6)	0.245 (11)
Mg_y1a	0.75	0.75	0.06618 (12)	0.00405 (12)	0.104 (8)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ca_x1	0.00617 (8)	0.00309 (7)	0.00219 (6)	0	0	0
Na_x1	0.00617 (8)	0.00309 (7)	0.00219 (6)	0	0	0
Ca_x2	0.00350 (3)	0.00573 (3)	0.00393 (3)	0.00060 (10)	−0.00042 (2)	−0.00012 (2)
Ca_x3	0.00586 (4)	0.00541 (3)	0.01324 (4)	0.00195 (2)	−0.00441 (3)	−0.00317 (3)
Ca_x4	0.00400 (6)	0.00400 (6)	0.00769 (11)	0	0	0
Al_y2	0.00200 (7)	0.00229 (7)	0.00365 (7)	0.00011 (5)	0.00036 (5)	0.00032 (5)
Mg_y2	0.00200 (7)	0.00229 (7)	0.00365 (7)	0.00011 (5)	0.00036 (5)	0.00032 (5)
Al_y3	0.00816 (4)	0.00591 (4)	0.00499 (4)	−0.00189 (3)	0.00175 (3)	−0.00082 (3)
Ti_y3	0.00816 (4)	0.00591 (4)	0.00499 (4)	−0.00189 (3)	0.00175 (3)	−0.00082 (3)
Fe_y3	0.00816 (4)	0.00591 (4)	0.00499 (4)	−0.00189 (3)	0.00175 (3)	−0.00082 (3)
Si_z1	0.00334 (5)	0.00334 (5)	0.00332 (8)	0	0	0
Si_z2	0.00308 (5)	0.00340 (5)	0.00354 (5)	−0.00007 (3)	−0.00027 (3)	0.00017 (3)
Si_z3	0.00729 (5)	0.00243 (5)	0.00273 (4)	0.00037 (4)	0.00043 (4)	0.00001 (3)
O1	0.00675 (11)	0.00373 (9)	0.00459 (9)	0.00035 (7)	0.00028 (8)	−0.00033 (7)
O2	0.00566 (10)	0.00594 (11)	0.00534 (10)	−0.00103 (8)	−0.00017 (8)	0.00181 (8)
O3	0.00402 (9)	0.00507 (10)	0.00451 (9)	−0.00032 (7)	0.00055 (7)	0.00004 (7)
O4	0.00373 (9)	0.00558 (10)	0.00488 (9)	0.00008 (7)	−0.00073 (7)	0.00069 (8)
O5	0.00871 (12)	0.00570 (11)	0.00548 (10)	0.00324 (9)	0.00059 (9)	−0.00056 (8)
O6	0.01575 (18)	0.00501 (11)	0.00584 (11)	−0.00219 (11)	−0.00169 (11)	0.00232 (9)
O7	0.00683 (11)	0.00400 (10)	0.00653 (10)	0.00069 (8)	0.00045 (8)	−0.00053 (8)
O8	0.00465 (10)	0.00381 (9)	0.00544 (9)	0.00064 (7)	−0.00082 (7)	−0.00157 (7)
O9	0.00754 (10)	0.00754 (10)	0.00377 (12)	−0.00195 (13)	−0.00041 (8)	0.00041 (8)
O10	0.00631 (16)	0.00631 (16)	0.0242 (5)	0	0	0
O11	0.00503 (10)	0.00657 (11)	0.00422 (9)	−0.00049 (8)	−0.00033 (7)	−0.00092 (8)
Fe_y1a	0.00053 (13)	0.00053 (13)	0.0111 (3)	0	0	0
Fe_y1b	0.00175 (10)	0.00175 (10)	0.00143 (13)	0	0	0
Mg_y1a	0.00053 (13)	0.00053 (13)	0.0111 (3)	0	0	0

Geometric parameters (Å, º) top

Ca_x1—Na_x1	0	Ca_x3—Al_y3^xxii	3.4173 (2)
Ca_x1—Ca_x2	3.6561 (1)	Ca_x3—Ti_y3^xxii	3.4173 (2)
Ca_x1—Ca_x2ⁱ	3.6561 (1)	Ca_x3—Si_z2^xxiii	3.0776 (2)
Ca_x1—Ca_x2ⁱⁱ	3.6561 (1)	Ca_x3—O7^xxiv	2.3453 (4)
Ca_x1—Ca_x2ⁱⁱⁱ	3.6561 (1)	Ca_x3—Fe_y1a^xx	3.3230 (9)
Ca_x1—Al_y3^iv	3.2890 (2)	Ca_x3—Fe_y1b^xx	3.0937 (4)
Ca_x1—Al_y3^v	3.2890 (2)	Ca_x3—Mg_y1a^xx	3.3230 (9)
Ca_x1—Al_y3^vi	3.2890 (2)	Ca_x4—Ca_x4ⁱⁱ	2.5212 (7)
Ca_x1—Al_y3^vii	3.2890 (2)	Ca_x4—Si_z3ⁱⁱ	3.0119 (2)
Ca_x1—Ti_y3^iv	3.2890 (2)	Ca_x4—Si_z3^xxv	3.0119 (2)
Ca_x1—Ti_y3^v	3.2890 (2)	Ca_x4—Si_z3^xxvi	3.0119 (2)
Ca_x1—Ti_y3^vi	3.2890 (2)	Ca_x4—Si_z3^xxvii	3.0119 (2)
Ca_x1—Ti_y3^vii	3.2890 (2)	Ca_x4—O6ⁱⁱ	2.2944 (6)
Ca_x1—Fe_y3^iv	3.2890 (2)	Ca_x4—O6^xxv	2.2944 (6)
Ca_x1—Fe_y3^v	3.2890 (2)	Ca_x4—O6^xxvi	2.2944 (6)
Ca_x1—Fe_y3^vi	3.2890 (2)	Ca_x4—O6^xxvii	2.2944 (6)
Ca_x1—Fe_y3^vii	3.2890 (2)	Ca_x4—Fe_y1a	0.9092 (14)
Ca_x1—Si_z1	2.951	Ca_x4—Fe_y1b	1.2904 (9)
Ca_x1—Si_z1ⁱⁱ	2.951	Ca_x4—Mg_y1a	0.9092 (14)
Ca_x1—O1	2.3407 (4)	Ca_x4—Mg_y1aⁱⁱ	3.4304 (14)
Ca_x1—O1ⁱ	2.3407 (4)	Al_y2—Mg_y2	0
Ca_x1—O1ⁱⁱ	2.3407 (4)	Al_y2—Al_y3	2.9548 (2)
Ca_x1—O1ⁱⁱⁱ	2.3407 (4)	Al_y2—Al_y3^xxviii	2.9548 (2)
Na_x1—Ca_x2	3.6561 (1)	Al_y2—Ti_y3	2.9548 (2)
Na_x1—Ca_x2ⁱ	3.6561 (1)	Al_y2—Ti_y3^xxviii	2.9548 (2)
Na_x1—Ca_x2ⁱⁱ	3.6561 (1)	Mg_y2—Al_y3	2.9548 (2)
Na_x1—Ca_x2ⁱⁱⁱ	3.6561 (1)	Mg_y2—Al_y3^xxviii	2.9548 (2)
Na_x1—Al_y3^iv	3.2890 (2)	Mg_y2—Ti_y3	2.9548 (2)
Na_x1—Al_y3^v	3.2890 (2)	Mg_y2—Ti_y3^xxviii	2.9548 (2)
Na_x1—Al_y3^vi	3.2890 (2)	Mg_y2—Fe_y3	2.9548 (2)
Na_x1—Al_y3^vii	3.2890 (2)	Mg_y2—Fe_y3^xxviii	2.9548 (2)
Na_x1—Ti_y3^iv	3.2890 (2)	Mg_y2—O4^xxix	1.9386 (4)
Na_x1—Ti_y3^v	3.2890 (2)	Mg_y2—O4^xxx	1.9386 (4)
Na_x1—Ti_y3^vi	3.2890 (2)	Mg_y2—O8^xxxi	1.8730 (4)
Na_x1—Ti_y3^vii	3.2890 (2)	Mg_y2—O8^xi	1.8730 (4)
Na_x1—Fe_y3^iv	3.2890 (2)	Mg_y2—O11	1.8751 (4)
Na_x1—Fe_y3^v	3.2890 (2)	Mg_y2—O11^xxviii	1.8751 (4)
Na_x1—Fe_y3^vi	3.2890 (2)	Al_y3—Ti_y3	0
Na_x1—Fe_y3^vii	3.2890 (2)	Al_y3—Fe_y3	0
Na_x1—Si_z1	2.951	Ti_y3—Fe_y3	0
Na_x1—Si_z1ⁱⁱ	2.951	Ti_y3—O1^v	1.9463 (5)
Na_x1—O1	2.3407 (4)	Ti_y3—O2^xxxii	1.8865 (4)
Na_x1—O1ⁱ	2.3407 (4)	Ti_y3—O3^xxxiii	1.9503 (4)
Na_x1—O1ⁱⁱ	2.3407 (4)	Ti_y3—O4^xxix	2.0831 (4)
Na_x1—O1ⁱⁱⁱ	2.3407 (4)	Ti_y3—O5^xxxi	1.9786 (5)
Ca_x2—Ca_x2ⁱⁱ	3.5898 (1)	Ti_y3—O11^xxviii	1.8758 (5)
Ca_x2—Ca_x3^viii	3.5779 (2)	Fe_y3—O1^v	1.9463 (5)
Ca_x2—Al_y2^ix	3.3394 (1)	Fe_y3—O2^xxxii	1.8865 (4)
Ca_x2—Mg_y2^ix	3.3394 (1)	Fe_y3—O3^xxxiii	1.9503 (4)
Ca_x2—Al_y3^iv	3.4120 (2)	Fe_y3—O4^xxix	2.0831 (4)
Ca_x2—Al_y3^vi	3.3255 (2)	Fe_y3—O5^xxxi	1.9786 (5)
Ca_x2—Al_y3^x	3.2895 (2)	Fe_y3—O11^xxviii	1.8758 (5)
Ca_x2—Ti_y3^iv	3.4120 (2)	Si_z1—O1	1.6402 (4)
Ca_x2—Ti_y3^vi	3.3255 (2)	Si_z1—O1ⁱ	1.6402 (4)
Ca_x2—Ti_y3^x	3.2895 (2)	Si_z1—O1^xxxiv	1.6402 (4)
Ca_x2—Fe_y3^vi	3.3255 (2)	Si_z1—O1^xxxv	1.6402 (4)
Ca_x2—Fe_y3^x	3.2895 (2)	Si_z2—O2	1.6427 (5)
Ca_x2—Si_z2^xi	3.1454 (2)	Si_z2—O3	1.6430 (4)
Ca_x2—Si_z3^xii	3.1941 (2)	Si_z2—O4	1.6719 (4)
Ca_x2—O2^xi	2.4240 (4)	Si_z2—O7	1.6106 (5)
Ca_x2—O3^xiii	2.3714 (4)	Si_z3—O5	1.6390 (5)
Ca_x2—O5^xii	2.3383 (5)	Si_z3—O6	1.6075 (5)
Ca_x2—O5^xiv	2.4258 (4)	Si_z3—O8	1.6218 (4)
Ca_x2—O8^xv	2.3230 (4)	Si_z3—O9	1.6577 (3)
Ca_x3—Ca_x3^xvi	3.6187 (2)	O6—Fe_y1aⁱⁱ	2.0670 (6)
Ca_x3—Ca_x3^xvii	3.6187 (2)	O6—Fe_y1bⁱⁱ	2.0853 (6)
Ca_x3—Ca_x3^xviii	3.8954 (2)	O6—Mg_y1aⁱⁱ	2.0670 (6)
Ca_x3—Ca_x3^xix	3.6574 (2)	O10—Fe_y1b	1.9820 (17)
Ca_x3—Ca_x4^xx	3.9653 (4)	Fe_y1a—Fe_y1b	0.3812 (15)
Ca_x3—Al_y2^xxi	3.4700 (1)	Fe_y1a—Mg_y1a	0
Ca_x3—Mg_y2^xxi	3.4700 (1)	Fe_y1b—Mg_y1a	0.3812 (15)

Na_x1—Ca_x1—Ca_x2	0	Ca_x3^xxxviii—Ca_x4—Ca_x3^xxxix	54.297 (6)
Na_x1—Ca_x1—Ca_x2ⁱ	0	Ca_x3^xxxviii—Ca_x4—Ca_x3^xl	54.297 (6)
Na_x1—Ca_x1—Ca_x2ⁱⁱ	0	Ca_x3^xxxviii—Ca_x4—Ca_x4ⁱⁱ	139.812 (5)
Na_x1—Ca_x1—Ca_x2ⁱⁱⁱ	0	Ca_x3^xxxviii—Ca_x4—Si_z3ⁱⁱ	67.498 (7)
Na_x1—Ca_x1—Al_y3^iv	0	Ca_x3^xxxviii—Ca_x4—Si_z3^xxv	109.663 (10)
Na_x1—Ca_x1—Al_y3^v	0	Ca_x3^xxxviii—Ca_x4—Si_z3^xxvi	120.820 (12)
Na_x1—Ca_x1—Al_y3^vi	0	Ca_x3^xxxviii—Ca_x4—Si_z3^xxvii	56.043 (6)
Na_x1—Ca_x1—Al_y3^vii	0	Ca_x3^xxxviii—Ca_x4—O6ⁱⁱ	35.820 (13)
Na_x1—Ca_x1—Ti_y3^iv	0	Ca_x3^xxxviii—Ca_x4—O6^xxv	98.333 (18)
Na_x1—Ca_x1—Ti_y3^v	0	Ca_x3^xxxviii—Ca_x4—O6^xxvi	89.832 (17)
Na_x1—Ca_x1—Ti_y3^vi	0	Ca_x3^xxxviii—Ca_x4—O6^xxvii	48.471 (14)
Na_x1—Ca_x1—Ti_y3^vii	0	Ca_x3^xxxviii—Ca_x4—Fe_y1a	40.188 (5)
Na_x1—Ca_x1—Fe_y3^iv	0	Ca_x3^xxxviii—Ca_x4—Fe_y1b	40.188 (5)
Na_x1—Ca_x1—Fe_y3^v	0	Ca_x3^xxxviii—Ca_x4—Mg_y1a	40.188 (5)
Na_x1—Ca_x1—Fe_y3^vi	0	Ca_x3^xxxviii—Ca_x4—Mg_y1aⁱⁱ	139.812 (5)
Na_x1—Ca_x1—Fe_y3^vii	0	Ca_x3^xxxix—Ca_x4—Ca_x3^xl	80.376 (9)
Na_x1—Ca_x1—Si_z1	0	Ca_x3^xxxix—Ca_x4—Ca_x4ⁱⁱ	139.812 (5)
Na_x1—Ca_x1—Si_z1ⁱⁱ	0	Ca_x3^xxxix—Ca_x4—Si_z3ⁱⁱ	56.043 (6)
Na_x1—Ca_x1—O1	0	Ca_x3^xxxix—Ca_x4—Si_z3^xxv	120.820 (12)
Na_x1—Ca_x1—O1ⁱ	0	Ca_x3^xxxix—Ca_x4—Si_z3^xxvi	67.498 (7)
Na_x1—Ca_x1—O1ⁱⁱ	0	Ca_x3^xxxix—Ca_x4—Si_z3^xxvii	109.663 (10)
Na_x1—Ca_x1—O1ⁱⁱⁱ	0	Ca_x3^xxxix—Ca_x4—O6ⁱⁱ	48.471 (14)
Ca_x2—Ca_x1—Ca_x2ⁱ	130.657 (2)	Ca_x3^xxxix—Ca_x4—O6^xxv	89.832 (17)
Ca_x2—Ca_x1—Ca_x2ⁱⁱ	58.803 (2)	Ca_x3^xxxix—Ca_x4—O6^xxvi	35.820 (13)
Ca_x2—Ca_x1—Ca_x2ⁱⁱⁱ	150.050 (2)	Ca_x3^xxxix—Ca_x4—O6^xxvii	98.333 (18)
Ca_x2—Ca_x1—Al_y3^iv	58.564 (3)	Ca_x3^xxxix—Ca_x4—Fe_y1a	40.188 (5)
Ca_x2—Ca_x1—Al_y3^v	152.401 (3)	Ca_x3^xxxix—Ca_x4—Fe_y1b	40.188 (5)
Ca_x2—Ca_x1—Al_y3^vi	56.923 (3)	Ca_x3^xxxix—Ca_x4—Mg_y1a	40.188 (5)
Ca_x2—Ca_x1—Al_y3^vii	100.434 (3)	Ca_x3^xxxix—Ca_x4—Mg_y1aⁱⁱ	139.812 (5)
Ca_x2—Ca_x1—Ti_y3^iv	58.564 (3)	Ca_x3^xl—Ca_x4—Ca_x4ⁱⁱ	139.812 (5)
Ca_x2—Ca_x1—Ti_y3^v	152.401 (3)	Ca_x3^xl—Ca_x4—Si_z3ⁱⁱ	120.820 (12)
Ca_x2—Ca_x1—Ti_y3^vi	56.923 (3)	Ca_x3^xl—Ca_x4—Si_z3^xxv	56.043 (6)
Ca_x2—Ca_x1—Ti_y3^vii	100.434 (3)	Ca_x3^xl—Ca_x4—Si_z3^xxvi	109.663 (10)
Ca_x2—Ca_x1—Fe_y3^iv	58.564 (3)	Ca_x3^xl—Ca_x4—Si_z3^xxvii	67.498 (7)
Ca_x2—Ca_x1—Fe_y3^v	152.401 (3)	Ca_x3^xl—Ca_x4—O6ⁱⁱ	89.832 (17)
Ca_x2—Ca_x1—Fe_y3^vi	56.923 (3)	Ca_x3^xl—Ca_x4—O6^xxv	48.471 (14)
Ca_x2—Ca_x1—Fe_y3^vii	100.434 (3)	Ca_x3^xl—Ca_x4—O6^xxvi	98.333 (18)
Ca_x2—Ca_x1—Si_z1	114.6717 (15)	Ca_x3^xl—Ca_x4—O6^xxvii	35.820 (13)
