Simple model of capillary condensation in porous media

S. M. Gatica, M. M. Calbi, and M. W. Cole
Phys. Rev. E 65, 061605 – Published 21 June 2002
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Abstract

We employ a simple model to describe the phase behavior of 4He and Ar in a hypothetical porous material consisting of a regular array of infinitely long, solid, parallel cylinders. We find that high porosity geometries exhibit two transitions: from vapor to film and from film to capillary condensed liquid. At low porosity, the film is replaced by a “necking” configuration, and for a range of intermediate porosity there are three transitions: from vapor to film, from film to necking and from necking to a capillary condensed phase.

  • Received 21 February 2002

DOI:https://doi.org/10.1103/PhysRevE.65.061605

©2002 American Physical Society

Authors & Affiliations

S. M. Gatica1, M. M. Calbi2, and M. W. Cole2

  • 1Departamento de Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, 1428 Buenos Aires, Argentina
  • 2Department of Physics, The Pennsylvania State University, University Park, Pennsylvania 16802

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Vol. 65, Iss. 6 — June 2002

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