Polymer-Induced Repulsive Forces: Exponential Scaling

O. Mondain-Monval, A. Espert, P. Omarjee, J. Bibette, F. Leal-Calderon, J. Philip, and J.-F. Joanny
Phys. Rev. Lett. 80, 1778 – Published 23 February 1998
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Abstract

The polymer-induced repulsive interactions between the surfaces of a liquid film are measured for two systems using two force measurement techniques, in the case where the polymer is in a good solvent and adsorbs at the liquid surface. The force decays exponentially with the film thickness with a decay length proportional to the radius of gyration. The data are compared with a recent theoretical work which predicts a repulsive exponentially decaying force at large thicknesses.

  • Received 22 September 1997

DOI:https://doi.org/10.1103/PhysRevLett.80.1778

©1998 American Physical Society

Authors & Affiliations

O. Mondain-Monval1,*, A. Espert1, P. Omarjee1, J. Bibette1, F. Leal-Calderon1, J. Philip2, and J.-F. Joanny3

  • 1Centre de Recherche Paul Pascal, Av. A. Schweitzer, 33600 Pessac, France
  • 2DPEND, IGCAR, Kalpakkam, 603 102 Tamil Nadu, India
  • 3Institut Charles Sadron, 6 rue Boussingault, 67000 Strasbourg, France

  • *Corresponding author.

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Vol. 80, Iss. 8 — 23 February 1998

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