Microscopic Mechanisms of the Brittleness of Viscoelastic Fluids

H. Tabuteau, S. Mora, G. Porte, M. Abkarian, and C. Ligoure
Phys. Rev. Lett. 102, 155501 – Published 14 April 2009
PDFHTMLExport Citation

Abstract

We show that a large class of viscoelastic fluids, i.e., transient networks, are brittle according to the Griffith’s theory of solid fracture. However, contrary to solids, cracks are intrinsic to the material arising from the equilibrium nature of the fluid microstructure. The brittleness of these fluids comes from thermal fluctuations of bonds distribution. In this approach, the rupture stress is predicted to be on the order of the Young modulus, in very good agreement with experimental values.

  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Received 27 October 2008

DOI:https://doi.org/10.1103/PhysRevLett.102.155501

©2009 American Physical Society

Authors & Affiliations

H. Tabuteau, S. Mora*, G. Porte, M. Abkarian, and C. Ligoure

  • Laboratoire des Colloïdes, Verres et Nanomatériaux, UMR 5587, Université Montpellier 2 and CNRS, Place Eugène Bataillon, F-34095 Montpellier Cedex, France

  • *smora@univ-montp2.fr

Article Text (Subscription Required)

Click to Expand

Supplemental Material (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 102, Iss. 15 — 17 April 2009

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review Letters

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×