Ca_x2—Ca_x1—Si_z1ⁱⁱ	65.3283 (15)	Ca_x3^xl—Ca_x4—Fe_y1a	40.188 (5)
Ca_x2—Ca_x1—O1	148.159 (10)	Ca_x3^xl—Ca_x4—Fe_y1b	40.188 (5)
Ca_x2—Ca_x1—O1ⁱ	81.098 (10)	Ca_x3^xl—Ca_x4—Mg_y1a	40.188 (5)
Ca_x2—Ca_x1—O1ⁱⁱ	92.921 (10)	Ca_x3^xl—Ca_x4—Mg_y1aⁱⁱ	139.812 (5)
Ca_x2—Ca_x1—O1ⁱⁱⁱ	41.778 (10)	Ca_x4ⁱⁱ—Ca_x4—Si_z3ⁱⁱ	91.734 (10)
Ca_x2ⁱ—Ca_x1—Ca_x2ⁱⁱ	150.050 (2)	Ca_x4ⁱⁱ—Ca_x4—Si_z3^xxv	91.734 (10)
Ca_x2ⁱ—Ca_x1—Ca_x2ⁱⁱⁱ	58.803 (2)	Ca_x4ⁱⁱ—Ca_x4—Si_z3^xxvi	91.734 (10)
Ca_x2ⁱ—Ca_x1—Al_y3^iv	152.401 (3)	Ca_x4ⁱⁱ—Ca_x4—Si_z3^xxvii	91.734 (10)
Ca_x2ⁱ—Ca_x1—Al_y3^v	58.564 (3)	Ca_x4ⁱⁱ—Ca_x4—O6ⁱⁱ	115.840 (16)
Ca_x2ⁱ—Ca_x1—Al_y3^vi	100.434 (3)	Ca_x4ⁱⁱ—Ca_x4—O6^xxv	115.840 (16)
Ca_x2ⁱ—Ca_x1—Al_y3^vii	56.923 (3)	Ca_x4ⁱⁱ—Ca_x4—O6^xxvi	115.840 (16)
Ca_x2ⁱ—Ca_x1—Ti_y3^iv	152.401 (3)	Ca_x4ⁱⁱ—Ca_x4—O6^xxvii	115.840 (16)
Ca_x2ⁱ—Ca_x1—Ti_y3^v	58.564 (3)	Ca_x4ⁱⁱ—Ca_x4—Fe_y1a	180.0 (5)
Ca_x2ⁱ—Ca_x1—Ti_y3^vi	100.434 (3)	Ca_x4ⁱⁱ—Ca_x4—Fe_y1b	180.0 (5)
Ca_x2ⁱ—Ca_x1—Ti_y3^vii	56.923 (3)	Ca_x4ⁱⁱ—Ca_x4—Mg_y1a	180.0 (5)
Ca_x2ⁱ—Ca_x1—Fe_y3^iv	152.401 (3)	Ca_x4ⁱⁱ—Ca_x4—Mg_y1aⁱⁱ	0.0 (5)
Ca_x2ⁱ—Ca_x1—Fe_y3^v	58.564 (3)	Si_z3ⁱⁱ—Ca_x4—Si_z3^xxv	176.532 (19)
Ca_x2ⁱ—Ca_x1—Fe_y3^vi	100.434 (3)	Si_z3ⁱⁱ—Ca_x4—Si_z3^xxvi	89.948 (5)
Ca_x2ⁱ—Ca_x1—Fe_y3^vii	56.923 (3)	Si_z3ⁱⁱ—Ca_x4—Si_z3^xxvii	89.948 (5)
Ca_x2ⁱ—Ca_x1—Si_z1	114.6717 (15)	Si_z3ⁱⁱ—Ca_x4—O6ⁱⁱ	31.759 (12)
Ca_x2ⁱ—Ca_x1—Si_z1ⁱⁱ	65.3283 (15)	Si_z3ⁱⁱ—Ca_x4—O6^xxv	145.48 (2)
Ca_x2ⁱ—Ca_x1—O1	81.098 (10)	Si_z3ⁱⁱ—Ca_x4—O6^xxvi	69.959 (13)
Ca_x2ⁱ—Ca_x1—O1ⁱ	148.159 (10)	Si_z3ⁱⁱ—Ca_x4—O6^xxvii	108.440 (14)
Ca_x2ⁱ—Ca_x1—O1ⁱⁱ	41.778 (10)	Si_z3ⁱⁱ—Ca_x4—Fe_y1a	88.266 (10)
Ca_x2ⁱ—Ca_x1—O1ⁱⁱⁱ	92.921 (10)	Si_z3ⁱⁱ—Ca_x4—Fe_y1b	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—Ca_x2ⁱⁱⁱ	130.657 (2)	Si_z3ⁱⁱ—Ca_x4—Mg_y1a	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—Al_y3^iv	56.923 (3)	Si_z3ⁱⁱ—Ca_x4—Mg_y1aⁱⁱ	91.734 (10)
Ca_x2ⁱⁱ—Ca_x1—Al_y3^v	100.434 (3)	Si_z3^xxv—Ca_x4—Si_z3^xxvi	89.948 (5)
Ca_x2ⁱⁱ—Ca_x1—Al_y3^vi	58.564 (3)	Si_z3^xxv—Ca_x4—Si_z3^xxvii	89.948 (5)
Ca_x2ⁱⁱ—Ca_x1—Al_y3^vii	152.401 (3)	Si_z3^xxv—Ca_x4—O6ⁱⁱ	145.48 (2)
Ca_x2ⁱⁱ—Ca_x1—Ti_y3^iv	56.923 (3)	Si_z3^xxv—Ca_x4—O6^xxv	31.759 (12)
Ca_x2ⁱⁱ—Ca_x1—Ti_y3^v	100.434 (3)	Si_z3^xxv—Ca_x4—O6^xxvi	108.440 (14)
Ca_x2ⁱⁱ—Ca_x1—Ti_y3^vi	58.564 (3)	Si_z3^xxv—Ca_x4—O6^xxvii	69.959 (13)
Ca_x2ⁱⁱ—Ca_x1—Ti_y3^vii	152.401 (3)	Si_z3^xxv—Ca_x4—Fe_y1a	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—Fe_y3^iv	56.923 (3)	Si_z3^xxv—Ca_x4—Fe_y1b	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—Fe_y3^v	100.434 (3)	Si_z3^xxv—Ca_x4—Mg_y1a	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—Fe_y3^vi	58.564 (3)	Si_z3^xxv—Ca_x4—Mg_y1aⁱⁱ	91.734 (10)
Ca_x2ⁱⁱ—Ca_x1—Fe_y3^vii	152.401 (3)	Si_z3^xxvi—Ca_x4—Si_z3^xxvii	176.532 (19)
Ca_x2ⁱⁱ—Ca_x1—Si_z1	65.3283 (15)	Si_z3^xxvi—Ca_x4—O6ⁱⁱ	108.440 (14)
Ca_x2ⁱⁱ—Ca_x1—Si_z1ⁱⁱ	114.6717 (15)	Si_z3^xxvi—Ca_x4—O6^xxv	69.959 (13)
Ca_x2ⁱⁱ—Ca_x1—O1	92.921 (10)	Si_z3^xxvi—Ca_x4—O6^xxvi	31.759 (12)
Ca_x2ⁱⁱ—Ca_x1—O1ⁱ	41.778 (10)	Si_z3^xxvi—Ca_x4—O6^xxvii	145.48 (2)
Ca_x2ⁱⁱ—Ca_x1—O1ⁱⁱ	148.159 (10)	Si_z3^xxvi—Ca_x4—Fe_y1a	88.266 (10)
Ca_x2ⁱⁱ—Ca_x1—O1ⁱⁱⁱ	81.098 (10)	Si_z3^xxvi—Ca_x4—Fe_y1b	88.266 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Al_y3^iv	100.434 (3)	Si_z3^xxvi—Ca_x4—Mg_y1a	88.266 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Al_y3^v	56.923 (3)	Si_z3^xxvi—Ca_x4—Mg_y1aⁱⁱ	91.734 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Al_y3^vi	152.401 (3)	Si_z3^xxvii—Ca_x4—O6ⁱⁱ	69.959 (13)
Ca_x2ⁱⁱⁱ—Ca_x1—Al_y3^vii	58.564 (3)	Si_z3^xxvii—Ca_x4—O6^xxv	108.440 (14)
Ca_x2ⁱⁱⁱ—Ca_x1—Ti_y3^iv	100.434 (3)	Si_z3^xxvii—Ca_x4—O6^xxvi	145.48 (2)
Ca_x2ⁱⁱⁱ—Ca_x1—Ti_y3^v	56.923 (3)	Si_z3^xxvii—Ca_x4—O6^xxvii	31.759 (12)
Ca_x2ⁱⁱⁱ—Ca_x1—Ti_y3^vi	152.401 (3)	Si_z3^xxvii—Ca_x4—Fe_y1a	88.266 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Ti_y3^vii	58.564 (3)	Si_z3^xxvii—Ca_x4—Fe_y1b	88.266 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Fe_y3^iv	100.434 (3)	Si_z3^xxvii—Ca_x4—Mg_y1a	88.266 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Fe_y3^v	56.923 (3)	Si_z3^xxvii—Ca_x4—Mg_y1aⁱⁱ	91.734 (10)
Ca_x2ⁱⁱⁱ—Ca_x1—Fe_y3^vi	152.401 (3)	O6ⁱⁱ—Ca_x4—O6^xxv	128.32 (3)
Ca_x2ⁱⁱⁱ—Ca_x1—Fe_y3^vii	58.564 (3)	O6ⁱⁱ—Ca_x4—O6^xxvi	79.049 (19)
Ca_x2ⁱⁱⁱ—Ca_x1—Si_z1	65.3283 (15)	O6ⁱⁱ—Ca_x4—O6^xxvii	79.049 (19)
Ca_x2ⁱⁱⁱ—Ca_x1—Si_z1ⁱⁱ	114.6717 (15)	O6ⁱⁱ—Ca_x4—Fe_y1a	64.160 (16)
Ca_x2ⁱⁱⁱ—Ca_x1—O1	41.778 (10)	O6ⁱⁱ—Ca_x4—Fe_y1b	64.160 (16)
Ca_x2ⁱⁱⁱ—Ca_x1—O1ⁱ	92.921 (10)	O6ⁱⁱ—Ca_x4—Mg_y1a	64.160 (16)
Ca_x2ⁱⁱⁱ—Ca_x1—O1ⁱⁱ	81.098 (10)	O6ⁱⁱ—Ca_x4—Mg_y1aⁱⁱ	115.840 (16)
Ca_x2ⁱⁱⁱ—Ca_x1—O1ⁱⁱⁱ	148.159 (10)	O6^xxv—Ca_x4—O6^xxvi	79.049 (19)
Al_y3^iv—Ca_x1—Al_y3^v	128.199 (3)	O6^xxv—Ca_x4—O6^xxvii	79.049 (19)
Al_y3^iv—Ca_x1—Al_y3^vi	104.452 (4)	O6^xxv—Ca_x4—Fe_y1a	64.160 (16)
Al_y3^iv—Ca_x1—Al_y3^vii	97.588 (4)	O6^xxv—Ca_x4—Fe_y1b	64.160 (16)
Al_y3^iv—Ca_x1—Ti_y3^iv	0.0 (5)	O6^xxv—Ca_x4—Mg_y1a	64.160 (16)
Al_y3^iv—Ca_x1—Ti_y3^v	128.199 (3)	O6^xxv—Ca_x4—Mg_y1aⁱⁱ	115.840 (16)
Al_y3^iv—Ca_x1—Ti_y3^vi	104.452 (4)	O6^xxvi—Ca_x4—O6^xxvii	128.32 (3)
Al_y3^iv—Ca_x1—Ti_y3^vii	97.588 (4)	O6^xxvi—Ca_x4—Fe_y1a	64.160 (16)
Al_y3^iv—Ca_x1—Fe_y3^iv	0.0 (5)	O6^xxvi—Ca_x4—Fe_y1b	64.160 (16)
Al_y3^iv—Ca_x1—Fe_y3^v	128.199 (3)	O6^xxvi—Ca_x4—Mg_y1a	64.160 (16)
Al_y3^iv—Ca_x1—Fe_y3^vi	104.452 (4)	O6^xxvi—Ca_x4—Mg_y1aⁱⁱ	115.840 (16)
Al_y3^iv—Ca_x1—Fe_y3^vii	97.588 (4)	O6^xxvii—Ca_x4—Fe_y1a	64.160 (16)
Al_y3^iv—Ca_x1—Si_z1	64.099 (2)	O6^xxvii—Ca_x4—Fe_y1b	64.160 (16)
Al_y3^iv—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	O6^xxvii—Ca_x4—Mg_y1a	64.160 (16)
Al_y3^iv—Ca_x1—O1	94.896 (10)	O6^xxvii—Ca_x4—Mg_y1aⁱⁱ	115.840 (16)
Al_y3^iv—Ca_x1—O1ⁱ	35.670 (11)	Fe_y1a—Ca_x4—Fe_y1b	0.0 (5)
Al_y3^iv—Ca_x1—O1ⁱⁱ	123.215 (11)	Fe_y1a—Ca_x4—Mg_y1a	0.0 (5)
Al_y3^iv—Ca_x1—O1ⁱⁱⁱ	100.326 (10)	Fe_y1a—Ca_x4—Mg_y1aⁱⁱ	180.0 (5)
Al_y3^v—Ca_x1—Al_y3^vi	97.588 (4)	Fe_y1b—Ca_x4—Mg_y1a	0.0 (5)
Al_y3^v—Ca_x1—Al_y3^vii	104.452 (4)	Fe_y1b—Ca_x4—Mg_y1aⁱⁱ	180.0 (5)
Al_y3^v—Ca_x1—Ti_y3^iv	128.199 (3)	Mg_y1a—Ca_x4—Mg_y1aⁱⁱ	180.0 (5)
Al_y3^v—Ca_x1—Ti_y3^v	0.0 (5)	Ca_x2^xiv—Al_y2—Ca_x2^xxxii	180.0 (5)
Al_y3^v—Ca_x1—Ti_y3^vi	97.588 (4)	Ca_x2^xiv—Al_y2—Ca_x3^xli	63.360 (3)
Al_y3^v—Ca_x1—Ti_y3^vii	104.452 (4)	Ca_x2^xiv—Al_y2—Ca_x3^xxii	116.640 (3)
Al_y3^v—Ca_x1—Fe_y3^iv	128.199 (3)	Ca_x2^xiv—Al_y2—Mg_y2	0
Al_y3^v—Ca_x1—Fe_y3^v	0.0 (5)	Ca_x2^xiv—Al_y2—Al_y3	117.333 (3)
Al_y3^v—Ca_x1—Fe_y3^vi	97.588 (4)	Ca_x2^xiv—Al_y2—Al_y3^xxviii	62.667 (3)
Al_y3^v—Ca_x1—Fe_y3^vii	104.452 (4)	Ca_x2^xiv—Al_y2—Ti_y3	117.333 (3)
Al_y3^v—Ca_x1—Si_z1	64.099 (2)	Ca_x2^xiv—Al_y2—Ti_y3^xxviii	62.667 (3)
Al_y3^v—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x2^xxxii—Al_y2—Ca_x3^xli	116.640 (3)
Al_y3^v—Ca_x1—O1	35.670 (11)	Ca_x2^xxxii—Al_y2—Ca_x3^xxii	63.360 (3)
Al_y3^v—Ca_x1—O1ⁱ	94.896 (10)	Ca_x2^xxxii—Al_y2—Mg_y2	0
Al_y3^v—Ca_x1—O1ⁱⁱ	100.326 (10)	Ca_x2^xxxii—Al_y2—Al_y3	62.667 (3)
Al_y3^v—Ca_x1—O1ⁱⁱⁱ	123.215 (11)	Ca_x2^xxxii—Al_y2—Al_y3^xxviii	117.333 (3)
Al_y3^vi—Ca_x1—Al_y3^vii	128.199 (3)	Ca_x2^xxxii—Al_y2—Ti_y3	62.667 (3)
Al_y3^vi—Ca_x1—Ti_y3^iv	104.452 (4)	Ca_x2^xxxii—Al_y2—Ti_y3^xxviii	117.333 (3)
Al_y3^vi—Ca_x1—Ti_y3^v	97.588 (4)	Ca_x3^xli—Al_y2—Ca_x3^xxii	180.0 (5)
Al_y3^vi—Ca_x1—Ti_y3^vi	0.0 (5)	Ca_x3^xli—Al_y2—Mg_y2	0
Al_y3^vi—Ca_x1—Ti_y3^vii	128.199 (3)	Ca_x3^xli—Al_y2—Al_y3	116.325 (4)
Al_y3^vi—Ca_x1—Fe_y3^iv	104.452 (4)	Ca_x3^xli—Al_y2—Al_y3^xxviii	63.675 (4)
Al_y3^vi—Ca_x1—Fe_y3^v	97.588 (4)	Ca_x3^xli—Al_y2—Ti_y3	116.325 (4)
Al_y3^vi—Ca_x1—Fe_y3^vi	0.0 (5)	Ca_x3^xli—Al_y2—Ti_y3^xxviii	63.675 (4)
Al_y3^vi—Ca_x1—Fe_y3^vii	128.199 (3)	Ca_x3^xxii—Al_y2—Mg_y2	0
Al_y3^vi—Ca_x1—Si_z1	115.901 (2)	Ca_x3^xxii—Al_y2—Al_y3	63.675 (4)
Al_y3^vi—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x3^xxii—Al_y2—Al_y3^xxviii	116.325 (4)
Al_y3^vi—Ca_x1—O1	123.215 (11)	Ca_x3^xxii—Al_y2—Ti_y3	63.675 (4)
Al_y3^vi—Ca_x1—O1ⁱ	100.326 (10)	Ca_x3^xxii—Al_y2—Ti_y3^xxviii	116.325 (4)
Al_y3^vi—Ca_x1—O1ⁱⁱ	94.896 (10)	Mg_y2—Al_y2—Al_y3	0
Al_y3^vi—Ca_x1—O1ⁱⁱⁱ	35.670 (11)	Mg_y2—Al_y2—Al_y3^xxviii	0
Al_y3^vii—Ca_x1—Ti_y3^iv	97.588 (4)	Mg_y2—Al_y2—Ti_y3	0
Al_y3^vii—Ca_x1—Ti_y3^v	104.452 (4)	Mg_y2—Al_y2—Ti_y3^xxviii	0
