Size and temporal dependence of the average kinetic-energy release during the evaporation of sputtered Cs(CsI)n+ clusters

Hyun Jin Hwang, Dilip K. Sensharma, and Mostafa A. El-Sayed
Phys. Rev. Lett. 64, 808 – Published 12 February 1990
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Abstract

The average kinetic-energy release is measured for the evaporation of CsI and (CsI)2 molecules from sputtered Cs(CsI)n+ clusters (n=2–17) in two different time windows. Size and temporal (temperature) dependence of the average kinetic-energy release (KER) is found to be in reasonable agreement with the predictions of the evaporative ensemble model, except for evaporation processes involving the cluster with magic number n=13. Agreement can be obtained for the latter if the assumption of the independence of the heat of evaporation on the cluster size in the model is removed.

  • Received 5 June 1989

DOI:https://doi.org/10.1103/PhysRevLett.64.808

©1990 American Physical Society

Authors & Affiliations

Hyun Jin Hwang, Dilip K. Sensharma, and Mostafa A. El-Sayed

  • Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90024-1569

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Vol. 64, Iss. 7 — 12 February 1990

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