{4-[(1-Naphthyl)­vinyl]­phenyl}di-p-tolyl­amine

Cao, X.-D.; Liu, D.-Z.; Zhou, X.-Q.; Sun, S.-F.

doi:10.1107/S1600536803025285

{4-[(1-Naphthyl)vinyl]phenyl}di-p-tolylamine

X.-D. Cao, D.-Z. Liu, X.-Q. Zhou and S.-F. Sun

The title compound, C₃₂H₂₇N, was synthesized via the Ullmann reaction. The structure has a pseudo-twofold axis approximately parallel to the b axis, and hence the pseudo-space group C2/c. The crystal packing is stabilized by weak C—H

π and and van der Waals interactions.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803025285/ci6291sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536803025285/ci6291Isup2.hkl Contains datablock I

CCDC reference: 227881

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.010 Å
R factor = 0.056
wR factor = 0.154
Data-to-parameter ratio = 7.1

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT111_ALERT_2_B ADDSYM Detects (Pseudo) Centre of Symmetry .....         81 PerFit
PLAT113_ALERT_2_B ADDSYM Suggests Possible Pseudo/New Spacegroup .       C2/c

Alert level C
PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical .          ?
PLAT089_ALERT_3_C Poor Data / Parameter Ratio (Zmax .LT. 18) .....       7.10
PLAT220_ALERT_2_C Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       2.96 Ratio
PLAT242_ALERT_2_C Check Low    U(eq) as Compared to Neighbors ....        C11
PLAT340_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ...         10

Alert level G
REFLT03_ALERT_4_G Please check that the estimate of the number of Friedel pairs is
            correct. If it is not, please give the correct count in the
            _publ_section_exptl_refinement section of the submitted CIF.
           From the CIF: _diffrn_reflns_theta_max           25.00
           From the CIF: _reflns_number_total               2130
           Count of symmetry unique reflns         2131
           Completeness (_total/calc)             99.95%
           TEST3: Check Friedels for noncentro structure
           Estimate of Friedel pairs measured         0
           Fraction of Friedel pairs measured     0.000
           Are heavy atom types Z>Si present           no

   0 ALERT level A = In general: serious problem
   2 ALERT level B = Potentially serious problem
   5 ALERT level C = Check and explain
   1 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   4 ALERT type 2 Indicator that the structure model may be wrong or deficient
   2 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 1997); cell refinement: SMART; data reduction: SAINT (Bruker, 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXTL.

{4-[(1-Naphthyl)vinyl]phenyl}di-p-tolylamine top

Crystal data top

C₃₂H₂₇N	F(000) = 904
M_r = 425.55	D_x = 1.167 Mg m⁻³
Monoclinic, Cc	Melting point = 383–386 K
Hall symbol: C -2yc	Mo Kα radiation, λ = 0.71073 Å
a = 18.482 (7) Å	Cell parameters from 724 reflections
b = 17.045 (7) Å	θ = 2.4–21.7°
c = 8.635 (3) Å	µ = 0.07 mm⁻¹
β = 117.094 (5)°	T = 293 K
V = 2421.9 (16) Å³	Plate, yellow
Z = 4	0.40 × 0.34 × 0.28 mm

Data collection top

Bruker SMART CCD area-detector diffractometer	2130 independent reflections
Radiation source: fine-focus sealed tube	1453 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.028
ω scans	θ_max = 25.0°, θ_min = 1.7°
Absorption correction: multi-scan (SADABS; Bruker, 1997)	h = −21→21
T_min = 0.973, T_max = 0.981	k = −20→10
5052 measured reflections	l = −10→7

Refinement top

Refinement on F²	74 restraints
Least-squares matrix: full	H-atom parameters constrained
R[F² > 2σ(F²)] = 0.056	w = 1/[σ²(F_o²) + (0.0877P)² + 0.2832P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.154	(Δ/σ)_max = 0.001
S = 1.06	Δρ_max = 0.18 e Å⁻³
2130 reflections	Δρ_min = −0.17 e Å⁻³
300 parameters

Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
N1	0.1212 (3)	0.18419 (18)	0.4176 (7)	0.0544 (9)
C1	0.1941 (3)	0.1443 (3)	0.4472 (6)	0.0491 (12)
C2	0.2680 (3)	0.1696 (3)	0.5739 (7)	0.0623 (14)
H2	0.2708	0.2120	0.6443	0.075*
C3	0.3376 (3)	0.1319 (4)	0.5954 (8)	0.0720 (16)
H3	0.3873	0.1500	0.6807	0.086*
C4	0.3367 (3)	0.0693 (3)	0.4971 (8)	0.0643 (15)
C5	0.2617 (3)	0.0437 (3)	0.3715 (7)	0.0646 (15)
H5	0.2588	0.0006	0.3027	0.078*
C6	0.1911 (3)	0.0811 (3)	0.3471 (7)	0.0570 (13)
H6	0.1413	0.0633	0.2620	0.068*
C7	0.4135 (4)	0.0291 (5)	0.5208 (11)	0.101 (2)
H7A	0.4543	0.0678	0.5383	0.152*
H7B	0.4029	−0.0012	0.4190	0.152*
H7C	0.4325	−0.0048	0.6203	0.152*
C8	0.0517 (3)	0.1396 (3)	0.3910 (7)	0.0517 (13)
C9	0.0576 (3)	0.0757 (4)	0.4948 (8)	0.0739 (17)
H9	0.1079	0.0621	0.5849	0.089*
C10	−0.0097 (4)	0.0320 (4)	0.4670 (9)	0.0780 (17)
H10	−0.0039	−0.0106	0.5388	0.094*
C11	−0.0845 (3)	0.0496 (3)	0.3367 (7)	0.0608 (14)
C12	−0.0916 (3)	0.1139 (4)	0.2354 (7)	0.0658 (15)
H12	−0.1425	0.1280	0.1483	0.079*
C13	−0.0241 (3)	0.1584 (3)	0.2602 (7)	0.0592 (14)
H13	−0.0302	0.2011	0.1882	0.071*
C14	−0.1582 (4)	0.0004 (4)	0.3066 (9)	0.090 (2)
H14A	−0.2065	0.0257	0.2221	0.135*
H14B	−0.1614	−0.0052	0.4140	0.135*
H14C	−0.1534	−0.0505	0.2645	0.135*
C15	0.1190 (3)	0.2659 (2)	0.4240 (7)	0.0477 (10)
C16	0.0721 (3)	0.3039 (3)	0.4874 (7)	0.0539 (13)
H16	0.0416	0.2744	0.5270	0.065*
C17	0.0694 (3)	0.3846 (3)	0.4937 (7)	0.0595 (13)
H17	0.0364	0.4081	0.5354	0.071*
C18	0.1148 (3)	0.4313 (3)	0.4393 (7)	0.0540 (12)
C19	0.1629 (3)	0.3932 (3)	0.3758 (6)	0.0554 (13)
H19	0.1943	0.4227	0.3386	0.066*
C20	0.1642 (3)	0.3126 (3)	0.3677 (6)	0.0530 (13)
H20	0.1962	0.2887	0.3235	0.064*
C21	0.1092 (3)	0.5166 (3)	0.4529 (7)	0.0614 (13)
H21	0.0739	0.5345	0.4948	0.074*
C22	0.1483 (3)	0.5707 (3)	0.4125 (7)	0.0672 (15)
H22	0.1846	0.5540	0.3721	0.081*
C23	0.1394 (4)	0.6557 (3)	0.4263 (8)	0.0688 (18)
C24	0.0682 (5)	0.6879 (4)	0.4052 (9)	0.092 (2)
H24	0.0247	0.6548	0.3845	0.111*
C25	0.0578 (7)	0.7689 (6)	0.4132 (11)	0.114 (3)
H25	0.0082	0.7888	0.3980	0.137*
C26	0.1182 (9)	0.8166 (5)	0.4421 (13)	0.118 (3)
H26	0.1102	0.8703	0.4452	0.141*
C27	0.1936 (7)	0.7895 (4)	0.4682 (10)	0.100 (2)
C28	0.2058 (5)	0.7066 (3)	0.4607 (8)	0.0794 (18)
C29	0.2826 (5)	0.6806 (4)	0.4872 (9)	0.094 (2)
H29	0.2899	0.6271	0.4786	0.112*
C30	0.3481 (6)	0.7299 (5)	0.5254 (11)	0.127 (3)
H30	0.3981	0.7107	0.5415	0.152*
C31	0.3353 (7)	0.8110 (6)	0.5387 (13)	0.140 (3)
H31	0.3782	0.8458	0.5679	0.168*
C32	0.2614 (8)	0.8386 (5)	0.5097 (12)	0.125 (3)
H32	0.2552	0.8924	0.5175	0.150*

