Abstract
For nonassociated, glass-forming liquids and polymers, thermodynamic scaling of structural relaxation times and viscosities is an empirical fact, demonstrated by various groups for dozens of materials. The and invariance of the isochoric fragility follows directly from this scaling. Apparent inconsistencies with these statements were reported recently by Grzybowski et al. [A. Grzybowski, K. Grzybowska, J. Zioło, and M. Paluch, Phys. Rev. E 74, 041503 (2006)]; however, the putative inconsistencies arise from use at higher pressures of parameters to correlate the isobaric and isochoric fragilities that are valid only for ambient pressure.
- Received 31 October 2006
DOI:https://doi.org/10.1103/PhysRevE.76.013501
©2007 American Physical Society