Al_y3^vii—Ca_x1—Ti_y3^vi	128.199 (3)	Al_y3—Al_y2—Al_y3^xxviii	180.0 (5)
Al_y3^vii—Ca_x1—Ti_y3^vii	0.0 (5)	Al_y3—Al_y2—Ti_y3	0.0 (5)
Al_y3^vii—Ca_x1—Fe_y3^iv	97.588 (4)	Al_y3—Al_y2—Ti_y3^xxviii	180.0 (5)
Al_y3^vii—Ca_x1—Fe_y3^v	104.452 (4)	Al_y3^xxviii—Al_y2—Ti_y3	180.0 (5)
Al_y3^vii—Ca_x1—Fe_y3^vi	128.199 (3)	Al_y3^xxviii—Al_y2—Ti_y3^xxviii	0.0 (5)
Al_y3^vii—Ca_x1—Fe_y3^vii	0.0 (5)	Ti_y3—Al_y2—Ti_y3^xxviii	180.0 (5)
Al_y3^vii—Ca_x1—Si_z1	115.901 (2)	Ca_x2^xiv—Mg_y2—Ca_x2^xxxii	180.0 (5)
Al_y3^vii—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x2^xiv—Mg_y2—Ca_x3^xli	63.360 (3)
Al_y3^vii—Ca_x1—O1	100.326 (10)	Ca_x2^xiv—Mg_y2—Ca_x3^xxii	116.640 (3)
Al_y3^vii—Ca_x1—O1ⁱ	123.215 (11)	Ca_x2^xiv—Mg_y2—Al_y2	0
Al_y3^vii—Ca_x1—O1ⁱⁱ	35.670 (11)	Ca_x2^xiv—Mg_y2—Al_y3	117.333 (3)
Al_y3^vii—Ca_x1—O1ⁱⁱⁱ	94.896 (10)	Ca_x2^xiv—Mg_y2—Al_y3^xxviii	62.667 (3)
Ti_y3^iv—Ca_x1—Ti_y3^v	128.199 (3)	Ca_x2^xiv—Mg_y2—Ti_y3	117.333 (3)
Ti_y3^iv—Ca_x1—Ti_y3^vi	104.452 (4)	Ca_x2^xiv—Mg_y2—Ti_y3^xxviii	62.667 (3)
Ti_y3^iv—Ca_x1—Ti_y3^vii	97.588 (4)	Ca_x2^xiv—Mg_y2—Fe_y3	117.333 (3)
Ti_y3^iv—Ca_x1—Fe_y3^iv	0.0 (5)	Ca_x2^xiv—Mg_y2—Fe_y3^xxviii	62.667 (3)
Ti_y3^iv—Ca_x1—Fe_y3^v	128.199 (3)	Ca_x2^xiv—Mg_y2—O4^xxix	133.258 (12)
Ti_y3^iv—Ca_x1—Fe_y3^vi	104.452 (4)	Ca_x2^xiv—Mg_y2—O4^xxx	46.742 (12)
Ti_y3^iv—Ca_x1—Fe_y3^vii	97.588 (4)	Ca_x2^xiv—Mg_y2—O8^xxxi	42.225 (12)
Ti_y3^iv—Ca_x1—Si_z1	64.099 (2)	Ca_x2^xiv—Mg_y2—O8^xi	137.775 (12)
Ti_y3^iv—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x2^xiv—Mg_y2—O11	84.132 (13)
Ti_y3^iv—Ca_x1—O1	94.896 (10)	Ca_x2^xiv—Mg_y2—O11^xxviii	95.868 (13)
Ti_y3^iv—Ca_x1—O1ⁱ	35.670 (11)	Ca_x2^xxxii—Mg_y2—Ca_x3^xli	116.640 (3)
Ti_y3^iv—Ca_x1—O1ⁱⁱ	123.215 (11)	Ca_x2^xxxii—Mg_y2—Ca_x3^xxii	63.360 (3)
Ti_y3^iv—Ca_x1—O1ⁱⁱⁱ	100.326 (10)	Ca_x2^xxxii—Mg_y2—Al_y2	0
Ti_y3^v—Ca_x1—Ti_y3^vi	97.588 (4)	Ca_x2^xxxii—Mg_y2—Al_y3	62.667 (3)
Ti_y3^v—Ca_x1—Ti_y3^vii	104.452 (4)	Ca_x2^xxxii—Mg_y2—Al_y3^xxviii	117.333 (3)
Ti_y3^v—Ca_x1—Fe_y3^iv	128.199 (3)	Ca_x2^xxxii—Mg_y2—Ti_y3	62.667 (3)
Ti_y3^v—Ca_x1—Fe_y3^v	0.0 (5)	Ca_x2^xxxii—Mg_y2—Ti_y3^xxviii	117.333 (3)
Ti_y3^v—Ca_x1—Fe_y3^vi	97.588 (4)	Ca_x2^xxxii—Mg_y2—Fe_y3	62.667 (3)
Ti_y3^v—Ca_x1—Fe_y3^vii	104.452 (4)	Ca_x2^xxxii—Mg_y2—Fe_y3^xxviii	117.333 (3)
Ti_y3^v—Ca_x1—Si_z1	64.099 (2)	Ca_x2^xxxii—Mg_y2—O4^xxix	46.742 (12)
Ti_y3^v—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x2^xxxii—Mg_y2—O4^xxx	133.258 (12)
Ti_y3^v—Ca_x1—O1	35.670 (11)	Ca_x2^xxxii—Mg_y2—O8^xxxi	137.775 (12)
Ti_y3^v—Ca_x1—O1ⁱ	94.896 (10)	Ca_x2^xxxii—Mg_y2—O8^xi	42.225 (12)
Ti_y3^v—Ca_x1—O1ⁱⁱ	100.326 (10)	Ca_x2^xxxii—Mg_y2—O11	95.868 (13)
Ti_y3^v—Ca_x1—O1ⁱⁱⁱ	123.215 (11)	Ca_x2^xxxii—Mg_y2—O11^xxviii	84.132 (13)
Ti_y3^vi—Ca_x1—Ti_y3^vii	128.199 (3)	Ca_x3^xli—Mg_y2—Ca_x3^xxii	180.0 (5)
Ti_y3^vi—Ca_x1—Fe_y3^iv	104.452 (4)	Ca_x3^xli—Mg_y2—Al_y2	0
Ti_y3^vi—Ca_x1—Fe_y3^v	97.588 (4)	Ca_x3^xli—Mg_y2—Al_y3	116.325 (4)
Ti_y3^vi—Ca_x1—Fe_y3^vi	0.0 (5)	Ca_x3^xli—Mg_y2—Al_y3^xxviii	63.675 (4)
Ti_y3^vi—Ca_x1—Fe_y3^vii	128.199 (3)	Ca_x3^xli—Mg_y2—Ti_y3	116.325 (4)
Ti_y3^vi—Ca_x1—Si_z1	115.901 (2)	Ca_x3^xli—Mg_y2—Ti_y3^xxviii	63.675 (4)
Ti_y3^vi—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x3^xli—Mg_y2—Fe_y3	116.325 (4)
Ti_y3^vi—Ca_x1—O1	123.215 (11)	Ca_x3^xli—Mg_y2—Fe_y3^xxviii	63.675 (4)
Ti_y3^vi—Ca_x1—O1ⁱ	100.326 (10)	Ca_x3^xli—Mg_y2—O4^xxix	86.333 (12)
Ti_y3^vi—Ca_x1—O1ⁱⁱ	94.896 (10)	Ca_x3^xli—Mg_y2—O4^xxx	93.667 (12)
Ti_y3^vi—Ca_x1—O1ⁱⁱⁱ	35.670 (11)	Ca_x3^xli—Mg_y2—O8^xxxi	47.944 (12)
Ti_y3^vii—Ca_x1—Fe_y3^iv	97.588 (4)	Ca_x3^xli—Mg_y2—O8^xi	132.056 (12)
Ti_y3^vii—Ca_x1—Fe_y3^v	104.452 (4)	Ca_x3^xli—Mg_y2—O11	42.986 (13)
Ti_y3^vii—Ca_x1—Fe_y3^vi	128.199 (3)	Ca_x3^xli—Mg_y2—O11^xxviii	137.014 (13)
Ti_y3^vii—Ca_x1—Fe_y3^vii	0.0 (5)	Ca_x3^xxii—Mg_y2—Al_y2	0
Ti_y3^vii—Ca_x1—Si_z1	115.901 (2)	Ca_x3^xxii—Mg_y2—Al_y3	63.675 (4)
Ti_y3^vii—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x3^xxii—Mg_y2—Al_y3^xxviii	116.325 (4)
Ti_y3^vii—Ca_x1—O1	100.326 (10)	Ca_x3^xxii—Mg_y2—Ti_y3	63.675 (4)
Ti_y3^vii—Ca_x1—O1ⁱ	123.215 (11)	Ca_x3^xxii—Mg_y2—Ti_y3^xxviii	116.325 (4)
Ti_y3^vii—Ca_x1—O1ⁱⁱ	35.670 (11)	Ca_x3^xxii—Mg_y2—Fe_y3	63.675 (4)
Ti_y3^vii—Ca_x1—O1ⁱⁱⁱ	94.896 (10)	Ca_x3^xxii—Mg_y2—Fe_y3^xxviii	116.325 (4)
Fe_y3^iv—Ca_x1—Fe_y3^v	128.199 (3)	Ca_x3^xxii—Mg_y2—O4^xxix	93.667 (12)
Fe_y3^iv—Ca_x1—Fe_y3^vi	104.452 (4)	Ca_x3^xxii—Mg_y2—O4^xxx	86.333 (12)
Fe_y3^iv—Ca_x1—Fe_y3^vii	97.588 (4)	Ca_x3^xxii—Mg_y2—O8^xxxi	132.056 (12)
Fe_y3^iv—Ca_x1—Si_z1	64.099 (2)	Ca_x3^xxii—Mg_y2—O8^xi	47.944 (12)
Fe_y3^iv—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x3^xxii—Mg_y2—O11	137.014 (13)
Fe_y3^iv—Ca_x1—O1	94.896 (10)	Ca_x3^xxii—Mg_y2—O11^xxviii	42.986 (13)
Fe_y3^iv—Ca_x1—O1ⁱ	35.670 (11)	Al_y2—Mg_y2—Al_y3	0
Fe_y3^iv—Ca_x1—O1ⁱⁱ	123.215 (11)	Al_y2—Mg_y2—Al_y3^xxviii	0
Fe_y3^iv—Ca_x1—O1ⁱⁱⁱ	100.326 (10)	Al_y2—Mg_y2—Ti_y3	0
Fe_y3^v—Ca_x1—Fe_y3^vi	97.588 (4)	Al_y2—Mg_y2—Ti_y3^xxviii	0
Fe_y3^v—Ca_x1—Fe_y3^vii	104.452 (4)	Al_y2—Mg_y2—Fe_y3	0
Fe_y3^v—Ca_x1—Si_z1	64.099 (2)	Al_y2—Mg_y2—Fe_y3^xxviii	0
Fe_y3^v—Ca_x1—Si_z1ⁱⁱ	115.901 (2)	Al_y2—Mg_y2—O4^xxix	0
Fe_y3^v—Ca_x1—O1	35.670 (11)	Al_y2—Mg_y2—O4^xxx	0
Fe_y3^v—Ca_x1—O1ⁱ	94.896 (10)	Al_y2—Mg_y2—O8^xxxi	0
Fe_y3^v—Ca_x1—O1ⁱⁱ	100.326 (10)	Al_y2—Mg_y2—O8^xi	0
Fe_y3^v—Ca_x1—O1ⁱⁱⁱ	123.215 (11)	Al_y2—Mg_y2—O11	0
Fe_y3^vi—Ca_x1—Fe_y3^vii	128.199 (3)	Al_y2—Mg_y2—O11^xxviii	0
Fe_y3^vi—Ca_x1—Si_z1	115.901 (2)	Al_y3—Mg_y2—Al_y3^xxviii	180.0 (5)
Fe_y3^vi—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Al_y3—Mg_y2—Ti_y3	0.0 (5)
Fe_y3^vi—Ca_x1—O1	123.215 (11)	Al_y3—Mg_y2—Ti_y3^xxviii	180.0 (5)
Fe_y3^vi—Ca_x1—O1ⁱ	100.326 (10)	Al_y3—Mg_y2—Fe_y3	0.0 (5)
Fe_y3^vi—Ca_x1—O1ⁱⁱ	94.896 (10)	Al_y3—Mg_y2—Fe_y3^xxviii	180.0 (5)
Fe_y3^vi—Ca_x1—O1ⁱⁱⁱ	35.670 (11)	Al_y3—Mg_y2—O4^xxix	44.654 (12)
Fe_y3^vii—Ca_x1—Si_z1	115.901 (2)	Al_y3—Mg_y2—O4^xxx	135.346 (12)
Fe_y3^vii—Ca_x1—Si_z1ⁱⁱ	64.099 (2)	Al_y3—Mg_y2—O8^xxxi	88.248 (12)
Fe_y3^vii—Ca_x1—O1	100.326 (10)	Al_y3—Mg_y2—O8^xi	91.752 (12)
Fe_y3^vii—Ca_x1—O1ⁱ	123.215 (11)	Al_y3—Mg_y2—O11	141.969 (13)
Fe_y3^vii—Ca_x1—O1ⁱⁱ	35.670 (11)	Al_y3—Mg_y2—O11^xxviii	38.031 (13)
Fe_y3^vii—Ca_x1—O1ⁱⁱⁱ	94.896 (10)	Al_y3^xxviii—Mg_y2—Ti_y3	180.0 (5)
Si_z1—Ca_x1—Si_z1ⁱⁱ	180.0 (5)	Al_y3^xxviii—Mg_y2—Ti_y3^xxviii	0.0 (5)
Si_z1—Ca_x1—O1	33.673 (10)	Al_y3^xxviii—Mg_y2—Fe_y3	180.0 (5)
Si_z1—Ca_x1—O1ⁱ	33.673 (10)	Al_y3^xxviii—Mg_y2—Fe_y3^xxviii	0.0 (5)
Si_z1—Ca_x1—O1ⁱⁱ	146.327 (10)	Al_y3^xxviii—Mg_y2—O4^xxix	135.346 (12)
Si_z1—Ca_x1—O1ⁱⁱⁱ	146.327 (10)	Al_y3^xxviii—Mg_y2—O4^xxx	44.654 (12)
Si_z1ⁱⁱ—Ca_x1—O1	146.327 (10)	Al_y3^xxviii—Mg_y2—O8^xxxi	91.752 (12)
Si_z1ⁱⁱ—Ca_x1—O1ⁱ	146.327 (10)	Al_y3^xxviii—Mg_y2—O8^xi	88.248 (12)
Si_z1ⁱⁱ—Ca_x1—O1ⁱⁱ	33.673 (10)	Al_y3^xxviii—Mg_y2—O11	38.031 (13)
Si_z1ⁱⁱ—Ca_x1—O1ⁱⁱⁱ	33.673 (10)	Al_y3^xxviii—Mg_y2—O11^xxviii	141.969 (13)
O1—Ca_x1—O1ⁱ	67.345 (14)	Ti_y3—Mg_y2—Ti_y3^xxviii	180.0 (5)
O1—Ca_x1—O1ⁱⁱ	117.765 (14)	Ti_y3—Mg_y2—Fe_y3	0.0 (5)
O1—Ca_x1—O1ⁱⁱⁱ	156.829 (15)	Ti_y3—Mg_y2—Fe_y3^xxviii	180.0 (5)
O1ⁱ—Ca_x1—O1ⁱⁱ	156.829 (15)	Ti_y3—Mg_y2—O4^xxix	44.654 (12)
O1ⁱ—Ca_x1—O1ⁱⁱⁱ	117.765 (14)	Ti_y3—Mg_y2—O4^xxx	135.346 (12)
O1ⁱⁱ—Ca_x1—O1ⁱⁱⁱ	67.345 (14)	Ti_y3—Mg_y2—O8^xxxi	88.248 (12)
Ca_x1—Na_x1—Ca_x2	0	Ti_y3—Mg_y2—O8^xi	91.752 (12)
Ca_x1—Na_x1—Ca_x2ⁱ	0	Ti_y3—Mg_y2—O11	141.969 (13)
Ca_x1—Na_x1—Ca_x2ⁱⁱ	0	Ti_y3—Mg_y2—O11^xxviii	38.031 (13)
Ca_x1—Na_x1—Ca_x2ⁱⁱⁱ	0	Ti_y3^xxviii—Mg_y2—Fe_y3	180.0 (5)
Ca_x1—Na_x1—Al_y3^iv	0	Ti_y3^xxviii—Mg_y2—Fe_y3^xxviii	0.0 (5)
Ca_x1—Na_x1—Al_y3^v	0	Ti_y3^xxviii—Mg_y2—O4^xxix	135.346 (12)
Ca_x1—Na_x1—Al_y3^vi	0	Ti_y3^xxviii—Mg_y2—O4^xxx	44.654 (12)
Ca_x1—Na_x1—Al_y3^vii	0	Ti_y3^xxviii—Mg_y2—O8^xxxi	91.752 (12)
Ca_x1—Na_x1—Ti_y3^iv	0	Ti_y3^xxviii—Mg_y2—O8^xi	88.248 (12)
Ca_x1—Na_x1—Ti_y3^v	0	Ti_y3^xxviii—Mg_y2—O11	38.031 (13)
Ca_x1—Na_x1—Ti_y3^vi	0	Ti_y3^xxviii—Mg_y2—O11^xxviii	141.969 (13)
Ca_x1—Na_x1—Ti_y3^vii	0	Fe_y3—Mg_y2—Fe_y3^xxviii	180.0 (5)
Ca_x1—Na_x1—Fe_y3^iv	0	Fe_y3—Mg_y2—O4^xxix	44.654 (12)
Ca_x1—Na_x1—Fe_y3^v	0	Fe_y3—Mg_y2—O4^xxx	135.346 (12)
Ca_x1—Na_x1—Fe_y3^vi	0	Fe_y3—Mg_y2—O8^xxxi	88.248 (12)