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
N1	0.0410 (18)	0.0349 (18)	0.087 (3)	0.000 (2)	0.0293 (17)	0.001 (2)
C1	0.042 (3)	0.043 (3)	0.060 (3)	0.002 (2)	0.020 (3)	0.003 (2)
C2	0.054 (3)	0.055 (3)	0.072 (4)	0.000 (3)	0.024 (3)	−0.010 (3)
C3	0.044 (3)	0.067 (4)	0.085 (4)	−0.001 (3)	0.012 (3)	−0.001 (3)
C4	0.050 (3)	0.065 (4)	0.082 (4)	0.014 (3)	0.034 (3)	0.013 (3)
C5	0.063 (4)	0.056 (3)	0.076 (4)	0.011 (3)	0.033 (3)	0.000 (3)
C6	0.046 (3)	0.044 (3)	0.070 (3)	−0.005 (2)	0.017 (3)	−0.006 (2)
C7	0.068 (4)	0.105 (5)	0.136 (6)	0.025 (4)	0.051 (4)	0.006 (4)
C8	0.047 (3)	0.040 (3)	0.073 (4)	0.001 (2)	0.031 (3)	0.000 (3)
C9	0.044 (3)	0.075 (4)	0.091 (4)	−0.001 (3)	0.021 (3)	0.024 (3)
C10	0.064 (4)	0.068 (4)	0.096 (4)	−0.004 (3)	0.031 (3)	0.022 (3)
C11	0.054 (3)	0.063 (3)	0.068 (4)	−0.010 (3)	0.030 (3)	−0.008 (3)
C12	0.045 (3)	0.078 (4)	0.064 (3)	−0.002 (3)	0.016 (3)	−0.012 (3)
C13	0.054 (3)	0.056 (3)	0.064 (4)	0.006 (3)	0.023 (3)	0.005 (2)
C14	0.068 (4)	0.097 (5)	0.107 (5)	−0.030 (4)	0.041 (4)	−0.019 (4)
C15	0.042 (2)	0.042 (2)	0.058 (2)	0.000 (2)	0.0220 (19)	0.001 (3)
C16	0.059 (3)	0.047 (3)	0.065 (3)	0.001 (2)	0.036 (3)	0.001 (2)
C17	0.061 (3)	0.055 (3)	0.066 (3)	0.006 (3)	0.032 (3)	−0.002 (3)
C18	0.044 (3)	0.045 (3)	0.059 (3)	−0.002 (3)	0.011 (2)	−0.006 (2)
C19	0.051 (3)	0.048 (3)	0.063 (3)	−0.007 (2)	0.022 (3)	0.013 (3)
C20	0.049 (3)	0.053 (3)	0.061 (3)	−0.001 (2)	0.029 (3)	−0.002 (2)
C21	0.052 (3)	0.062 (3)	0.069 (3)	0.003 (3)	0.026 (2)	0.002 (3)
C22	0.077 (4)	0.056 (3)	0.064 (3)	0.000 (3)	0.029 (3)	−0.002 (3)
C23	0.107 (6)	0.043 (3)	0.055 (3)	0.015 (3)	0.035 (3)	0.000 (3)
C24	0.133 (6)	0.058 (4)	0.087 (5)	0.023 (4)	0.051 (4)	0.006 (3)
C25	0.146 (7)	0.103 (6)	0.097 (5)	0.038 (5)	0.059 (5)	−0.001 (4)
C26	0.174 (7)	0.073 (4)	0.101 (5)	0.013 (6)	0.058 (5)	0.002 (4)
C27	0.159 (6)	0.069 (4)	0.075 (4)	−0.024 (5)	0.057 (4)	−0.004 (4)
C28	0.140 (6)	0.046 (3)	0.056 (3)	−0.007 (4)	0.047 (4)	−0.003 (3)
C29	0.119 (6)	0.072 (4)	0.091 (5)	−0.019 (4)	0.049 (4)	−0.009 (4)
C30	0.166 (7)	0.105 (5)	0.110 (5)	−0.046 (5)	0.064 (5)	−0.016 (4)
C31	0.177 (7)	0.114 (6)	0.125 (6)	−0.061 (6)	0.064 (6)	−0.015 (5)
C32	0.193 (8)	0.074 (4)	0.103 (5)	−0.027 (5)	0.063 (5)	−0.012 (4)

