Crystal-Like Nature of Acoustic Excitations in Glassy Ethanol

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, L. Börjesson, S. C. Santucci, and R. Verbeni
Phys. Rev. Lett. 93, 145502 – Published 30 September 2004

Abstract

We report on inelastic x-ray scattering experiments on crystalline and glassy phases of ethanol in order to directly compare the influence of disorder on high frequency acoustic excitations. We find that both the dispersion and the line-width of the longitudinal acoustic excitations in the glass are the same as in the polycrystal in the reciprocal space portion covering the 1st and 2nd Brillouin zones. The structural disorder is found to play little role apart from an intrinsic angular averaging, and the nature of these excitations must essentially be the same in both glass and poly crystal.

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  • Received 1 April 2004

DOI:https://doi.org/10.1103/PhysRevLett.93.145502

©2004 American Physical Society

Authors & Affiliations

A. Matic1, C. Masciovecchio2, D. Engberg1, G. Monaco3, L. Börjesson1, S. C. Santucci2, and R. Verbeni3

  • 1Department of Applied Physics, Chalmers University of Technology, SE-41296 Göteborg, Sweden
  • 2Sincrotrone Trieste, I-34012 Basovizza, Trieste, Italy
  • 3European Synchrotron Radiation Facility, BP-220, F-38043 Grenoble, France

Comments & Replies

Comment on “Crystal-Like Nature of Acoustic Excitations in Glassy Ethanol”

F. J. Bermejo, R. Fernandez-Perea, and A. V. Krivchikov
Phys. Rev. Lett. 98, 229601 (2007)

Matic et al. Reply:

A. Matic, C. Masciovecchio, D. Engberg, G. Monaco, and L. Börjesson
Phys. Rev. Lett. 98, 229602 (2007)

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Vol. 93, Iss. 14 — 1 October 2004

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