Rheology of Wormlike Micelles: Two Universality Classes

Ben O'Shaughnessy and Jane Yu
Phys. Rev. Lett. 74, 4329 – Published 22 May 1995
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Abstract

We identify two classes of rheology in solutions of wormlike micellar chains which break reversibly. In “mean-field” (MF) systems, new ends created by breaks recombine with other chains and stress relaxes exponentially [M. E. Cates, Macromolecules 20, 2289 (1987)]. By contrast, in “diffusion-controlled” (DC) cases, self-recombination dominates and the relaxation process is a Lévy walk, leading to algebraic short time decay. The long time decay remains exponential, but with a different time scale. Our estimates suggest that current experimental systems include both MF and DC types.

  • Received 3 January 1995

DOI:https://doi.org/10.1103/PhysRevLett.74.4329

©1995 American Physical Society

Authors & Affiliations

Ben O'Shaughnessy1 and Jane Yu2

  • 1Department of Chemical Engineering, Materials Science and Mining Engineering, Columbia University, New York, New York 10027
  • 2Department of Physics, Columbia University, New York, New York 10027

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Vol. 74, Iss. 21 — 22 May 1995

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