Ca_x1—Na_x1—Fe_y3^vii	0	Fe_y3—Mg_y2—O8^xi	91.752 (12)
Ca_x1—Na_x1—Si_z1	0	Fe_y3—Mg_y2—O11	141.969 (13)
Ca_x1—Na_x1—Si_z1ⁱⁱ	0	Fe_y3—Mg_y2—O11^xxviii	38.031 (13)
Ca_x1—Na_x1—O1	0	Fe_y3^xxviii—Mg_y2—O4^xxix	135.346 (12)
Ca_x1—Na_x1—O1ⁱ	0	Fe_y3^xxviii—Mg_y2—O4^xxx	44.654 (12)
Ca_x1—Na_x1—O1ⁱⁱ	0	Fe_y3^xxviii—Mg_y2—O8^xxxi	91.752 (12)
Ca_x1—Na_x1—O1ⁱⁱⁱ	0	Fe_y3^xxviii—Mg_y2—O8^xi	88.248 (12)
Ca_x2—Na_x1—Ca_x2ⁱ	130.657 (2)	Fe_y3^xxviii—Mg_y2—O11	38.031 (13)
Ca_x2—Na_x1—Ca_x2ⁱⁱ	58.803 (2)	Fe_y3^xxviii—Mg_y2—O11^xxviii	141.969 (13)
Ca_x2—Na_x1—Ca_x2ⁱⁱⁱ	150.050 (2)	O4^xxix—Mg_y2—O4^xxx	180.0 (5)
Ca_x2—Na_x1—Al_y3^iv	58.564 (3)	O4^xxix—Mg_y2—O8^xxxi	91.035 (17)
Ca_x2—Na_x1—Al_y3^v	152.401 (3)	O4^xxix—Mg_y2—O8^xi	88.965 (17)
Ca_x2—Na_x1—Al_y3^vi	56.923 (3)	O4^xxix—Mg_y2—O11	97.489 (17)
Ca_x2—Na_x1—Al_y3^vii	100.434 (3)	O4^xxix—Mg_y2—O11^xxviii	82.511 (17)
Ca_x2—Na_x1—Ti_y3^iv	58.564 (3)	O4^xxx—Mg_y2—O8^xxxi	88.965 (17)
Ca_x2—Na_x1—Ti_y3^v	152.401 (3)	O4^xxx—Mg_y2—O8^xi	91.035 (17)
Ca_x2—Na_x1—Ti_y3^vi	56.923 (3)	O4^xxx—Mg_y2—O11	82.511 (17)
Ca_x2—Na_x1—Ti_y3^vii	100.434 (3)	O4^xxx—Mg_y2—O11^xxviii	97.489 (17)
Ca_x2—Na_x1—Fe_y3^iv	58.564 (3)	O8^xxxi—Mg_y2—O8^xi	180.0 (5)
Ca_x2—Na_x1—Fe_y3^v	152.401 (3)	O8^xxxi—Mg_y2—O11	89.215 (18)
Ca_x2—Na_x1—Fe_y3^vi	56.923 (3)	O8^xxxi—Mg_y2—O11^xxviii	90.785 (18)
Ca_x2—Na_x1—Fe_y3^vii	100.434 (3)	O8^xi—Mg_y2—O11	90.785 (18)
Ca_x2—Na_x1—Si_z1	114.6717 (15)	O8^xi—Mg_y2—O11^xxviii	89.215 (18)
Ca_x2—Na_x1—Si_z1ⁱⁱ	65.3283 (15)	O11—Mg_y2—O11^xxviii	180.0 (5)
Ca_x2—Na_x1—O1	148.159 (10)	Ca_x1^xlii—Al_y3—Na_x1^xlii	0.0 (5)
Ca_x2—Na_x1—O1ⁱ	81.098 (10)	Ca_x1^xlii—Al_y3—Ca_x2^xlii	66.103 (3)
Ca_x2—Na_x1—O1ⁱⁱ	92.921 (10)	Ca_x1^xlii—Al_y3—Ca_x2^vi	67.108 (3)
Ca_x2—Na_x1—O1ⁱⁱⁱ	41.778 (10)	Ca_x1^xlii—Al_y3—Ca_x2^xxxii	113.268 (5)
Ca_x2ⁱ—Na_x1—Ca_x2ⁱⁱ	150.050 (2)	Ca_x1^xlii—Al_y3—Ca_x3^xxii	119.384 (5)
Ca_x2ⁱ—Na_x1—Ca_x2ⁱⁱⁱ	58.803 (2)	Ca_x1^xlii—Al_y3—Al_y2	173.672 (5)
Ca_x2ⁱ—Na_x1—Al_y3^iv	152.401 (3)	Ca_x1^xlii—Al_y3—Mg_y2	173.672 (5)
Ca_x2ⁱ—Na_x1—Al_y3^v	58.564 (3)	Ca_x1^xlii—Al_y3—Ti_y3	0
Ca_x2ⁱ—Na_x1—Al_y3^vi	100.434 (3)	Ca_x1^xlii—Al_y3—Fe_y3	0
Ca_x2ⁱ—Na_x1—Al_y3^vii	56.923 (3)	Na_x1^xlii—Al_y3—Ca_x2^xlii	66.103 (3)
Ca_x2ⁱ—Na_x1—Ti_y3^iv	152.401 (3)	Na_x1^xlii—Al_y3—Ca_x2^vi	67.108 (3)
Ca_x2ⁱ—Na_x1—Ti_y3^v	58.564 (3)	Na_x1^xlii—Al_y3—Ca_x2^xxxii	113.268 (5)
Ca_x2ⁱ—Na_x1—Ti_y3^vi	100.434 (3)	Na_x1^xlii—Al_y3—Ca_x3^xxii	119.384 (5)
Ca_x2ⁱ—Na_x1—Ti_y3^vii	56.923 (3)	Na_x1^xlii—Al_y3—Al_y2	173.672 (5)
Ca_x2ⁱ—Na_x1—Fe_y3^iv	152.401 (3)	Na_x1^xlii—Al_y3—Mg_y2	173.672 (5)
Ca_x2ⁱ—Na_x1—Fe_y3^v	58.564 (3)	Na_x1^xlii—Al_y3—Ti_y3	0
Ca_x2ⁱ—Na_x1—Fe_y3^vi	100.434 (3)	Na_x1^xlii—Al_y3—Fe_y3	0
Ca_x2ⁱ—Na_x1—Fe_y3^vii	56.923 (3)	Ca_x2^xlii—Al_y3—Ca_x2^vi	64.375 (4)
Ca_x2ⁱ—Na_x1—Si_z1	114.6717 (15)	Ca_x2^xlii—Al_y3—Ca_x2^xxxii	176.707 (6)
Ca_x2ⁱ—Na_x1—Si_z1ⁱⁱ	65.3283 (15)	Ca_x2^xlii—Al_y3—Ca_x3^xxii	118.784 (5)
Ca_x2ⁱ—Na_x1—O1	81.098 (10)	Ca_x2^xlii—Al_y3—Al_y2	115.858 (5)
Ca_x2ⁱ—Na_x1—O1ⁱ	148.159 (10)	Ca_x2^xlii—Al_y3—Mg_y2	115.858 (5)
Ca_x2ⁱ—Na_x1—O1ⁱⁱ	41.778 (10)	Ca_x2^xlii—Al_y3—Ti_y3	0
Ca_x2ⁱ—Na_x1—O1ⁱⁱⁱ	92.921 (10)	Ca_x2^xlii—Al_y3—Fe_y3	0
Ca_x2ⁱⁱ—Na_x1—Ca_x2ⁱⁱⁱ	130.657 (2)	Ca_x2^vi—Al_y3—Ca_x2^xxxii	112.343 (5)
Ca_x2ⁱⁱ—Na_x1—Al_y3^iv	56.923 (3)	Ca_x2^vi—Al_y3—Ca_x3^xxii	173.323 (6)
Ca_x2ⁱⁱ—Na_x1—Al_y3^v	100.434 (3)	Ca_x2^vi—Al_y3—Al_y2	107.887 (5)
Ca_x2ⁱⁱ—Na_x1—Al_y3^vi	58.564 (3)	Ca_x2^vi—Al_y3—Mg_y2	107.887 (5)
Ca_x2ⁱⁱ—Na_x1—Al_y3^vii	152.401 (3)	Ca_x2^vi—Al_y3—Ti_y3	0
Ca_x2ⁱⁱ—Na_x1—Ti_y3^iv	56.923 (3)	Ca_x2^vi—Al_y3—Fe_y3	0
Ca_x2ⁱⁱ—Na_x1—Ti_y3^v	100.434 (3)	Ca_x2^xxxii—Al_y3—Ca_x3^xxii	64.447 (4)
Ca_x2ⁱⁱ—Na_x1—Ti_y3^vi	58.564 (3)	Ca_x2^xxxii—Al_y3—Al_y2	64.398 (3)
Ca_x2ⁱⁱ—Na_x1—Ti_y3^vii	152.401 (3)	Ca_x2^xxxii—Al_y3—Mg_y2	64.398 (3)
Ca_x2ⁱⁱ—Na_x1—Fe_y3^iv	56.923 (3)	Ca_x2^xxxii—Al_y3—Ti_y3	0
Ca_x2ⁱⁱ—Na_x1—Fe_y3^v	100.434 (3)	Ca_x2^xxxii—Al_y3—Fe_y3	0
Ca_x2ⁱⁱ—Na_x1—Fe_y3^vi	58.564 (3)	Ca_x3^xxii—Al_y3—Al_y2	65.522 (4)
Ca_x2ⁱⁱ—Na_x1—Fe_y3^vii	152.401 (3)	Ca_x3^xxii—Al_y3—Mg_y2	65.522 (4)
Ca_x2ⁱⁱ—Na_x1—Si_z1	65.3283 (15)	Ca_x3^xxii—Al_y3—Ti_y3	0
Ca_x2ⁱⁱ—Na_x1—Si_z1ⁱⁱ	114.6717 (15)	Ca_x3^xxii—Al_y3—Fe_y3	0
Ca_x2ⁱⁱ—Na_x1—O1	92.921 (10)	Al_y2—Al_y3—Mg_y2	0.0 (5)
Ca_x2ⁱⁱ—Na_x1—O1ⁱ	41.778 (10)	Al_y2—Al_y3—Ti_y3	0
Ca_x2ⁱⁱ—Na_x1—O1ⁱⁱ	148.159 (10)	Al_y2—Al_y3—Fe_y3	0
Ca_x2ⁱⁱ—Na_x1—O1ⁱⁱⁱ	81.098 (10)	Mg_y2—Al_y3—Ti_y3	0
Ca_x2ⁱⁱⁱ—Na_x1—Al_y3^iv	100.434 (3)	Mg_y2—Al_y3—Fe_y3	0
Ca_x2ⁱⁱⁱ—Na_x1—Al_y3^v	56.923 (3)	Ti_y3—Al_y3—Fe_y3	0
Ca_x2ⁱⁱⁱ—Na_x1—Al_y3^vi	152.401 (3)	Ca_x1^xlii—Ti_y3—Na_x1^xlii	0.0 (5)
Ca_x2ⁱⁱⁱ—Na_x1—Al_y3^vii	58.564 (3)	Ca_x1^xlii—Ti_y3—Ca_x2^xlii	66.103 (3)
Ca_x2ⁱⁱⁱ—Na_x1—Ti_y3^iv	100.434 (3)	Ca_x1^xlii—Ti_y3—Ca_x2^vi	67.108 (3)
Ca_x2ⁱⁱⁱ—Na_x1—Ti_y3^v	56.923 (3)	Ca_x1^xlii—Ti_y3—Ca_x2^xxxii	113.268 (5)
Ca_x2ⁱⁱⁱ—Na_x1—Ti_y3^vi	152.401 (3)	Ca_x1^xlii—Ti_y3—Ca_x3^xxii	119.384 (5)
Ca_x2ⁱⁱⁱ—Na_x1—Ti_y3^vii	58.564 (3)	Ca_x1^xlii—Ti_y3—Al_y2	173.672 (5)
Ca_x2ⁱⁱⁱ—Na_x1—Fe_y3^iv	100.434 (3)	Ca_x1^xlii—Ti_y3—Mg_y2	173.672 (5)
Ca_x2ⁱⁱⁱ—Na_x1—Fe_y3^v	56.923 (3)	Ca_x1^xlii—Ti_y3—Al_y3	0
Ca_x2ⁱⁱⁱ—Na_x1—Fe_y3^vi	152.401 (3)	Ca_x1^xlii—Ti_y3—Fe_y3	0
Ca_x2ⁱⁱⁱ—Na_x1—Fe_y3^vii	58.564 (3)	Ca_x1^xlii—Ti_y3—O1^v	44.532 (12)
Ca_x2ⁱⁱⁱ—Na_x1—Si_z1	65.3283 (15)	Ca_x1^xlii—Ti_y3—O2^xxxii	50.388 (14)
Ca_x2ⁱⁱⁱ—Na_x1—Si_z1ⁱⁱ	114.6717 (15)	Ca_x1^xlii—Ti_y3—O3^xxxiii	88.252 (13)
Ca_x2ⁱⁱⁱ—Na_x1—O1	41.778 (10)	Ca_x1^xlii—Ti_y3—O4^xxix	133.010 (12)
Ca_x2ⁱⁱⁱ—Na_x1—O1ⁱ	92.921 (10)	Ca_x1^xlii—Ti_y3—O5^xxxi	93.810 (14)
Ca_x2ⁱⁱⁱ—Na_x1—O1ⁱⁱ	81.098 (10)	Ca_x1^xlii—Ti_y3—O11^xxviii	148.240 (14)
Ca_x2ⁱⁱⁱ—Na_x1—O1ⁱⁱⁱ	148.159 (10)	Na_x1^xlii—Ti_y3—Ca_x2^xlii	66.103 (3)
Al_y3^iv—Na_x1—Al_y3^v	128.199 (3)	Na_x1^xlii—Ti_y3—Ca_x2^vi	67.108 (3)
Al_y3^iv—Na_x1—Al_y3^vi	104.452 (4)	Na_x1^xlii—Ti_y3—Ca_x2^xxxii	113.268 (5)
Al_y3^iv—Na_x1—Al_y3^vii	97.588 (4)	Na_x1^xlii—Ti_y3—Ca_x3^xxii	119.384 (5)
Al_y3^iv—Na_x1—Ti_y3^iv	0.0 (5)	Na_x1^xlii—Ti_y3—Al_y2	173.672 (5)
Al_y3^iv—Na_x1—Ti_y3^v	128.199 (3)	Na_x1^xlii—Ti_y3—Mg_y2	173.672 (5)
Al_y3^iv—Na_x1—Ti_y3^vi	104.452 (4)	Na_x1^xlii—Ti_y3—Al_y3	0
Al_y3^iv—Na_x1—Ti_y3^vii	97.588 (4)	Na_x1^xlii—Ti_y3—Fe_y3	0
Al_y3^iv—Na_x1—Fe_y3^iv	0.0 (5)	Na_x1^xlii—Ti_y3—O1^v	44.532 (12)
Al_y3^iv—Na_x1—Fe_y3^v	128.199 (3)	Na_x1^xlii—Ti_y3—O2^xxxii	50.388 (14)
Al_y3^iv—Na_x1—Fe_y3^vi	104.452 (4)	Na_x1^xlii—Ti_y3—O3^xxxiii	88.252 (13)
Al_y3^iv—Na_x1—Fe_y3^vii	97.588 (4)	Na_x1^xlii—Ti_y3—O4^xxix	133.010 (12)
Al_y3^iv—Na_x1—Si_z1	64.099 (2)	Na_x1^xlii—Ti_y3—O5^xxxi	93.810 (14)
Al_y3^iv—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Na_x1^xlii—Ti_y3—O11^xxviii	148.240 (14)
Al_y3^iv—Na_x1—O1	94.896 (10)	Ca_x2^xlii—Ti_y3—Ca_x2^vi	64.375 (4)
Al_y3^iv—Na_x1—O1ⁱ	35.670 (11)	Ca_x2^xlii—Ti_y3—Ca_x2^xxxii	176.707 (6)
Al_y3^iv—Na_x1—O1ⁱⁱ	123.215 (11)	Ca_x2^xlii—Ti_y3—Ca_x3^xxii	118.784 (5)
Al_y3^iv—Na_x1—O1ⁱⁱⁱ	100.326 (10)	Ca_x2^xlii—Ti_y3—Al_y2	115.858 (5)
Al_y3^v—Na_x1—Al_y3^vi	97.588 (4)	Ca_x2^xlii—Ti_y3—Mg_y2	115.858 (5)
Al_y3^v—Na_x1—Al_y3^vii	104.452 (4)	Ca_x2^xlii—Ti_y3—Al_y3	0
Al_y3^v—Na_x1—Ti_y3^iv	128.199 (3)	Ca_x2^xlii—Ti_y3—Fe_y3	0
Al_y3^v—Na_x1—Ti_y3^v	0.0 (5)	Ca_x2^xlii—Ti_y3—O1^v	93.316 (13)
Al_y3^v—Na_x1—Ti_y3^vi	97.588 (4)	Ca_x2^xlii—Ti_y3—O2^xxxii	43.585 (14)
Al_y3^v—Na_x1—Ti_y3^vii	104.452 (4)	Ca_x2^xlii—Ti_y3—O3^xxxiii	137.041 (13)
Al_y3^v—Na_x1—Fe_y3^iv	128.199 (3)	Ca_x2^xlii—Ti_y3—O4^xxix	129.547 (13)
Al_y3^v—Na_x1—Fe_y3^v	0.0 (5)	Ca_x2^xlii—Ti_y3—O5^xxxi	44.248 (13)
Al_y3^v—Na_x1—Fe_y3^vi	97.588 (4)	Ca_x2^xlii—Ti_y3—O11^xxviii	96.456 (14)
Al_y3^v—Na_x1—Fe_y3^vii	104.452 (4)	Ca_x2^vi—Ti_y3—Ca_x2^xxxii	112.343 (5)
Al_y3^v—Na_x1—Si_z1	64.099 (2)	Ca_x2^vi—Ti_y3—Ca_x3^xxii	173.323 (6)
Al_y3^v—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x2^vi—Ti_y3—Al_y2	107.887 (5)
Al_y3^v—Na_x1—O1	35.670 (11)	Ca_x2^vi—Ti_y3—Mg_y2	107.887 (5)
Al_y3^v—Na_x1—O1ⁱ	94.896 (10)	Ca_x2^vi—Ti_y3—Al_y3	0
Al_y3^v—Na_x1—O1ⁱⁱ	100.326 (10)	Ca_x2^vi—Ti_y3—Fe_y3	0
Al_y3^v—Na_x1—O1ⁱⁱⁱ	123.215 (11)	Ca_x2^vi—Ti_y3—O1^v	47.384 (13)
Al_y3^vi—Na_x1—Al_y3^vii	128.199 (3)	Ca_x2^vi—Ti_y3—O2^xxxii	95.835 (14)
Al_y3^vi—Na_x1—Ti_y3^iv	104.452 (4)	Ca_x2^vi—Ti_y3—O3^xxxiii	137.564 (14)