Geometric parameters (Å, º) top

N1—C15	1.395 (5)	C15—C20	1.393 (7)
N1—C8	1.417 (6)	C16—C17	1.377 (7)
N1—C1	1.425 (6)	C16—H16	0.93
C1—C6	1.367 (7)	C17—C18	1.384 (7)
C1—C2	1.374 (7)	C17—H17	0.93
C2—C3	1.373 (8)	C18—C19	1.398 (7)
C2—H2	0.93	C18—C21	1.467 (7)
C3—C4	1.360 (8)	C19—C20	1.377 (7)
C3—H3	0.93	C19—H19	0.93
C4—C5	1.386 (8)	C20—H20	0.93
C4—C7	1.503 (8)	C21—C22	1.314 (7)
C5—C6	1.378 (7)	C21—H21	0.93
C5—H5	0.93	C22—C23	1.469 (7)
C6—H6	0.93	C22—H22	0.93
C7—H7A	0.96	C23—C24	1.358 (9)
C7—H7B	0.96	C23—C28	1.419 (9)
C7—H7C	0.96	C24—C25	1.401 (11)
C8—C13	1.378 (7)	C24—H24	0.93
C8—C9	1.384 (8)	C25—C26	1.309 (13)
C9—C10	1.374 (8)	C25—H25	0.93
C9—H9	0.93	C26—C27	1.386 (14)
C10—C11	1.361 (8)	C26—H26	0.93
C10—H10	0.93	C27—C32	1.412 (13)
C11—C12	1.370 (8)	C27—C28	1.435 (9)
C11—C14	1.518 (7)	C28—C29	1.403 (10)
C12—C13	1.391 (7)	C29—C30	1.385 (10)
C12—H12	0.93	C29—H29	0.93
C13—H13	0.93	C30—C31	1.415 (13)
C14—H14A	0.96	C30—H30	0.93
C14—H14B	0.96	C31—C32	1.355 (12)
C14—H14C	0.96	C31—H31	0.93
C15—C16	1.379 (7)	C32—H32	0.93

