Abstract
We study ionic transport in nano- and microcrystalline composites using standard impedance spectroscopy. In the nanocrystalline samples (average grain size of about 20 nm), the ionic conductivity increases with increasing content of up to a maximum at . Above , vanishes. By contrast, in the microcrystalline samples (grain size about ), decreases monotonically with and vanishes above . We can explain this strikingly different behavior by a percolation model that assumes an enhanced conductivity at the interfaces between insulating and conducting phases in both materials and explicitly takes into account the different grain sizes.
- Received 16 August 1999
DOI:https://doi.org/10.1103/PhysRevLett.84.2889
©2000 American Physical Society