Al_y3^vi—Na_x1—Ti_y3^v	97.588 (4)	Ca_x2^vi—Ti_y3—O4^xxix	81.231 (12)
Al_y3^vi—Na_x1—Ti_y3^vi	0.0 (5)	Ca_x2^vi—Ti_y3—O5^xxxi	43.748 (14)
Al_y3^vi—Na_x1—Ti_y3^vii	128.199 (3)	Ca_x2^vi—Ti_y3—O11^xxviii	130.998 (15)
Al_y3^vi—Na_x1—Fe_y3^iv	104.452 (4)	Ca_x2^xxxii—Ti_y3—Ca_x3^xxii	64.447 (4)
Al_y3^vi—Na_x1—Fe_y3^v	97.588 (4)	Ca_x2^xxxii—Ti_y3—Al_y2	64.398 (3)
Al_y3^vi—Na_x1—Fe_y3^vi	0.0 (5)	Ca_x2^xxxii—Ti_y3—Mg_y2	64.398 (3)
Al_y3^vi—Na_x1—Fe_y3^vii	128.199 (3)	Ca_x2^xxxii—Ti_y3—Al_y3	0
Al_y3^vi—Na_x1—Si_z1	115.901 (2)	Ca_x2^xxxii—Ti_y3—Fe_y3	0
Al_y3^vi—Na_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x2^xxxii—Ti_y3—O1^v	84.298 (12)
Al_y3^vi—Na_x1—O1	123.215 (11)	Ca_x2^xxxii—Ti_y3—O2^xxxii	138.758 (15)
Al_y3^vi—Na_x1—O1ⁱ	100.326 (10)	Ca_x2^xxxii—Ti_y3—O3^xxxiii	45.451 (12)
Al_y3^vi—Na_x1—O1ⁱⁱ	94.896 (10)	Ca_x2^xxxii—Ti_y3—O4^xxix	48.264 (11)
Al_y3^vi—Na_x1—O1ⁱⁱⁱ	35.670 (11)	Ca_x2^xxxii—Ti_y3—O5^xxxi	133.350 (14)
Al_y3^vii—Na_x1—Ti_y3^iv	97.588 (4)	Ca_x2^xxxii—Ti_y3—O11^xxviii	85.575 (14)
Al_y3^vii—Na_x1—Ti_y3^v	104.452 (4)	Ca_x3^xxii—Ti_y3—Al_y2	65.522 (4)
Al_y3^vii—Na_x1—Ti_y3^vi	128.199 (3)	Ca_x3^xxii—Ti_y3—Mg_y2	65.522 (4)
Al_y3^vii—Na_x1—Ti_y3^vii	0.0 (5)	Ca_x3^xxii—Ti_y3—Al_y3	0
Al_y3^vii—Na_x1—Fe_y3^iv	97.588 (4)	Ca_x3^xxii—Ti_y3—Fe_y3	0
Al_y3^vii—Na_x1—Fe_y3^v	104.452 (4)	Ca_x3^xxii—Ti_y3—O1^v	135.493 (14)
Al_y3^vii—Na_x1—Fe_y3^vi	128.199 (3)	Ca_x3^xxii—Ti_y3—O2^xxxii	89.998 (14)
Al_y3^vii—Na_x1—Fe_y3^vii	0.0 (5)	Ca_x3^xxii—Ti_y3—O3^xxxiii	44.820 (12)
Al_y3^vii—Na_x1—Si_z1	115.901 (2)	Ca_x3^xxii—Ti_y3—O4^xxix	92.587 (12)
Al_y3^vii—Na_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x3^xxii—Ti_y3—O5^xxxi	133.638 (15)
Al_y3^vii—Na_x1—O1	100.326 (10)	Ca_x3^xxii—Ti_y3—O11^xxviii	44.406 (14)
Al_y3^vii—Na_x1—O1ⁱ	123.215 (11)	Al_y2—Ti_y3—Mg_y2	0.0 (5)
Al_y3^vii—Na_x1—O1ⁱⁱ	35.670 (11)	Al_y2—Ti_y3—Al_y3	0
Al_y3^vii—Na_x1—O1ⁱⁱⁱ	94.896 (10)	Al_y2—Ti_y3—Fe_y3	0
Ti_y3^iv—Na_x1—Ti_y3^v	128.199 (3)	Al_y2—Ti_y3—O1^v	129.294 (13)
Ti_y3^iv—Na_x1—Ti_y3^vi	104.452 (4)	Al_y2—Ti_y3—O2^xxxii	135.432 (15)
Ti_y3^iv—Na_x1—Ti_y3^vii	97.588 (4)	Al_y2—Ti_y3—O3^xxxiii	93.484 (13)
Ti_y3^iv—Na_x1—Fe_y3^iv	0.0 (5)	Al_y2—Ti_y3—O4^xxix	40.849 (11)
Ti_y3^iv—Na_x1—Fe_y3^v	128.199 (3)	Al_y2—Ti_y3—O5^xxxi	84.469 (14)
Ti_y3^iv—Na_x1—Fe_y3^vi	104.452 (4)	Al_y2—Ti_y3—O11^xxviii	38.015 (13)
Ti_y3^iv—Na_x1—Fe_y3^vii	97.588 (4)	Mg_y2—Ti_y3—Al_y3	0
Ti_y3^iv—Na_x1—Si_z1	64.099 (2)	Mg_y2—Ti_y3—Fe_y3	0
Ti_y3^iv—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Mg_y2—Ti_y3—O1^v	129.294 (13)
Ti_y3^iv—Na_x1—O1	94.896 (10)	Mg_y2—Ti_y3—O2^xxxii	135.432 (15)
Ti_y3^iv—Na_x1—O1ⁱ	35.670 (11)	Mg_y2—Ti_y3—O3^xxxiii	93.484 (13)
Ti_y3^iv—Na_x1—O1ⁱⁱ	123.215 (11)	Mg_y2—Ti_y3—O4^xxix	40.849 (11)
Ti_y3^iv—Na_x1—O1ⁱⁱⁱ	100.326 (10)	Mg_y2—Ti_y3—O5^xxxi	84.469 (14)
Ti_y3^v—Na_x1—Ti_y3^vi	97.588 (4)	Mg_y2—Ti_y3—O11^xxviii	38.015 (13)
Ti_y3^v—Na_x1—Ti_y3^vii	104.452 (4)	Al_y3—Ti_y3—Fe_y3	0
Ti_y3^v—Na_x1—Fe_y3^iv	128.199 (3)	Al_y3—Ti_y3—O1^v	0
Ti_y3^v—Na_x1—Fe_y3^v	0.0 (5)	Al_y3—Ti_y3—O2^xxxii	0
Ti_y3^v—Na_x1—Fe_y3^vi	97.588 (4)	Al_y3—Ti_y3—O3^xxxiii	0
Ti_y3^v—Na_x1—Fe_y3^vii	104.452 (4)	Al_y3—Ti_y3—O4^xxix	0
Ti_y3^v—Na_x1—Si_z1	64.099 (2)	Al_y3—Ti_y3—O5^xxxi	0
Ti_y3^v—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Al_y3—Ti_y3—O11^xxviii	0
Ti_y3^v—Na_x1—O1	35.670 (11)	Fe_y3—Ti_y3—O1^v	0
Ti_y3^v—Na_x1—O1ⁱ	94.896 (10)	Fe_y3—Ti_y3—O2^xxxii	0
Ti_y3^v—Na_x1—O1ⁱⁱ	100.326 (10)	Fe_y3—Ti_y3—O3^xxxiii	0
Ti_y3^v—Na_x1—O1ⁱⁱⁱ	123.215 (11)	Fe_y3—Ti_y3—O4^xxix	0
Ti_y3^vi—Na_x1—Ti_y3^vii	128.199 (3)	Fe_y3—Ti_y3—O5^xxxi	0
Ti_y3^vi—Na_x1—Fe_y3^iv	104.452 (4)	Fe_y3—Ti_y3—O11^xxviii	0
Ti_y3^vi—Na_x1—Fe_y3^v	97.588 (4)	O1^v—Ti_y3—O2^xxxii	94.561 (19)
Ti_y3^vi—Na_x1—Fe_y3^vi	0.0 (5)	O1^v—Ti_y3—O3^xxxiii	90.684 (18)
Ti_y3^vi—Na_x1—Fe_y3^vii	128.199 (3)	O1^v—Ti_y3—O4^xxix	88.479 (17)
Ti_y3^vi—Na_x1—Si_z1	115.901 (2)	O1^v—Ti_y3—O5^xxxi	90.814 (19)
Ti_y3^vi—Na_x1—Si_z1ⁱⁱ	64.099 (2)	O1^v—Ti_y3—O11^xxviii	167.008 (18)
Ti_y3^vi—Na_x1—O1	123.215 (11)	O2^xxxii—Ti_y3—O3^xxxiii	93.464 (18)
Ti_y3^vi—Na_x1—O1ⁱ	100.326 (10)	O2^xxxii—Ti_y3—O4^xxix	172.565 (19)
Ti_y3^vi—Na_x1—O1ⁱⁱ	94.896 (10)	O2^xxxii—Ti_y3—O5^xxxi	87.829 (19)
Ti_y3^vi—Na_x1—O1ⁱⁱⁱ	35.670 (11)	O2^xxxii—Ti_y3—O11^xxviii	98.418 (19)
Ti_y3^vii—Na_x1—Fe_y3^iv	97.588 (4)	O3^xxxiii—Ti_y3—O4^xxix	93.282 (17)
Ti_y3^vii—Na_x1—Fe_y3^v	104.452 (4)	O3^xxxiii—Ti_y3—O5^xxxi	177.94 (2)
Ti_y3^vii—Na_x1—Fe_y3^vi	128.199 (3)	O3^xxxiii—Ti_y3—O11^xxviii	87.991 (19)
Ti_y3^vii—Na_x1—Fe_y3^vii	0.0 (5)	O4^xxix—Ti_y3—O5^xxxi	85.342 (18)
Ti_y3^vii—Na_x1—Si_z1	115.901 (2)	O4^xxix—Ti_y3—O11^xxviii	78.700 (17)
Ti_y3^vii—Na_x1—Si_z1ⁱⁱ	64.099 (2)	O5^xxxi—Ti_y3—O11^xxviii	90.23 (2)
Ti_y3^vii—Na_x1—O1	100.326 (10)	Ca_x1^xlii—Fe_y3—Na_x1^xlii	0.0 (5)
Ti_y3^vii—Na_x1—O1ⁱ	123.215 (11)	Ca_x1^xlii—Fe_y3—Ca_x2^vi	67.108 (3)
Ti_y3^vii—Na_x1—O1ⁱⁱ	35.670 (11)	Ca_x1^xlii—Fe_y3—Ca_x2^xxxii	113.268 (5)
Ti_y3^vii—Na_x1—O1ⁱⁱⁱ	94.896 (10)	Ca_x1^xlii—Fe_y3—Mg_y2	173.672 (5)
Fe_y3^iv—Na_x1—Fe_y3^v	128.199 (3)	Ca_x1^xlii—Fe_y3—Al_y3	0
Fe_y3^iv—Na_x1—Fe_y3^vi	104.452 (4)	Ca_x1^xlii—Fe_y3—Ti_y3	0
Fe_y3^iv—Na_x1—Fe_y3^vii	97.588 (4)	Ca_x1^xlii—Fe_y3—O1^v	44.532 (12)
Fe_y3^iv—Na_x1—Si_z1	64.099 (2)	Ca_x1^xlii—Fe_y3—O2^xxxii	50.388 (14)
Fe_y3^iv—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Ca_x1^xlii—Fe_y3—O3^xxxiii	88.252 (13)
Fe_y3^iv—Na_x1—O1	94.896 (10)	Ca_x1^xlii—Fe_y3—O4^xxix	133.010 (12)
Fe_y3^iv—Na_x1—O1ⁱ	35.670 (11)	Ca_x1^xlii—Fe_y3—O5^xxxi	93.810 (14)
Fe_y3^iv—Na_x1—O1ⁱⁱ	123.215 (11)	Ca_x1^xlii—Fe_y3—O11^xxviii	148.240 (14)
Fe_y3^iv—Na_x1—O1ⁱⁱⁱ	100.326 (10)	Na_x1^xlii—Fe_y3—Ca_x2^vi	67.108 (3)
Fe_y3^v—Na_x1—Fe_y3^vi	97.588 (4)	Na_x1^xlii—Fe_y3—Ca_x2^xxxii	113.268 (5)
Fe_y3^v—Na_x1—Fe_y3^vii	104.452 (4)	Na_x1^xlii—Fe_y3—Mg_y2	173.672 (5)
Fe_y3^v—Na_x1—Si_z1	64.099 (2)	Na_x1^xlii—Fe_y3—Al_y3	0
Fe_y3^v—Na_x1—Si_z1ⁱⁱ	115.901 (2)	Na_x1^xlii—Fe_y3—Ti_y3	0
Fe_y3^v—Na_x1—O1	35.670 (11)	Na_x1^xlii—Fe_y3—O1^v	44.532 (12)
Fe_y3^v—Na_x1—O1ⁱ	94.896 (10)	Na_x1^xlii—Fe_y3—O2^xxxii	50.388 (14)
Fe_y3^v—Na_x1—O1ⁱⁱ	100.326 (10)	Na_x1^xlii—Fe_y3—O3^xxxiii	88.252 (13)
Fe_y3^v—Na_x1—O1ⁱⁱⁱ	123.215 (11)	Na_x1^xlii—Fe_y3—O4^xxix	133.010 (12)
Fe_y3^vi—Na_x1—Fe_y3^vii	128.199 (3)	Na_x1^xlii—Fe_y3—O5^xxxi	93.810 (14)
Fe_y3^vi—Na_x1—Si_z1	115.901 (2)	Na_x1^xlii—Fe_y3—O11^xxviii	148.240 (14)
Fe_y3^vi—Na_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x2^vi—Fe_y3—Ca_x2^xxxii	112.343 (5)
Fe_y3^vi—Na_x1—O1	123.215 (11)	Ca_x2^vi—Fe_y3—Mg_y2	107.887 (5)
Fe_y3^vi—Na_x1—O1ⁱ	100.326 (10)	Ca_x2^vi—Fe_y3—Al_y3	0
Fe_y3^vi—Na_x1—O1ⁱⁱ	94.896 (10)	Ca_x2^vi—Fe_y3—Ti_y3	0
Fe_y3^vi—Na_x1—O1ⁱⁱⁱ	35.670 (11)	Ca_x2^vi—Fe_y3—O1^v	47.384 (13)
Fe_y3^vii—Na_x1—Si_z1	115.901 (2)	Ca_x2^vi—Fe_y3—O2^xxxii	95.835 (14)
Fe_y3^vii—Na_x1—Si_z1ⁱⁱ	64.099 (2)	Ca_x2^vi—Fe_y3—O3^xxxiii	137.564 (14)
Fe_y3^vii—Na_x1—O1	100.326 (10)	Ca_x2^vi—Fe_y3—O4^xxix	81.231 (12)
Fe_y3^vii—Na_x1—O1ⁱ	123.215 (11)	Ca_x2^vi—Fe_y3—O5^xxxi	43.748 (14)
Fe_y3^vii—Na_x1—O1ⁱⁱ	35.670 (11)	Ca_x2^vi—Fe_y3—O11^xxviii	130.998 (15)
Fe_y3^vii—Na_x1—O1ⁱⁱⁱ	94.896 (10)	Ca_x2^xxxii—Fe_y3—Mg_y2	64.398 (3)
Si_z1—Na_x1—Si_z1ⁱⁱ	180.0 (5)	Ca_x2^xxxii—Fe_y3—Al_y3	0
Si_z1—Na_x1—O1	33.673 (10)	Ca_x2^xxxii—Fe_y3—Ti_y3	0
Si_z1—Na_x1—O1ⁱ	33.673 (10)	Ca_x2^xxxii—Fe_y3—O1^v	84.298 (12)
Si_z1—Na_x1—O1ⁱⁱ	146.327 (10)	Ca_x2^xxxii—Fe_y3—O2^xxxii	138.758 (15)
Si_z1—Na_x1—O1ⁱⁱⁱ	146.327 (10)	Ca_x2^xxxii—Fe_y3—O3^xxxiii	45.451 (12)
Si_z1ⁱⁱ—Na_x1—O1	146.327 (10)	Ca_x2^xxxii—Fe_y3—O4^xxix	48.264 (11)
Si_z1ⁱⁱ—Na_x1—O1ⁱ	146.327 (10)	Ca_x2^xxxii—Fe_y3—O5^xxxi	133.350 (14)
Si_z1ⁱⁱ—Na_x1—O1ⁱⁱ	33.673 (10)	Ca_x2^xxxii—Fe_y3—O11^xxviii	85.575 (14)
Si_z1ⁱⁱ—Na_x1—O1ⁱⁱⁱ	33.673 (10)	Mg_y2—Fe_y3—Al_y3	0
O1—Na_x1—O1ⁱ	67.345 (14)	Mg_y2—Fe_y3—Ti_y3	0
O1—Na_x1—O1ⁱⁱ	117.765 (14)	Mg_y2—Fe_y3—O1^v	129.294 (13)
O1—Na_x1—O1ⁱⁱⁱ	156.829 (15)	Mg_y2—Fe_y3—O2^xxxii	135.432 (15)
O1ⁱ—Na_x1—O1ⁱⁱ	156.829 (15)	Mg_y2—Fe_y3—O3^xxxiii	93.484 (13)
O1ⁱ—Na_x1—O1ⁱⁱⁱ	117.765 (14)	Mg_y2—Fe_y3—O4^xxix	40.849 (11)
O1ⁱⁱ—Na_x1—O1ⁱⁱⁱ	67.345 (14)	Mg_y2—Fe_y3—O5^xxxi	84.469 (14)
Ca_x1—Ca_x2—Na_x1	0.0 (5)	Mg_y2—Fe_y3—O11^xxviii	38.015 (13)
