Shear flows and segregation in the reaction A+B

M. J. Howard and G. T. Barkema
Phys. Rev. E 53, 5949 – Published 1 June 1996
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Abstract

We study theoretically and numerically the effects of the linear velocity field v=v0yx^ on the irreversible reaction A+B. Assuming homogeneous initial conditions for the two species, with equal initial densities, we demonstrate the presence of a crossover time tcv01. For tv01, the kinetics are unaffected by the shear and we retain both the effect of species segregation (for d<4) and the density decay rate Atα, where α=min(d4, 1). We calculate the amplitude A to leading order in a small density expansion for 2<~d<4, and give bounds in d=4. However, for tv01, the critical dimension for anomalous kinetics is reduced to dc=2, with the density decay rate Bt1 holding for d>~2. Bounds are calculated for the amplitude B in d=2, which depend on the velocity gradient v0 and the (equal) diffusion constants D. We also briefly consider the case of a nonlinear shear flow, where we give a more general form for the crossover time tc. Finally, we perform numerical simulations for a linear shear flow in d=2 with results in agreement with theoretical predictions.

  • Received 22 December 1995

DOI:https://doi.org/10.1103/PhysRevE.53.5949

©1996 American Physical Society

Authors & Affiliations

M. J. Howard1 and G. T. Barkema2

  • 1Department of Physics, Theoretical Physics, 1 Keble Road, Oxford OX1 3NP, United Kingdom
  • 2Institute for Advanced Study, Olden Lane, Princeton, New Jersey 08540

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Vol. 53, Iss. 6 — June 1996

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