Abstract
We studied the crystal and magnetic structure of the compound for using stoichiometric samples. For the system’s ground state is insulating canted antiferromagnetic. For below the Jahn-Teller transition temperature the crystal structure undergoes a monoclinic distortion. The crystal structure can be described with space group which permits two Mn sites. The unit-cell strain parameter increases for , taking the maximum value at the Curie point, and then decreases. Below abruptly changes slope and finally approaches with nearly zero slope. The change of at is connected to a characteristic feature in the magnetic measurements. As increases towards the ferromagnetic metallic boundary, although is reduced appreciably, the monoclinic structure is preserved. The monoclinic structure is discussed with relation to the orbital ordering, which can produce the ferromagnetic insulating ground state. We also studied samples that were prepared in air atmosphere. This category of samples shows ferromagnetic insulating behavior without following the particular variation of the parameter. The crystal structure of these samples is related to the so-called structure.
- Received 14 September 2004
DOI:https://doi.org/10.1103/PhysRevB.72.064425
©2005 American Physical Society