Molecular-dynamics study of the nematic-isotropic interface

Nobuhiko Akino, Friederike Schmid, and Michael P. Allen
Phys. Rev. E 63, 041706 – Published 27 March 2001
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Abstract

We present large-scale molecular-dynamics simulations of a nematic-isotropic interface in a system of repulsive ellipsoidal molecules, focusing in particular on the capillary-wave fluctuations of the interfacial position. The interface anchors the nematic phase in a planar way, i.e., the director aligns parallel to the interface. Capillary waves in the direction parallel and perpendicular to the director are considered separately. We find that the spectrum is anisotropic, the amplitudes of capillary waves being larger in the direction perpendicular to the director. In the long-wavelength limit, however, the spectrum becomes isotropic and compares well with the predictions of a simple capillary-wave theory.

  • Received 6 November 2000

DOI:https://doi.org/10.1103/PhysRevE.63.041706

©2001 American Physical Society

Authors & Affiliations

Nobuhiko Akino1, Friederike Schmid2, and Michael P. Allen3

  • 1Max-Planck-Institut für Polymerforschung, Postfach 3148, D-55021 Mainz, Germany
  • 2Fakultät für Physik, Universität Bielefeld, Universitätsstrasse 25, D-33615 Bielefeld, Germany
  • 3H. H. Wills Physics Laboratory, University of Bristol, Royal Fort, Tyndall Avenue, Bristol BS8 1TL, United Kingdom

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Issue

Vol. 63, Iss. 4 — April 2001

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