Ca_x1—Ca_x2—Ca_x2ⁱⁱ	60.599 (2)	Al_y3—Fe_y3—Ti_y3	0
Ca_x1—Ca_x2—Ca_x3^viii	152.282 (4)	Al_y3—Fe_y3—O1^v	0
Ca_x1—Ca_x2—Al_y2^ix	125.983 (3)	Al_y3—Fe_y3—O2^xxxii	0
Ca_x1—Ca_x2—Mg_y2^ix	125.983 (3)	Al_y3—Fe_y3—O3^xxxiii	0
Ca_x1—Ca_x2—Al_y3^iv	55.332 (3)	Al_y3—Fe_y3—O4^xxix	0
Ca_x1—Ca_x2—Al_y3^vi	55.969 (3)	Al_y3—Fe_y3—O5^xxxi	0
Ca_x1—Ca_x2—Al_y3^x	100.793 (4)	Al_y3—Fe_y3—O11^xxviii	0
Ca_x1—Ca_x2—Ti_y3^iv	55.332 (3)	Ti_y3—Fe_y3—O1^v	0
Ca_x1—Ca_x2—Ti_y3^vi	55.969 (3)	Ti_y3—Fe_y3—O2^xxxii	0
Ca_x1—Ca_x2—Ti_y3^x	100.793 (4)	Ti_y3—Fe_y3—O3^xxxiii	0
Ca_x1—Ca_x2—Fe_y3^vi	55.969 (3)	Ti_y3—Fe_y3—O4^xxix	0
Ca_x1—Ca_x2—Fe_y3^x	100.793 (4)	Ti_y3—Fe_y3—O5^xxxi	0
Ca_x1—Ca_x2—Si_z2^xi	66.117 (4)	Ti_y3—Fe_y3—O11^xxviii	0
Ca_x1—Ca_x2—Si_z3^xii	108.686 (4)	O1^v—Fe_y3—O2^xxxii	94.561 (19)
Ca_x1—Ca_x2—O2^xi	43.867 (10)	O1^v—Fe_y3—O3^xxxiii	90.684 (18)
Ca_x1—Ca_x2—O3^xiii	109.386 (10)	O1^v—Fe_y3—O4^xxix	88.479 (17)
Ca_x1—Ca_x2—O5^xii	79.085 (12)	O1^v—Fe_y3—O5^xxxi	90.814 (19)
Ca_x1—Ca_x2—O5^xiv	78.110 (12)	O1^v—Fe_y3—O11^xxviii	167.008 (18)
Ca_x1—Ca_x2—O8^xv	153.668 (11)	O2^xxxii—Fe_y3—O3^xxxiii	93.464 (18)
Na_x1—Ca_x2—Ca_x2ⁱⁱ	60.599 (2)	O2^xxxii—Fe_y3—O4^xxix	172.565 (19)
Na_x1—Ca_x2—Ca_x3^viii	152.282 (4)	O2^xxxii—Fe_y3—O5^xxxi	87.829 (19)
Na_x1—Ca_x2—Al_y2^ix	125.983 (3)	O2^xxxii—Fe_y3—O11^xxviii	98.418 (19)
Na_x1—Ca_x2—Mg_y2^ix	125.983 (3)	O3^xxxiii—Fe_y3—O4^xxix	93.282 (17)
Na_x1—Ca_x2—Al_y3^iv	55.332 (3)	O3^xxxiii—Fe_y3—O5^xxxi	177.94 (2)
Na_x1—Ca_x2—Al_y3^vi	55.969 (3)	O3^xxxiii—Fe_y3—O11^xxviii	87.991 (19)
Na_x1—Ca_x2—Al_y3^x	100.793 (4)	O4^xxix—Fe_y3—O5^xxxi	85.342 (18)
Na_x1—Ca_x2—Ti_y3^iv	55.332 (3)	O4^xxix—Fe_y3—O11^xxviii	78.700 (17)
Na_x1—Ca_x2—Ti_y3^vi	55.969 (3)	O5^xxxi—Fe_y3—O11^xxviii	90.23 (2)
Na_x1—Ca_x2—Ti_y3^x	100.793 (4)	Ca_x1—Si_z1—Ca_x1^xxxiv	180.0 (5)
Na_x1—Ca_x2—Fe_y3^vi	55.969 (3)	Ca_x1—Si_z1—Na_x1	0.0 (5)
Na_x1—Ca_x2—Fe_y3^x	100.793 (4)	Ca_x1—Si_z1—Na_x1^xxxiv	180.0 (5)
Na_x1—Ca_x2—Si_z2^xi	66.117 (4)	Ca_x1—Si_z1—O1	52.301 (14)
Na_x1—Ca_x2—Si_z3^xii	108.686 (4)	Ca_x1—Si_z1—O1ⁱ	52.301 (14)
Na_x1—Ca_x2—O2^xi	43.867 (10)	Ca_x1—Si_z1—O1^xxxiv	127.699 (14)
Na_x1—Ca_x2—O3^xiii	109.386 (10)	Ca_x1—Si_z1—O1^xxxv	127.699 (14)
Na_x1—Ca_x2—O5^xii	79.085 (12)	Ca_x1^xxxiv—Si_z1—Na_x1	180.0 (5)
Na_x1—Ca_x2—O5^xiv	78.110 (12)	Ca_x1^xxxiv—Si_z1—Na_x1^xxxiv	0.0 (5)
Na_x1—Ca_x2—O8^xv	153.668 (11)	Ca_x1^xxxiv—Si_z1—O1	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Ca_x3^viii	132.734 (4)	Ca_x1^xxxiv—Si_z1—O1ⁱ	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Al_y2^ix	145.684 (4)	Ca_x1^xxxiv—Si_z1—O1^xxxiv	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Mg_y2^ix	145.684 (4)	Ca_x1^xxxiv—Si_z1—O1^xxxv	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Al_y3^iv	56.645 (3)	Na_x1—Si_z1—Na_x1^xxxiv	180.0 (5)
Ca_x2ⁱⁱ—Ca_x2—Al_y3^vi	58.980 (3)	Na_x1—Si_z1—O1	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Al_y3^x	158.577 (5)	Na_x1—Si_z1—O1ⁱ	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Ti_y3^iv	56.645 (3)	Na_x1—Si_z1—O1^xxxiv	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Ti_y3^vi	58.980 (3)	Na_x1—Si_z1—O1^xxxv	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Ti_y3^x	158.577 (5)	Na_x1^xxxiv—Si_z1—O1	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Fe_y3^vi	58.980 (3)	Na_x1^xxxiv—Si_z1—O1ⁱ	127.699 (14)
Ca_x2ⁱⁱ—Ca_x2—Fe_y3^x	158.577 (5)	Na_x1^xxxiv—Si_z1—O1^xxxiv	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Si_z2^xi	111.448 (5)	Na_x1^xxxiv—Si_z1—O1^xxxv	52.301 (14)
Ca_x2ⁱⁱ—Ca_x2—Si_z3^xii	62.849 (4)	O1—Si_z1—O1ⁱ	104.603 (19)
Ca_x2ⁱⁱ—Ca_x2—O2^xi	80.513 (10)	O1—Si_z1—O1^xxxiv	111.96 (2)
Ca_x2ⁱⁱ—Ca_x2—O3^xiii	135.869 (10)	O1—Si_z1—O1^xxxv	111.96 (2)
Ca_x2ⁱⁱ—Ca_x2—O5^xii	42.033 (11)	O1ⁱ—Si_z1—O1^xxxiv	111.96 (2)
Ca_x2ⁱⁱ—Ca_x2—O5^xiv	40.195 (11)	O1ⁱ—Si_z1—O1^xxxv	111.96 (2)
Ca_x2ⁱⁱ—Ca_x2—O8^xv	125.197 (10)	O1^xxxiv—Si_z1—O1^xxxv	104.603 (19)
Ca_x3^viii—Ca_x2—Al_y2^ix	60.100 (3)	Ca_x2^xliii—Si_z2—Ca_x3^xii	174.362 (7)
Ca_x3^viii—Ca_x2—Mg_y2^ix	60.100 (3)	Ca_x2^xliii—Si_z2—O2	49.464 (16)
Ca_x3^viii—Ca_x2—Al_y3^iv	150.849 (5)	Ca_x2^xliii—Si_z2—O3	122.739 (17)
Ca_x3^viii—Ca_x2—Al_y3^vi	106.416 (4)	Ca_x2^xliii—Si_z2—O4	50.771 (15)
Ca_x3^viii—Ca_x2—Al_y3^x	59.507 (4)	Ca_x2^xliii—Si_z2—O7	131.615 (18)
Ca_x3^viii—Ca_x2—Ti_y3^iv	150.849 (5)	Ca_x3^xii—Si_z2—O2	133.578 (18)
Ca_x3^viii—Ca_x2—Ti_y3^vi	106.416 (4)	Ca_x3^xii—Si_z2—O3	52.586 (15)
Ca_x3^viii—Ca_x2—Ti_y3^x	59.507 (4)	Ca_x3^xii—Si_z2—O4	126.091 (16)
Ca_x3^viii—Ca_x2—Fe_y3^vi	106.416 (4)	Ca_x3^xii—Si_z2—O7	53.141 (17)
Ca_x3^viii—Ca_x2—Fe_y3^x	59.507 (4)	O2—Si_z2—O3	111.85 (2)
Ca_x3^viii—Ca_x2—Si_z2^xi	114.618 (5)	O2—Si_z2—O4	100.19 (2)
Ca_x3^viii—Ca_x2—Si_z3^xii	71.241 (4)	O2—Si_z2—O7	114.95 (2)
Ca_x3^viii—Ca_x2—O2^xi	145.267 (11)	O3—Si_z2—O4	110.64 (2)
Ca_x3^viii—Ca_x2—O3^xiii	43.061 (10)	O3—Si_z2—O7	105.64 (2)
Ca_x3^viii—Ca_x2—O5^xii	98.012 (12)	O4—Si_z2—O7	113.70 (2)
Ca_x3^viii—Ca_x2—O5^xiv	128.611 (12)	Ca_x2^xxiii—Si_z3—Ca_x4ⁱⁱ	97.993 (5)
Ca_x3^viii—Ca_x2—O8^xv	46.912 (10)	Ca_x2^xxiii—Si_z3—O5	44.863 (16)
Al_y2^ix—Ca_x2—Mg_y2^ix	0.0 (5)	Ca_x2^xxiii—Si_z3—O6	66.23 (2)
Al_y2^ix—Ca_x2—Al_y3^iv	97.301 (4)	Ca_x2^xxiii—Si_z3—O8	133.725 (17)
Al_y2^ix—Ca_x2—Al_y3^vi	155.273 (4)	Ca_x2^xxiii—Si_z3—O9	116.450 (17)
Al_y2^ix—Ca_x2—Al_y3^x	52.934 (3)	Ca_x4ⁱⁱ—Si_z3—O5	133.981 (18)
Al_y2^ix—Ca_x2—Ti_y3^iv	97.301 (4)	Ca_x4ⁱⁱ—Si_z3—O6	48.70 (2)
Al_y2^ix—Ca_x2—Ti_y3^vi	155.273 (4)	Ca_x4ⁱⁱ—Si_z3—O8	113.381 (18)
Al_y2^ix—Ca_x2—Ti_y3^x	52.934 (3)	Ca_x4ⁱⁱ—Si_z3—O9	60.478 (17)
Al_y2^ix—Ca_x2—Fe_y3^vi	155.273 (4)	O5—Si_z3—O6	110.85 (3)
Al_y2^ix—Ca_x2—Fe_y3^x	52.934 (3)	O5—Si_z3—O8	112.54 (2)
Al_y2^ix—Ca_x2—Si_z2^xi	60.022 (4)	O5—Si_z3—O9	106.82 (2)
Al_y2^ix—Ca_x2—Si_z3^xii	125.309 (5)	O6—Si_z3—O8	110.16 (2)
Al_y2^ix—Ca_x2—O2^xi	86.852 (11)	O6—Si_z3—O9	107.69 (3)
Al_y2^ix—Ca_x2—O3^xiii	77.083 (10)	O8—Si_z3—O9	108.58 (2)
Al_y2^ix—Ca_x2—O5^xii	154.931 (12)	Ca_x1—O1—Na_x1	0.0 (5)
Al_y2^ix—Ca_x2—O5^xiv	105.549 (11)	Ca_x1—O1—Ti_y3^v	99.798 (17)
Al_y2^ix—Ca_x2—O8^xv	32.809 (10)	Ca_x1—O1—Fe_y3^v	99.798 (17)
Mg_y2^ix—Ca_x2—Al_y3^iv	97.301 (4)	Ca_x1—O1—Si_z1	94.026 (18)
Mg_y2^ix—Ca_x2—Al_y3^vi	155.273 (4)	Na_x1—O1—Ti_y3^v	99.798 (17)
Mg_y2^ix—Ca_x2—Al_y3^x	52.934 (3)	Na_x1—O1—Fe_y3^v	99.798 (17)
Mg_y2^ix—Ca_x2—Ti_y3^iv	97.301 (4)	Na_x1—O1—Si_z1	94.026 (18)
Mg_y2^ix—Ca_x2—Ti_y3^vi	155.273 (4)	Ti_y3^v—O1—Fe_y3^v	0.0 (5)
Mg_y2^ix—Ca_x2—Ti_y3^x	52.934 (3)	Ti_y3^v—O1—Si_z1	135.69 (3)
Mg_y2^ix—Ca_x2—Fe_y3^vi	155.273 (4)	Fe_y3^v—O1—Si_z1	135.69 (3)
Mg_y2^ix—Ca_x2—Fe_y3^x	52.934 (3)	Ca_x2^xliii—O2—Ti_y3^x	103.966 (19)
Mg_y2^ix—Ca_x2—Si_z2^xi	60.022 (4)	Ca_x2^xliii—O2—Fe_y3^x	103.966 (19)
Mg_y2^ix—Ca_x2—Si_z3^xii	125.309 (5)	Ca_x2^xliii—O2—Si_z2	99.54 (2)
Mg_y2^ix—Ca_x2—O2^xi	86.852 (11)	Ti_y3^x—O2—Fe_y3^x	0.0 (5)
Mg_y2^ix—Ca_x2—O3^xiii	77.083 (10)	Ti_y3^x—O2—Si_z2	131.50 (3)
Mg_y2^ix—Ca_x2—O5^xii	154.931 (12)	Fe_y3^x—O2—Si_z2	131.50 (3)
Mg_y2^ix—Ca_x2—O5^xiv	105.549 (11)	Ca_x2^xiii—O3—Ti_y3^xliv	98.668 (16)
Mg_y2^ix—Ca_x2—O8^xv	32.809 (10)	Ca_x2^xiii—O3—Fe_y3^xliv	98.668 (16)
Al_y3^iv—Ca_x2—Al_y3^vi	101.009 (4)	Ca_x2^xiii—O3—Si_z2	124.46 (2)
Al_y3^iv—Ca_x2—Al_y3^x	123.584 (5)	Ti_y3^xliv—O3—Fe_y3^xliv	0.0 (5)
Al_y3^iv—Ca_x2—Ti_y3^iv	0.0 (5)	Ti_y3^xliv—O3—Si_z2	131.84 (2)
Al_y3^iv—Ca_x2—Ti_y3^vi	101.009 (4)	Fe_y3^xliv—O3—Si_z2	131.84 (2)
Al_y3^iv—Ca_x2—Ti_y3^x	123.584 (5)	Mg_y2^xlv—O4—Ti_y3^xlv	94.497 (17)
Al_y3^iv—Ca_x2—Fe_y3^vi	101.009 (4)	Mg_y2^xlv—O4—Fe_y3^xlv	94.497 (17)
Al_y3^iv—Ca_x2—Fe_y3^x	123.584 (5)	Mg_y2^xlv—O4—Si_z2	128.04 (2)
Al_y3^iv—Ca_x2—Si_z2^xi	58.636 (4)	Ti_y3^xlv—O4—Fe_y3^xlv	0.0 (5)
Al_y3^iv—Ca_x2—Si_z3^xii	116.481 (5)	Ti_y3^xlv—O4—Si_z2	133.84 (2)
Al_y3^iv—Ca_x2—O2^xi	32.449 (10)	Fe_y3^xlv—O4—Si_z2	133.84 (2)
Al_y3^iv—Ca_x2—O3^xiii	156.431 (11)	Ca_x2^xxiii—O5—Ca_x2^ix	97.773 (17)
Al_y3^iv—Ca_x2—O5^xii	98.452 (11)	Ca_x2^xxiii—O5—Ti_y3^xlvi	100.44 (2)
Al_y3^iv—Ca_x2—O5^xiv	34.690 (12)	Ca_x2^xxiii—O5—Fe_y3^xlvi	100.44 (2)
Al_y3^iv—Ca_x2—O8^xv	104.026 (11)	Ca_x2^xxiii—O5—Si_z3	105.50 (2)
Al_y3^vi—Ca_x2—Al_y3^x	102.672 (5)	Ca_x2^ix—O5—Ti_y3^xlvi	101.062 (19)
Al_y3^vi—Ca_x2—Ti_y3^iv	101.009 (4)	Ca_x2^ix—O5—Fe_y3^xlvi	101.062 (19)