C15—N1—C8	120.1 (4)	C20—C15—N1	121.5 (4)
C15—N1—C1	120.8 (4)	C17—C16—C15	121.7 (5)
C8—N1—C1	119.1 (3)	C17—C16—H16	119.1
C6—C1—C2	119.4 (5)	C15—C16—H16	119.1
C6—C1—N1	120.0 (5)	C16—C17—C18	121.4 (5)
C2—C1—N1	120.6 (4)	C16—C17—H17	119.3
C3—C2—C1	119.4 (5)	C18—C17—H17	119.3
C3—C2—H2	120.3	C17—C18—C19	117.2 (4)
C1—C2—H2	120.3	C17—C18—C21	117.9 (5)
C4—C3—C2	122.6 (6)	C19—C18—C21	124.9 (4)
C4—C3—H3	118.7	C20—C19—C18	120.9 (4)
C2—C3—H3	118.7	C20—C19—H19	119.6
C3—C4—C5	117.3 (5)	C18—C19—H19	119.6
C3—C4—C7	122.0 (6)	C19—C20—C15	121.6 (4)
C5—C4—C7	120.7 (6)	C19—C20—H20	119.2
C6—C5—C4	120.9 (5)	C15—C20—H20	119.2
C6—C5—H5	119.5	C22—C21—C18	127.4 (5)
C4—C5—H5	119.5	C22—C21—H21	116.3
C1—C6—C5	120.3 (5)	C18—C21—H21	116.3
C1—C6—H6	119.8	C21—C22—C23	125.1 (5)
C5—C6—H6	119.8	C21—C22—H22	117.5
C4—C7—H7A	109.5	C23—C22—H22	117.5
C4—C7—H7B	109.5	C24—C23—C28	118.3 (6)
H7A—C7—H7B	109.5	C24—C23—C22	121.7 (6)
C4—C7—H7C	109.5	C28—C23—C22	120.1 (6)
H7A—C7—H7C	109.5	C23—C24—C25	122.5 (8)
H7B—C7—H7C	109.5	C23—C24—H24	118.8
C13—C8—C9	117.6 (5)	C25—C24—H24	118.8
C13—C8—N1	121.1 (5)	C26—C25—C24	119.8 (9)
C9—C8—N1	121.3 (5)	C26—C25—H25	120.1
C10—C9—C8	121.1 (5)	C24—C25—H25	120.1
C10—C9—H9	119.5	C25—C26—C27	122.0 (8)
C8—C9—H9	119.5	C25—C26—H26	119.0
C11—C10—C9	121.6 (6)	C27—C26—H26	119.0
C11—C10—H10	119.2	C26—C27—C32	123.7 (9)
C9—C10—H10	119.2	C26—C27—C28	119.1 (8)
C10—C11—C12	118.0 (5)	C32—C27—C28	117.1 (9)
C10—C11—C14	121.0 (6)	C29—C28—C23	123.7 (5)
C12—C11—C14	121.0 (6)	C29—C28—C27	118.1 (7)
C11—C12—C13	121.3 (5)	C23—C28—C27	118.2 (7)
C11—C12—H12	119.3	C30—C29—C28	123.9 (7)
C13—C12—H12	119.3	C30—C29—H29	118.1
C8—C13—C12	120.4 (5)	C28—C29—H29	118.1
C8—C13—H13	119.8	C29—C30—C31	116.8 (9)
C12—C13—H13	119.8	C29—C30—H30	121.6
C11—C14—H14A	109.5	C31—C30—H30	121.6
C11—C14—H14B	109.5	C32—C31—C30	121.1 (9)
H14A—C14—H14B	109.5	C32—C31—H31	119.4
C11—C14—H14C	109.5	C30—C31—H31	119.4
H14A—C14—H14C	109.5	C31—C32—C27	122.9 (9)
H14B—C14—H14C	109.5	C31—C32—H32	118.5
C16—C15—C20	117.2 (4)	C27—C32—H32	118.5
C16—C15—N1	121.3 (5)

