Solving the time-dependent Schrödinger equation using complex-coordinate contours

C. William McCurdy, Carrie K. Stroud, and Matthew K. Wisinski
Phys. Rev. A 43, 5980 – Published 1 June 1991
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Abstract

The complex-coordinates approach in scattering theory is extended to the time-dependent Schrödinger equation by using Simon’s exterior scaling contour, and it is shown to cause outgoing wave packets to vanish for large distances in collision problems. Numerical applications are given for one- and two-dimensional problems where the complex-coordinates method is shown to eliminate reflections of outgoing wave packets from the boundaries of the coordinate space grid used in the calculations. The extension of the exterior scaling approach to the time-dependent description of a charged particle in dc and ac electromagnetic fields is given, and numerical results on these problems are also presented.

  • Received 19 November 1990

DOI:https://doi.org/10.1103/PhysRevA.43.5980

©1991 American Physical Society

Authors & Affiliations

C. William McCurdy, Carrie K. Stroud, and Matthew K. Wisinski

  • Department of Chemistry, The Ohio State University, 120 West Eighteenth Avenue, Columbus, Ohio 43210

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Issue

Vol. 43, Iss. 11 — June 1991

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