Improved quantum hard-sphere ground-state equations of state

M. A. Solís, M. de Llano, J. W. Clark, and George A. Baker, Jr.
Phys. Rev. E 76, 031125 – Published 20 September 2007

Abstract

The London ground-state energy formula as a function of number density for a system of identical boson hard spheres, corrected for the reduced mass of a pair of particles in a “sphere-of-influence” picture, and generalized to fermion hard-sphere systems with two and four intrinsic degrees of freedom, has a double-pole at the ultimate regular (or periodic, e.g., face-centered-cubic) close-packing density usually associated with a crystalline branch. Improved fluid branches are constructed based upon exact, field-theoretic perturbation-theory low-density expansions for many-boson and many-fermion systems, extrapolated to intermediate densities via Padé and other approximants, but whose ultimate density is irregular or random closest close-packing as suggested in studies of a classical system of hard spheres. Results show substantially improved agreement with the best available Green-function Monte Carlo and diffusion Monte Carlo simulations for bosons, as well as with ladder, variational Fermi hypernetted chain, and so-called L-expansion data for two-component fermions.

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  • Received 16 May 2007

DOI:https://doi.org/10.1103/PhysRevE.76.031125

©2007 American Physical Society

Authors & Affiliations

M. A. Solís1,2, M. de Llano3, J. W. Clark1, and George A. Baker, Jr.4

  • 1Department of Physics, Washington University, St. Louis, Missouri 63130, USA
  • 2Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000 México, D.F., Mexico
  • 3Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Apartado Postal 70-360, 04510 México, D.F., Mexico and Consortium of the Americas for Interdisciplinary Science, University of New Mexico, Albuquerque, New Mexico 87131, USA
  • 4Theoretical Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA

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Issue

Vol. 76, Iss. 3 — September 2007

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