C15—N1—C1—C6	−139.1 (5)	C15—C16—C17—C18	−1.2 (8)
C8—N1—C1—C6	44.4 (7)	C16—C17—C18—C19	0.7 (8)
C15—N1—C1—C2	39.7 (8)	C16—C17—C18—C21	−179.1 (5)
C8—N1—C1—C2	−136.9 (5)	C17—C18—C19—C20	0.3 (8)
C6—C1—C2—C3	1.1 (8)	C21—C18—C19—C20	−179.9 (5)
N1—C1—C2—C3	−177.6 (5)	C18—C19—C20—C15	−0.8 (8)
C1—C2—C3—C4	−0.7 (9)	C16—C15—C20—C19	0.4 (8)
C2—C3—C4—C5	−0.2 (9)	N1—C15—C20—C19	−179.2 (5)
C2—C3—C4—C7	179.3 (6)	C17—C18—C21—C22	178.3 (6)
C3—C4—C5—C6	0.6 (8)	C19—C18—C21—C22	−1.5 (10)
C7—C4—C5—C6	−178.8 (6)	C18—C21—C22—C23	179.0 (5)
C2—C1—C6—C5	−0.7 (8)	C21—C22—C23—C24	−30.6 (10)
N1—C1—C6—C5	178.1 (5)	C21—C22—C23—C28	150.1 (5)
C4—C5—C6—C1	−0.2 (8)	C28—C23—C24—C25	1.1 (10)
C15—N1—C8—C13	48.1 (7)	C22—C23—C24—C25	−178.3 (6)
C1—N1—C8—C13	−135.4 (5)	C23—C24—C25—C26	0.0 (12)
C15—N1—C8—C9	−132.1 (6)	C24—C25—C26—C27	−1.0 (14)
C1—N1—C8—C9	44.5 (8)	C25—C26—C27—C32	−176.2 (7)
C13—C8—C9—C10	0.8 (9)	C25—C26—C27—C28	0.9 (13)
N1—C8—C9—C10	−179.1 (6)	C24—C23—C28—C29	179.2 (6)
C8—C9—C10—C11	0.0 (10)	C22—C23—C28—C29	−1.5 (9)
C9—C10—C11—C12	−1.5 (9)	C24—C23—C28—C27	−1.1 (8)
C9—C10—C11—C14	179.5 (6)	C22—C23—C28—C27	178.2 (5)
C10—C11—C12—C13	2.2 (8)	C26—C27—C28—C29	179.9 (8)
C14—C11—C12—C13	−178.8 (5)	C32—C27—C28—C29	−2.8 (9)
C9—C8—C13—C12	−0.1 (7)	C26—C27—C28—C23	0.2 (9)
N1—C8—C13—C12	179.8 (5)	C32—C27—C28—C23	177.5 (7)
C11—C12—C13—C8	−1.4 (8)	C23—C28—C29—C30	−178.2 (6)
C8—N1—C15—C16	31.6 (8)	C27—C28—C29—C30	2.1 (10)
C1—N1—C15—C16	−144.9 (5)	C28—C29—C30—C31	0.4 (11)
C8—N1—C15—C20	−148.8 (5)	C29—C30—C31—C32	−2.1 (13)
C1—N1—C15—C20	34.7 (8)	C30—C31—C32—C27	1.2 (14)
C20—C15—C16—C17	0.6 (9)	C26—C27—C32—C31	178.4 (9)
N1—C15—C16—C17	−179.8 (5)	C28—C27—C32—C31	1.3 (12)

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
C2—H2···Cg3ⁱ	0.93	3.09	3.835 (7)	138
C10—H10···Cg1ⁱⁱ	0.93	3.26	4.107 (8)	153
C16—H16···Cg2ⁱ	0.93	3.15	3.586 (6)	111
C20—H20···Cg2ⁱⁱⁱ	0.93	3.03	3.592 (6)	121
C30—H30···Cg1^iv	0.93	3.30	4.079 (11)	142

Symmetry codes: (i) x, −y+1, z+1/2; (ii) x, −y, z+1/2; (iii) x, −y+1, z−1/2; (iv) x+1/2, y+1/2, z.

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{4-[(1-Naphthyl)­vinyl]­phenyl}di-p-tolyl­amine

Supporting information

Key indicators

checkCIF/PLATON results

{4-[(1-Naphthyl)vinyl]phenyl}di-p-tolylamine