Abstract
Mössbauer spectroscopy in magnetic external fields up to 8 T and in the temperature range 1.5–160 K, demonstrates that remains paramagnetic well below =25 K. The specific-heat anomaly, the cusp in magnetic susceptibility, and the changes in the shape of the Mössbauer spectra observed at 25 K are attributed to a structural transition. Both the bulk susceptibility and the Mössbauer data can be satisfactorily reproduced under the assumption of an inhomogeneous compressional-expansional internal distortion of the oxygen sublattice. It is suggested that a magnetic ordering of is prevented (or at least depressed) by this competitive structural transition.
- Received 20 February 1985
DOI:https://doi.org/10.1103/PhysRevB.32.257
©1985 American Physical Society