Abstract
The carbon Auger line shapes obtained from three diverse gas-phase transition-metal carbonyls are analyzed. Some features in the line shape directly reflect the amount of backbonding. The analysis indicates that the dominant initial state is the adiabatically relaxed ground state. The final-state holes are either localized on the same ligand or described by a state consisting of one hole on a ligand and the other on the metal atom. The latter state may be viewed as a -backbonding—assisted interatomic decay.
- Received 12 August 1980
DOI:https://doi.org/10.1103/PhysRevLett.46.911
©1981 American Physical Society