Dynamics of A+BC Reaction Fronts in the Presence of Buoyancy-Driven Convection

L. Rongy, P. M. J. Trevelyan, and A. De Wit
Phys. Rev. Lett. 101, 084503 – Published 22 August 2008

Abstract

The dynamics of A+BC fronts in horizontal solution layers can be influenced by buoyancy-driven convection as soon as the densities of A, B, and C are not all identical. Such convective motions can lead to front propagation even in the case of equal diffusion coefficients and initial concentration of reactants for which reaction-diffusion (RD) scalings predict a nonmoving front. We show theoretically that the dynamics in the presence of convection can in that case be predicted solely on the basis of the knowledge of the one-dimensional RD density profile across the front.

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  • Received 27 March 2008

DOI:https://doi.org/10.1103/PhysRevLett.101.084503

©2008 American Physical Society

Authors & Affiliations

L. Rongy, P. M. J. Trevelyan, and A. De Wit

  • Nonlinear Physical Chemistry Unit, CP 231, Faculté des Sciences, Université Libre de Bruxelles (ULB), 1050 Brussels, Belgium

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Vol. 101, Iss. 8 — 22 August 2008

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