Al_y3^vi—Ca_x2—Ti_y3^vi	0.0 (5)	Ca_x2^ix—O5—Si_z3	120.65 (2)
Al_y3^vi—Ca_x2—Ti_y3^x	102.672 (5)	Ti_y3^xlvi—O5—Fe_y3^xlvi	0.0 (5)
Al_y3^vi—Ca_x2—Fe_y3^vi	0.0 (5)	Ti_y3^xlvi—O5—Si_z3	126.11 (3)
Al_y3^vi—Ca_x2—Fe_y3^x	102.672 (5)	Fe_y3^xlvi—O5—Si_z3	126.11 (3)
Al_y3^vi—Ca_x2—Si_z2^xi	117.161 (5)	Ca_x4ⁱⁱ—O6—Si_z3	99.54 (3)
Al_y3^vi—Ca_x2—Si_z3^xii	59.325 (5)	Ca_x4ⁱⁱ—O6—Fe_y1aⁱⁱ	23.32 (4)
Al_y3^vi—Ca_x2—O2^xi	99.828 (11)	Ca_x4ⁱⁱ—O6—Fe_y1bⁱⁱ	33.84 (2)
Al_y3^vi—Ca_x2—O3^xiii	79.506 (10)	Ca_x4ⁱⁱ—O6—Mg_y1aⁱⁱ	23.32 (4)
Al_y3^vi—Ca_x2—O5^xii	35.813 (12)	Si_z3—O6—Fe_y1aⁱⁱ	115.64 (4)
Al_y3^vi—Ca_x2—O5^xiv	98.952 (11)	Si_z3—O6—Fe_y1bⁱⁱ	122.16 (3)
Al_y3^vi—Ca_x2—O8^xv	150.354 (11)	Si_z3—O6—Mg_y1aⁱⁱ	115.64 (4)
Al_y3^x—Ca_x2—Ti_y3^iv	123.584 (5)	Fe_y1aⁱⁱ—O6—Fe_y1bⁱⁱ	10.52 (4)
Al_y3^x—Ca_x2—Ti_y3^vi	102.672 (5)	Fe_y1aⁱⁱ—O6—Mg_y1aⁱⁱ	0.0 (5)
Al_y3^x—Ca_x2—Ti_y3^x	0.0 (5)	Fe_y1bⁱⁱ—O6—Mg_y1aⁱⁱ	10.52 (4)
Al_y3^x—Ca_x2—Fe_y3^vi	102.672 (5)	Ca_x3^xv—O7—Si_z2	131.58 (2)
Al_y3^x—Ca_x2—Fe_y3^x	0.0 (5)	Ca_x2^xxiv—O8—Mg_y2^xlvi	104.966 (17)
Al_y3^x—Ca_x2—Si_z2^xi	64.970 (4)	Ca_x2^xxiv—O8—Si_z3	121.39 (2)
Al_y3^x—Ca_x2—Si_z3^xii	119.708 (5)	Mg_y2^xlvi—O8—Si_z3	126.12 (2)
Al_y3^x—Ca_x2—O2^xi	93.065 (11)	Si_z3—O9—Si_z3^xxvi	136.48 (3)
Al_y3^x—Ca_x2—O3^xiii	35.881 (10)	Mg_y2—O11—Ti_y3^xxviii	103.95 (2)
Al_y3^x—Ca_x2—O5^xii	129.052 (12)	Mg_y2—O11—Fe_y3^xxviii	103.95 (2)
Al_y3^x—Ca_x2—O5^xiv	152.921 (12)	Ti_y3^xxviii—O11—Fe_y3^xxviii	0.0 (5)
Al_y3^x—Ca_x2—O8^xv	76.219 (10)	Ca_x3^xxxvii—Fe_y1a—Ca_x3^xxxviii	100.71 (4)
Ti_y3^iv—Ca_x2—Ti_y3^vi	101.009 (4)	Ca_x3^xxxvii—Fe_y1a—Ca_x3^xxxix	65.98 (2)
Ti_y3^iv—Ca_x2—Ti_y3^x	123.584 (5)	Ca_x3^xxxvii—Fe_y1a—Ca_x3^xl	65.98 (2)
Ti_y3^iv—Ca_x2—Fe_y3^vi	101.009 (4)	Ca_x3^xxxvii—Fe_y1a—Ca_x4	129.643 (18)
Ti_y3^iv—Ca_x2—Fe_y3^x	123.584 (5)	Ca_x3^xxxvii—Fe_y1a—O6ⁱⁱ	127.23 (5)
Ti_y3^iv—Ca_x2—Si_z2^xi	58.636 (4)	Ca_x3^xxxvii—Fe_y1a—O6^xxv	48.62 (2)
Ti_y3^iv—Ca_x2—Si_z3^xii	116.481 (5)	Ca_x3^xxxvii—Fe_y1a—O6^xxvi	62.28 (2)
Ti_y3^iv—Ca_x2—O2^xi	32.449 (10)	Ca_x3^xxxvii—Fe_y1a—O6^xxvii	114.15 (4)
Ti_y3^iv—Ca_x2—O3^xiii	156.431 (11)	Ca_x3^xxxvii—Fe_y1a—Fe_y1b	50.357 (18)
Ti_y3^iv—Ca_x2—O5^xii	98.452 (11)	Ca_x3^xxxvii—Fe_y1a—Mg_y1a	0
Ti_y3^iv—Ca_x2—O5^xiv	34.690 (12)	Ca_x3^xxxviii—Fe_y1a—Ca_x3^xxxix	65.98 (2)
Ti_y3^iv—Ca_x2—O8^xv	104.026 (11)	Ca_x3^xxxviii—Fe_y1a—Ca_x3^xl	65.98 (2)
Ti_y3^vi—Ca_x2—Ti_y3^x	102.672 (5)	Ca_x3^xxxviii—Fe_y1a—Ca_x4	129.643 (18)
Ti_y3^vi—Ca_x2—Fe_y3^vi	0.0 (5)	Ca_x3^xxxviii—Fe_y1a—O6ⁱⁱ	48.62 (2)
Ti_y3^vi—Ca_x2—Fe_y3^x	102.672 (5)	Ca_x3^xxxviii—Fe_y1a—O6^xxv	127.23 (5)
Ti_y3^vi—Ca_x2—Si_z2^xi	117.161 (5)	Ca_x3^xxxviii—Fe_y1a—O6^xxvi	114.15 (4)
Ti_y3^vi—Ca_x2—Si_z3^xii	59.325 (5)	Ca_x3^xxxviii—Fe_y1a—O6^xxvii	62.28 (2)
Ti_y3^vi—Ca_x2—O2^xi	99.828 (11)	Ca_x3^xxxviii—Fe_y1a—Fe_y1b	50.357 (18)
Ti_y3^vi—Ca_x2—O3^xiii	79.506 (10)	Ca_x3^xxxviii—Fe_y1a—Mg_y1a	0
Ti_y3^vi—Ca_x2—O5^xii	35.813 (12)	Ca_x3^xxxix—Fe_y1a—Ca_x3^xl	100.71 (4)
Ti_y3^vi—Ca_x2—O5^xiv	98.952 (11)	Ca_x3^xxxix—Fe_y1a—Ca_x4	129.643 (18)
Ti_y3^vi—Ca_x2—O8^xv	150.354 (11)	Ca_x3^xxxix—Fe_y1a—O6ⁱⁱ	62.28 (2)
Ti_y3^x—Ca_x2—Fe_y3^vi	102.672 (5)	Ca_x3^xxxix—Fe_y1a—O6^xxv	114.15 (4)
Ti_y3^x—Ca_x2—Fe_y3^x	0.0 (5)	Ca_x3^xxxix—Fe_y1a—O6^xxvi	48.62 (2)
Ti_y3^x—Ca_x2—Si_z2^xi	64.970 (4)	Ca_x3^xxxix—Fe_y1a—O6^xxvii	127.23 (5)
Ti_y3^x—Ca_x2—Si_z3^xii	119.708 (5)	Ca_x3^xxxix—Fe_y1a—Fe_y1b	50.357 (18)
Ti_y3^x—Ca_x2—O2^xi	93.065 (11)	Ca_x3^xxxix—Fe_y1a—Mg_y1a	0
Ti_y3^x—Ca_x2—O3^xiii	35.881 (10)	Ca_x3^xl—Fe_y1a—Ca_x4	129.643 (18)
Ti_y3^x—Ca_x2—O5^xii	129.052 (12)	Ca_x3^xl—Fe_y1a—O6ⁱⁱ	114.15 (4)
Ti_y3^x—Ca_x2—O5^xiv	152.921 (12)	Ca_x3^xl—Fe_y1a—O6^xxv	62.28 (2)
Ti_y3^x—Ca_x2—O8^xv	76.219 (10)	Ca_x3^xl—Fe_y1a—O6^xxvi	127.23 (5)
Fe_y3^vi—Ca_x2—Fe_y3^x	102.672 (5)	Ca_x3^xl—Fe_y1a—O6^xxvii	48.62 (2)
Fe_y3^vi—Ca_x2—Si_z2^xi	117.161 (5)	Ca_x3^xl—Fe_y1a—Fe_y1b	50.357 (18)
Fe_y3^vi—Ca_x2—Si_z3^xii	59.325 (5)	Ca_x3^xl—Fe_y1a—Mg_y1a	0
Fe_y3^vi—Ca_x2—O2^xi	99.828 (11)	Ca_x4—Fe_y1a—O6ⁱⁱ	92.52 (4)
Fe_y3^vi—Ca_x2—O3^xiii	79.506 (10)	Ca_x4—Fe_y1a—O6^xxv	92.52 (4)
Fe_y3^vi—Ca_x2—O5^xii	35.813 (12)	Ca_x4—Fe_y1a—O6^xxvi	92.52 (4)
Fe_y3^vi—Ca_x2—O5^xiv	98.952 (11)	Ca_x4—Fe_y1a—O6^xxvii	92.52 (4)
Fe_y3^vi—Ca_x2—O8^xv	150.354 (11)	Ca_x4—Fe_y1a—Fe_y1b	180.0 (5)
Fe_y3^x—Ca_x2—Si_z2^xi	64.970 (4)	Ca_x4—Fe_y1a—Mg_y1a	0
Fe_y3^x—Ca_x2—Si_z3^xii	119.708 (5)	O6ⁱⁱ—Fe_y1a—O6^xxv	174.96 (8)
Fe_y3^x—Ca_x2—O2^xi	93.065 (11)	O6ⁱⁱ—Fe_y1a—O6^xxvi	89.889 (19)
Fe_y3^x—Ca_x2—O3^xiii	35.881 (10)	O6ⁱⁱ—Fe_y1a—O6^xxvii	89.889 (19)
Fe_y3^x—Ca_x2—O5^xii	129.052 (12)	O6ⁱⁱ—Fe_y1a—Fe_y1b	87.48 (4)
Fe_y3^x—Ca_x2—O5^xiv	152.921 (12)	O6ⁱⁱ—Fe_y1a—Mg_y1a	0
Fe_y3^x—Ca_x2—O8^xv	76.219 (10)	O6^xxv—Fe_y1a—O6^xxvi	89.889 (19)
Si_z2^xi—Ca_x2—Si_z3^xii	174.136 (6)	O6^xxv—Fe_y1a—O6^xxvii	89.889 (19)
Si_z2^xi—Ca_x2—O2^xi	31.000 (11)	O6^xxv—Fe_y1a—Fe_y1b	87.48 (4)
Si_z2^xi—Ca_x2—O3^xiii	99.837 (11)	O6^xxv—Fe_y1a—Mg_y1a	0
Si_z2^xi—Ca_x2—O5^xii	144.947 (13)	O6^xxvi—Fe_y1a—O6^xxvii	174.96 (8)
Si_z2^xi—Ca_x2—O5^xiv	90.700 (12)	O6^xxvi—Fe_y1a—Fe_y1b	87.48 (4)
Si_z2^xi—Ca_x2—O8^xv	89.635 (11)	O6^xxvi—Fe_y1a—Mg_y1a	0
Si_z3^xii—Ca_x2—O2^xi	143.202 (11)	O6^xxvii—Fe_y1a—Fe_y1b	87.48 (4)
Si_z3^xii—Ca_x2—O3^xiii	84.339 (10)	O6^xxvii—Fe_y1a—Mg_y1a	0
Si_z3^xii—Ca_x2—O5^xii	29.633 (12)	Fe_y1b—Fe_y1a—Mg_y1a	0
Si_z3^xii—Ca_x2—O5^xiv	85.421 (12)	Ca_x3^xxxvii—Fe_y1b—Ca_x3^xxxviii	111.61 (2)
Si_z3^xii—Ca_x2—O8^xv	94.936 (11)	Ca_x3^xxxvii—Fe_y1b—Ca_x3^xxxix	71.585 (11)
O2^xi—Ca_x2—O3^xiii	123.991 (15)	Ca_x3^xxxvii—Fe_y1b—Ca_x3^xl	71.585 (11)
O2^xi—Ca_x2—O5^xii	116.466 (16)	Ca_x3^xxxvii—Fe_y1b—Ca_x4	124.197 (11)
O2^xi—Ca_x2—O5^xiv	67.137 (15)	Ca_x3^xxxvii—Fe_y1b—O6ⁱⁱ	138.78 (2)
O2^xi—Ca_x2—O8^xv	109.818 (15)	Ca_x3^xxxvii—Fe_y1b—O6^xxv	53.438 (15)
O3^xiii—Ca_x2—O5^xii	95.361 (15)	Ca_x3^xxxvii—Fe_y1b—O6^xxvi	67.221 (15)
O3^xiii—Ca_x2—O5^xiv	168.865 (16)	Ca_x3^xxxvii—Fe_y1b—O6^xxvii	122.936 (19)
O3^xiii—Ca_x2—O8^xv	83.778 (14)	Ca_x3^xxxvii—Fe_y1b—O10	55.803 (11)
O5^xii—Ca_x2—O5^xiv	77.685 (15)	Ca_x3^xxxvii—Fe_y1b—Fe_y1a	124.197 (11)
O5^xii—Ca_x2—O8^xv	123.472 (16)	Ca_x3^xxxvii—Fe_y1b—Mg_y1a	124.197 (11)
O5^xiv—Ca_x2—O8^xv	92.768 (15)	Ca_x3^xxxviii—Fe_y1b—Ca_x3^xxxix	71.585 (11)
Ca_x2^xxxvi—Ca_x3—Ca_x3^xvi	127.630 (5)	Ca_x3^xxxviii—Fe_y1b—Ca_x3^xl	71.585 (11)
Ca_x2^xxxvi—Ca_x3—Ca_x3^xvii	100.066 (4)	Ca_x3^xxxviii—Fe_y1b—Ca_x4	124.197 (11)
Ca_x2^xxxvi—Ca_x3—Ca_x3^xviii	128.034 (4)	Ca_x3^xxxviii—Fe_y1b—O6ⁱⁱ	53.438 (15)
Ca_x2^xxxvi—Ca_x3—Ca_x3^xix	155.002 (5)	Ca_x3^xxxviii—Fe_y1b—O6^xxv	138.78 (2)
Ca_x2^xxxvi—Ca_x3—Ca_x4^xx	76.600 (5)	Ca_x3^xxxviii—Fe_y1b—O6^xxvi	122.936 (19)
Ca_x2^xxxvi—Ca_x3—Al_y2^xxi	56.540 (3)	Ca_x3^xxxviii—Fe_y1b—O6^xxvii	67.221 (15)
Ca_x2^xxxvi—Ca_x3—Mg_y2^xxi	56.540 (3)	Ca_x3^xxxviii—Fe_y1b—O10	55.803 (11)
Ca_x2^xxxvi—Ca_x3—Al_y3^xxii	56.046 (3)	Ca_x3^xxxviii—Fe_y1b—Fe_y1a	124.197 (11)
Ca_x2^xxxvi—Ca_x3—Ti_y3^xxii	56.046 (3)	Ca_x3^xxxviii—Fe_y1b—Mg_y1a	124.197 (11)
Ca_x2^xxxvi—Ca_x3—Si_z2^xxiii	64.329 (4)	Ca_x3^xxxix—Fe_y1b—Ca_x3^xl	111.61 (2)
Ca_x2^xxxvi—Ca_x3—O7^xxiv	126.436 (12)	Ca_x3^xxxix—Fe_y1b—Ca_x4	124.197 (11)
Ca_x2^xxxvi—Ca_x3—Fe_y1a^xx	86.262 (18)	Ca_x3^xxxix—Fe_y1b—O6ⁱⁱ	67.221 (15)
Ca_x2^xxxvi—Ca_x3—Fe_y1b^xx	91.442 (11)	Ca_x3^xxxix—Fe_y1b—O6^xxv	122.936 (19)
Ca_x2^xxxvi—Ca_x3—Mg_y1a^xx	86.262 (18)	Ca_x3^xxxix—Fe_y1b—O6^xxvi	53.438 (15)
Ca_x3^xvi—Ca_x3—Ca_x3^xvii	90.000 (4)	Ca_x3^xxxix—Fe_y1b—O6^xxvii	138.78 (2)
Ca_x3^xvi—Ca_x3—Ca_x3^xviii	100.912 (4)	Ca_x3^xxxix—Fe_y1b—O10	55.803 (11)
Ca_x3^xvi—Ca_x3—Ca_x3^xix	64.736 (4)	Ca_x3^xxxix—Fe_y1b—Fe_y1a	124.197 (11)
Ca_x3^xvi—Ca_x3—Ca_x4^xx	62.852 (4)	Ca_x3^xxxix—Fe_y1b—Mg_y1a	124.197 (11)
Ca_x3^xvi—Ca_x3—Al_y2^xxi	98.890 (4)	Ca_x3^xl—Fe_y1b—Ca_x4	124.197 (11)
Ca_x3^xvi—Ca_x3—Mg_y2^xxi	98.890 (4)	Ca_x3^xl—Fe_y1b—O6ⁱⁱ	122.936 (19)
Ca_x3^xvi—Ca_x3—Al_y3^xxii	144.510 (5)	Ca_x3^xl—Fe_y1b—O6^xxv	67.221 (15)
Ca_x3^xvi—Ca_x3—Ti_y3^xxii	144.510 (5)	Ca_x3^xl—Fe_y1b—O6^xxvi	138.78 (2)
Ca_x3^xvi—Ca_x3—Si_z2^xxiii	154.628 (6)	Ca_x3^xl—Fe_y1b—O6^xxvii	53.438 (15)
Ca_x3^xvi—Ca_x3—O7^xxiv	42.689 (11)	Ca_x3^xl—Fe_y1b—O10	55.803 (11)
Ca_x3^xvi—Ca_x3—Fe_y1a^xx	57.009 (10)	Ca_x3^xl—Fe_y1b—Fe_y1a	124.197 (11)
