Re-Evaluation of Some Thermodynamic Properties of Gadolinium Metal

F. J. Jelinek, B. C. Gerstein, M. Griffel, R. E. Skochdopole, and F. H. Spedding
Phys. Rev. 149, 489 – Published 16 September 1966
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Abstract

The heat capacity of Gd metal has previously been measured over the temperature range 15 to 355°K by M. Griffel et al. In this note, the γ coefficient (16×104 cal/g atom deg2 in the original work) used in calculating the electronic specific heat of Gd has been replaced by the more recent value of 22×104, cal/g atom deg2. This leads to a slightly higher calculated Debye temperature and a subsequent readjustment of the lattice-specific-heat term. In addition, an error was discovered in the evaluation of the thermodynamic functions, particularly the (ST0) term. A Simpson's-rule integration procedure was applied to the original heat-capacity data and the thermodynamic functions were re-evaluated. These changes lead to a magneticentropy calculation considerably closer to the complete spin-order entropy, RIn8, than was reported in the original work.

  • Received 16 March 1966

DOI:https://doi.org/10.1103/PhysRev.149.489

©1966 American Physical Society

Authors & Affiliations

F. J. Jelinek, B. C. Gerstein, M. Griffel*, R. E. Skochdopole, and F. H. Spedding

  • Institute for Atomic Research and Department of Physical Chemistry, Iowa State University, Ames, Iowa

  • *Present address: Department of Biochemistry University of Pennsylvania, Philadelphia, Pennsylvania.
  • Present address: Dow Chemical Company, Midland Michigan.

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Vol. 149, Iss. 2 — September 1966

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