Conductivity measurements in a shear-banding wormlike micellar system

Panos J. Photinos, M. R. López-González, Corey V. Hoven, and Paul T. Callaghan
Phys. Rev. E 82, 011502 – Published 9 July 2010

Abstract

Shear banding in the cetylpyridinium chloride/sodium salicylate micellar system is investigated using electrical conductivity measurements parallel to the velocity and parallel to the vorticity in a cylindrical Couette cell. The measurements show that the conductivity parallel to the velocity (vorticity) increases (decreases) monotonically with applied shear rate. The shear-induced anisotropy is over one order of magnitude lower than the anisotropy of the Nc nematic phase. The steady-state conductivity measurements indicate that the anisotropy of the shear induced low-viscosity (high shear rate) phase is not significantly larger than the anisotropy of the high viscosity (low shear rate) phase. We estimate that the micelles in the shear induced low viscosity band are relatively short, with a characteristic length to diameter ratio of 5–15. The relaxation behavior following the onset of shear is markedly different above and below the first critical value γ̇1, in agreement with results obtained by other methods. The transient measurements show that the overall anisotropy of the sample decreases as the steady state is approached, i.e., the micellar length/the degree of order decrease.

  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Figure
  • Received 11 February 2010

DOI:https://doi.org/10.1103/PhysRevE.82.011502

©2010 American Physical Society

Authors & Affiliations

Panos J. Photinos1, M. R. López-González2,*, Corey V. Hoven1,†, and Paul T. Callaghan2

  • 1Department of Physics, Southern Oregon University, Ashland, Oregon 97520, USA
  • 2MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, Wellington, New Zealand

  • *Present address: Department of Clinical Physics, Faculty of Medicine, University of Glasgow, Scotland, UK.
  • Present address: Department of Materials, University of California, Santa Barbara, California 93106.

Article Text (Subscription Required)

Click to Expand

References (Subscription Required)

Click to Expand
Issue

Vol. 82, Iss. 1 — July 2010

Reuse & Permissions
Access Options
Author publication services for translation and copyediting assistance advertisement

Authorization Required


×
×

Images

×

Sign up to receive regular email alerts from Physical Review E

Log In

Cancel
×

Search


Article Lookup

Paste a citation or DOI

Enter a citation
×