Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes

L. C. Lin, H. F. Meng, J. T. Shy, S. F. Horng, L. S. Yu, C. H. Chen, H. H. Liaw, C. C. Huang, K. Y. Peng, and S. A. Chen
Phys. Rev. Lett. 90, 036601 – Published 23 January 2003

Abstract

The triplet to singlet exciton formation ratio in a MEH-PPV light-emitting diode is measured by comparing the triplet-induced absorptions with optical and electric excitations at the same singlet exciton density. The ratio is a strong universal decreasing function of the averaged electric field. Using 4 ns for singlet to triplet intersystem crossing time, the ratio is significantly larger than the spin-independent value 3 at intermediate field but is reduced to about 2 for higher field.

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  • Received 29 August 2002

DOI:https://doi.org/10.1103/PhysRevLett.90.036601

©2003 American Physical Society

Authors & Affiliations

L. C. Lin1, H. F. Meng1,*, J. T. Shy2, S. F. Horng3, L. S. Yu4, C. H. Chen1, H. H. Liaw1, C. C. Huang1, K. Y. Peng4, and S. A. Chen4

  • 1Institute of Physics, National Chiao Tung University, Hsinchu 300, Taiwan, Republic of China
  • 2Department of Physics, National Tsing Hua University, Hsinchu 300, Taiwan, Republic of China
  • 3Department of Electric Engineering, National Tsing Hua University, Hsinchu 300, Taiwan, Republic of China
  • 4Department of Chemical Engineering, National Tsing Hua University, Hsinchu 300, Taiwan, Republic of China

  • *Corresponding author. Electronic address: meng@cc.nctu.edu.tw

Comments & Replies

Lin et al. Reply

L. C. Lin, H. F. Meng, J. T. Shy, S. F. Horng, L. S. Yu, C. H. Chen, H. H. Liaw, C. C. Huang, K. Y. Peng, and S. A. Chen
Phys. Rev. Lett. 91, 219703 (2003)

Comment on “Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes”

A. S. Dhoot and N. C. Greenham
Phys. Rev. Lett. 91, 219702 (2003)

Comment on “Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes”

R. Österbacka
Phys. Rev. Lett. 91, 219701 (2003)

Lin et al. Reply:

L. C. Lin, H. F. Meng, J. T. Shy, S. F. Horng, L. S. Yu, C. H. Chen, H. H. Liaw, C. C. Huang, K. Y. Peng, and S. A. Chen
Phys. Rev. Lett. 92, 059702 (2004)

Comment on “Triplet-to-Singlet Exciton Formation in poly(p-phenylene-vinylene) Light-Emitting Diodes”

M. Schott
Phys. Rev. Lett. 92, 059701 (2004)

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Vol. 90, Iss. 3 — 24 January 2003

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