Role of hydrogen and lithium impurities in radiation damage in neutron-irradiated MgO single crystals

R. González, I. Vergara, D. Cáceres, and Y. Chen
Phys. Rev. B 65, 224108 – Published 6 June 2002
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Abstract

Radiation damage induced by neutron irradiation was studied by optical absorption measurements in undoped MgO crystals and in MgO crystals intentionally doped with either hydrogen or lithium impurities. The oxygen-vacancy concentration incurred by the neutron irradiation increases with neutron dose. Suppression of radiation damage as characterized by oxygen vacancies is observed in MgO:H crystals and attributed to migration of oxygen vacancies to microcavities filled with hydrogen gas. In MgO:Li crystals irradiated with neutron doses below 1018 neutrons/cm2, most of the oxygen vacancies are camouflaged as hydride ions formed by the capture of protons by the oxygen vacancies. Substitutional lithium ions are also displaced. We postulate that they aggregate at Li2O precipitates. Thermal annealing experiments demonstrate that protons are mobile at 700 K and lithium ions at 1100 K.

  • Received 29 January 2002

DOI:https://doi.org/10.1103/PhysRevB.65.224108

©2002 American Physical Society

Authors & Affiliations

R. González, I. Vergara, and D. Cáceres

  • Departamento de Física, Escuela Politécnica Superior, Universidad Carlos III, Avda. de la Universidad, 30, 28911 Leganés, (Madrid), Spain

Y. Chen

  • Division of Materials Sciences, Office of Basic Energy Sciences, SC 13, The U.S. Department of Energy, Germantown, Maryland 20874-1290

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Vol. 65, Iss. 22 — 1 June 2002

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