Ca_x3^xvi—Ca_x3—Fe_y1b^xx	54.207 (6)	Ca_x3^xl—Fe_y1b—Mg_y1a	124.197 (11)
Ca_x3^xvi—Ca_x3—Mg_y1a^xx	57.009 (10)	Ca_x4—Fe_y1b—O6ⁱⁱ	82.00 (2)
Ca_x3^xvii—Ca_x3—Ca_x3^xviii	58.113 (4)	Ca_x4—Fe_y1b—O6^xxv	82.00 (2)
Ca_x3^xvii—Ca_x3—Ca_x3^xix	101.631 (5)	Ca_x4—Fe_y1b—O6^xxvi	82.00 (2)
Ca_x3^xvii—Ca_x3—Ca_x4^xx	62.852 (4)	Ca_x4—Fe_y1b—O6^xxvii	82.00 (2)
Ca_x3^xvii—Ca_x3—Al_y2^xxi	155.441 (5)	Ca_x4—Fe_y1b—O10	180.0 (5)
Ca_x3^xvii—Ca_x3—Mg_y2^xxi	155.441 (5)	Ca_x4—Fe_y1b—Fe_y1a	0.0 (5)
Ca_x3^xvii—Ca_x3—Al_y3^xxii	125.330 (5)	Ca_x4—Fe_y1b—Mg_y1a	0.0 (5)
Ca_x3^xvii—Ca_x3—Ti_y3^xxii	125.330 (5)	O6ⁱⁱ—Fe_y1b—O6^xxv	163.99 (4)
Ca_x3^xvii—Ca_x3—Si_z2^xxiii	64.872 (5)	O6ⁱⁱ—Fe_y1b—O6^xxvi	88.889 (19)
Ca_x3^xvii—Ca_x3—O7^xxiv	126.601 (12)	O6ⁱⁱ—Fe_y1b—O6^xxvii	88.889 (19)
Ca_x3^xvii—Ca_x3—Fe_y1a^xx	57.009 (10)	O6ⁱⁱ—Fe_y1b—O10	98.00 (2)
Ca_x3^xvii—Ca_x3—Fe_y1b^xx	54.207 (6)	O6ⁱⁱ—Fe_y1b—Fe_y1a	82.00 (2)
Ca_x3^xvii—Ca_x3—Mg_y1a^xx	57.009 (10)	O6ⁱⁱ—Fe_y1b—Mg_y1a	82.00 (2)
Ca_x3^xviii—Ca_x3—Ca_x3^xix	57.152 (4)	O6^xxv—Fe_y1b—O6^xxvi	88.889 (19)
Ca_x3^xviii—Ca_x3—Ca_x4^xx	118.532 (5)	O6^xxv—Fe_y1b—O6^xxvii	88.889 (19)
Ca_x3^xviii—Ca_x3—Al_y2^xxi	140.405 (4)	O6^xxv—Fe_y1b—O10	98.00 (2)
Ca_x3^xviii—Ca_x3—Mg_y2^xxi	140.405 (4)	O6^xxv—Fe_y1b—Fe_y1a	82.00 (2)
Ca_x3^xviii—Ca_x3—Al_y3^xxii	96.249 (4)	O6^xxv—Fe_y1b—Mg_y1a	82.00 (2)
Ca_x3^xviii—Ca_x3—Ti_y3^xxii	96.249 (4)	O6^xxvi—Fe_y1b—O6^xxvii	163.99 (4)
Ca_x3^xviii—Ca_x3—Si_z2^xxiii	63.719 (4)	O6^xxvi—Fe_y1b—O10	98.00 (2)
Ca_x3^xviii—Ca_x3—O7^xxiv	100.772 (11)	O6^xxvi—Fe_y1b—Fe_y1a	82.00 (2)
Ca_x3^xviii—Ca_x3—Fe_y1a^xx	110.092 (16)	O6^xxvi—Fe_y1b—Mg_y1a	82.00 (2)
Ca_x3^xviii—Ca_x3—Fe_y1b^xx	105.485 (10)	O6^xxvii—Fe_y1b—O10	98.00 (2)
Ca_x3^xviii—Ca_x3—Mg_y1a^xx	110.092 (16)	O6^xxvii—Fe_y1b—Fe_y1a	82.00 (2)
Ca_x3^xix—Ca_x3—Ca_x4^xx	124.801 (5)	O6^xxvii—Fe_y1b—Mg_y1a	82.00 (2)
Ca_x3^xix—Ca_x3—Al_y2^xxi	102.869 (4)	O10—Fe_y1b—Fe_y1a	180.0 (5)
Ca_x3^xix—Ca_x3—Mg_y2^xxi	102.869 (4)	O10—Fe_y1b—Mg_y1a	180.0 (5)
Ca_x3^xix—Ca_x3—Al_y3^xxii	100.699 (5)	Fe_y1a—Fe_y1b—Mg_y1a	0.0 (5)
Ca_x3^xix—Ca_x3—Ti_y3^xxii	100.699 (5)	Ca_x3^xxxvii—Mg_y1a—Ca_x3^xxxviii	100.71 (4)
Ca_x3^xix—Ca_x3—Si_z2^xxiii	114.881 (6)	Ca_x3^xxxvii—Mg_y1a—Ca_x3^xxxix	65.98 (2)
Ca_x3^xix—Ca_x3—O7^xxiv	44.068 (11)	Ca_x3^xxxvii—Mg_y1a—Ca_x3^xl	65.98 (2)
Ca_x3^xix—Ca_x3—Fe_y1a^xx	116.093 (16)	Ca_x3^xxxvii—Mg_y1a—Ca_x4	129.643 (18)
Ca_x3^xix—Ca_x3—Fe_y1b^xx	111.333 (10)	Ca_x3^xxxvii—Mg_y1a—Ca_x4ⁱⁱ	129.643 (18)
Ca_x3^xix—Ca_x3—Mg_y1a^xx	116.093 (16)	Ca_x3^xxxvii—Mg_y1a—O6ⁱⁱ	127.23 (5)
Ca_x4^xx—Ca_x3—Al_y2^xxi	100.998 (5)	Ca_x3^xxxvii—Mg_y1a—O6^xxv	48.62 (2)
Ca_x4^xx—Ca_x3—Mg_y2^xxi	100.998 (5)	Ca_x3^xxxvii—Mg_y1a—O6^xxvi	62.28 (2)
Ca_x4^xx—Ca_x3—Al_y3^xxii	132.425 (6)	Ca_x3^xxxvii—Mg_y1a—O6^xxvii	114.15 (4)
Ca_x4^xx—Ca_x3—Ti_y3^xxii	132.425 (6)	Ca_x3^xxxvii—Mg_y1a—Fe_y1a	0
Ca_x4^xx—Ca_x3—Si_z2^xxiii	105.206 (5)	Ca_x3^xxxvii—Mg_y1a—Fe_y1b	50.357 (18)
Ca_x4^xx—Ca_x3—O7^xxiv	100.561 (11)	Ca_x3^xxxviii—Mg_y1a—Ca_x3^xxxix	65.98 (2)
Ca_x4^xx—Ca_x3—Fe_y1a^xx	10.169 (19)	Ca_x3^xxxviii—Mg_y1a—Ca_x3^xl	65.98 (2)
Ca_x4^xx—Ca_x3—Fe_y1b^xx	15.614 (12)	Ca_x3^xxxviii—Mg_y1a—Ca_x4	129.643 (18)
Ca_x4^xx—Ca_x3—Mg_y1a^xx	10.169 (19)	Ca_x3^xxxviii—Mg_y1a—Ca_x4ⁱⁱ	129.643 (18)
Al_y2^xxi—Ca_x3—Mg_y2^xxi	0.0 (5)	Ca_x3^xxxviii—Mg_y1a—O6ⁱⁱ	48.62 (2)
Al_y2^xxi—Ca_x3—Al_y3^xxii	50.803 (3)	Ca_x3^xxxviii—Mg_y1a—O6^xxv	127.23 (5)
Al_y2^xxi—Ca_x3—Ti_y3^xxii	50.803 (3)	Ca_x3^xxxviii—Mg_y1a—O6^xxvi	114.15 (4)
Al_y2^xxi—Ca_x3—Si_z2^xxiii	105.587 (5)	Ca_x3^xxxviii—Mg_y1a—O6^xxvii	62.28 (2)
Al_y2^xxi—Ca_x3—O7^xxiv	72.292 (11)	Ca_x3^xxxviii—Mg_y1a—Fe_y1a	0
Al_y2^xxi—Ca_x3—Fe_y1a^xx	109.465 (15)	Ca_x3^xxxviii—Mg_y1a—Fe_y1b	50.357 (18)
Al_y2^xxi—Ca_x3—Fe_y1b^xx	113.921 (10)	Ca_x3^xxxix—Mg_y1a—Ca_x3^xl	100.71 (4)
Al_y2^xxi—Ca_x3—Mg_y1a^xx	109.465 (15)	Ca_x3^xxxix—Mg_y1a—Ca_x4	129.643 (18)
Mg_y2^xxi—Ca_x3—Al_y3^xxii	50.803 (3)	Ca_x3^xxxix—Mg_y1a—Ca_x4ⁱⁱ	129.643 (18)
Mg_y2^xxi—Ca_x3—Ti_y3^xxii	50.803 (3)	Ca_x3^xxxix—Mg_y1a—O6ⁱⁱ	62.28 (2)
Mg_y2^xxi—Ca_x3—Si_z2^xxiii	105.587 (5)	Ca_x3^xxxix—Mg_y1a—O6^xxv	114.15 (4)
Mg_y2^xxi—Ca_x3—O7^xxiv	72.292 (11)	Ca_x3^xxxix—Mg_y1a—O6^xxvi	48.62 (2)
Mg_y2^xxi—Ca_x3—Fe_y1a^xx	109.465 (15)	Ca_x3^xxxix—Mg_y1a—O6^xxvii	127.23 (5)
Mg_y2^xxi—Ca_x3—Fe_y1b^xx	113.921 (10)	Ca_x3^xxxix—Mg_y1a—Fe_y1a	0
Mg_y2^xxi—Ca_x3—Mg_y1a^xx	109.465 (15)	Ca_x3^xxxix—Mg_y1a—Fe_y1b	50.357 (18)
Al_y3^xxii—Ca_x3—Ti_y3^xxii	0.0 (5)	Ca_x3^xl—Mg_y1a—Ca_x4	129.643 (18)
Al_y3^xxii—Ca_x3—Si_z2^xxiii	60.458 (5)	Ca_x3^xl—Mg_y1a—Ca_x4ⁱⁱ	129.643 (18)
Al_y3^xxii—Ca_x3—O7^xxiv	103.716 (12)	Ca_x3^xl—Mg_y1a—O6ⁱⁱ	114.15 (4)
Al_y3^xxii—Ca_x3—Fe_y1a^xx	142.277 (18)	Ca_x3^xl—Mg_y1a—O6^xxv	62.28 (2)
Al_y3^xxii—Ca_x3—Fe_y1b^xx	147.487 (12)	Ca_x3^xl—Mg_y1a—O6^xxvi	127.23 (5)
Al_y3^xxii—Ca_x3—Mg_y1a^xx	142.277 (18)	Ca_x3^xl—Mg_y1a—O6^xxvii	48.62 (2)
Ti_y3^xxii—Ca_x3—Si_z2^xxiii	60.458 (5)	Ca_x3^xl—Mg_y1a—Fe_y1a	0
Ti_y3^xxii—Ca_x3—O7^xxiv	103.716 (12)	Ca_x3^xl—Mg_y1a—Fe_y1b	50.357 (18)
Ti_y3^xxii—Ca_x3—Fe_y1a^xx	142.277 (18)	Ca_x4—Mg_y1a—Ca_x4ⁱⁱ	0.0 (5)
Ti_y3^xxii—Ca_x3—Fe_y1b^xx	147.487 (12)	Ca_x4—Mg_y1a—O6ⁱⁱ	92.52 (4)
Ti_y3^xxii—Ca_x3—Mg_y1a^xx	142.277 (18)	Ca_x4—Mg_y1a—O6^xxv	92.52 (4)
Si_z2^xxiii—Ca_x3—O7^xxiv	154.006 (13)	Ca_x4—Mg_y1a—O6^xxvi	92.52 (4)
Si_z2^xxiii—Ca_x3—Fe_y1a^xx	107.296 (6)	Ca_x4—Mg_y1a—O6^xxvii	92.52 (4)
Si_z2^xxiii—Ca_x3—Fe_y1b^xx	108.197 (5)	Ca_x4—Mg_y1a—Fe_y1a	0
Si_z2^xxiii—Ca_x3—Mg_y1a^xx	107.296 (6)	Ca_x4—Mg_y1a—Fe_y1b	180.0 (5)
O7^xxiv—Ca_x3—Fe_y1a^xx	97.492 (13)	Ca_x4ⁱⁱ—Mg_y1a—O6ⁱⁱ	92.52 (4)
O7^xxiv—Ca_x3—Fe_y1b^xx	95.754 (12)	Ca_x4ⁱⁱ—Mg_y1a—O6^xxv	92.52 (4)
O7^xxiv—Ca_x3—Mg_y1a^xx	97.492 (13)	Ca_x4ⁱⁱ—Mg_y1a—O6^xxvi	92.52 (4)
Fe_y1a^xx—Ca_x3—Fe_y1b^xx	5.45 (2)	Ca_x4ⁱⁱ—Mg_y1a—O6^xxvii	92.52 (4)
Fe_y1a^xx—Ca_x3—Mg_y1a^xx	0.0 (5)	Ca_x4ⁱⁱ—Mg_y1a—Fe_y1a	0
Fe_y1b^xx—Ca_x3—Mg_y1a^xx	5.45 (2)	Ca_x4ⁱⁱ—Mg_y1a—Fe_y1b	180.0 (5)
Ca_x3^xxxvii—Ca_x4—Ca_x3^xxxviii	80.376 (9)	O6ⁱⁱ—Mg_y1a—O6^xxv	174.96 (8)
Ca_x3^xxxvii—Ca_x4—Ca_x3^xxxix	54.297 (6)	O6ⁱⁱ—Mg_y1a—O6^xxvi	89.889 (19)
Ca_x3^xxxvii—Ca_x4—Ca_x3^xl	54.297 (6)	O6ⁱⁱ—Mg_y1a—O6^xxvii	89.889 (19)
Ca_x3^xxxvii—Ca_x4—Ca_x4ⁱⁱ	139.812 (5)	O6ⁱⁱ—Mg_y1a—Fe_y1a	0
Ca_x3^xxxvii—Ca_x4—Si_z3ⁱⁱ	109.663 (10)	O6ⁱⁱ—Mg_y1a—Fe_y1b	87.48 (4)
Ca_x3^xxxvii—Ca_x4—Si_z3^xxv	67.498 (7)	O6^xxv—Mg_y1a—O6^xxvi	89.889 (19)
Ca_x3^xxxvii—Ca_x4—Si_z3^xxvi	56.043 (6)	O6^xxv—Mg_y1a—O6^xxvii	89.889 (19)
Ca_x3^xxxvii—Ca_x4—Si_z3^xxvii	120.820 (12)	O6^xxv—Mg_y1a—Fe_y1a	0
Ca_x3^xxxvii—Ca_x4—O6ⁱⁱ	98.333 (18)	O6^xxv—Mg_y1a—Fe_y1b	87.48 (4)
Ca_x3^xxxvii—Ca_x4—O6^xxv	35.820 (13)	O6^xxvi—Mg_y1a—O6^xxvii	174.96 (8)
Ca_x3^xxxvii—Ca_x4—O6^xxvi	48.471 (14)	O6^xxvi—Mg_y1a—Fe_y1a	0
Ca_x3^xxxvii—Ca_x4—O6^xxvii	89.832 (17)	O6^xxvi—Mg_y1a—Fe_y1b	87.48 (4)
Ca_x3^xxxvii—Ca_x4—Fe_y1a	40.188 (5)	O6^xxvii—Mg_y1a—Fe_y1a	0
Ca_x3^xxxvii—Ca_x4—Fe_y1b	40.188 (5)	O6^xxvii—Mg_y1a—Fe_y1b	87.48 (4)
Ca_x3^xxxvii—Ca_x4—Mg_y1a	40.188 (5)	Fe_y1a—Mg_y1a—Fe_y1b	0
Ca_x3^xxxvii—Ca_x4—Mg_y1aⁱⁱ	139.812 (5)

Symmetry codes: (i) −x+3/2, −y+1/2, z; (ii) −x+3/2, y, −z+1/2; (iii) x, −y+1/2, −z+1/2; (iv) x+1, y, z; (v) −x+1/2, −y+1/2, z; (vi) −x+1/2, y, −z+1/2; (vii) x+1, −y+1/2, −z+1/2; (viii) y, x−1, −z+3/2; (ix) y+1, x, −z+1/2; (x) −y+1, −x, z+1/2; (xi) −y+1, −x+1, z−1/2; (xii) −y+3/2, x−1, z; (xiii) −x+3/2, y, −z+3/2; (xiv) y, x−1, −z+1/2; (xv) x, y−1, z; (xvi) −y+3/2, x, z; (xvii) y, −x+3/2, z; (xviii) x, −y+3/2, −z+3/2; (xix) y, x, −z+3/2; (xx) x, y, z+1; (xxi) x+1, y+1, z+1; (xxii) −x+1, −y+1, −z+1; (xxiii) y+1, −x+3/2, z; (xxiv) x, y+1, z; (xxv) x, −y+3/2, −z+1/2; (xxvi) y, x, −z+1/2; (xxvii) −y+3/2, −x+3/2, −z+1/2; (xxviii) −x, −y, −z; (xxix) x−1, y, z−1; (xxx) −x+1, −y, −z+1; (xxxi) y−1, x−1, −z+1/2; (xxxii) −y, −x+1, z−1/2; (xxxiii) −y, x−1/2, −z+1; (xxxiv) y+1/2, −x+1, −z; (xxxv) −y+1, x−1/2, −z; (xxxvi) y+1, x, −z+3/2; (xxxvii) x, y, z−1; (xxxviii) −x+3/2, −y+3/2, z−1; (xxxix) −y+3/2, x, z−1; (xl) y, −x+3/2, z−1; (xli) x−1, y−1, z−1; (xlii) x−1, y, z; (xliii) −y+1, −x+1, z+1/2; (xliv) y+1/2, −x, −z+1; (xlv) x+1, y, z+1; (xlvi) y+1, x+1, −z+1/2.

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