Dynamical local-field factors and effective interactions in the three-dimensional electron liquid

C. F. Richardson and N. W. Ashcroft
Phys. Rev. B 50, 8170 – Published 15 September 1994
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Abstract

We present a study of the local-field factors for the homogeneous, isotropic, three-dimensional interacting electron liquid as a function of momentum, imaginary frequency (iw), and density (rs). A variational approach is used to solve integral equations for the density-density and spin-spin response functions, and it provides approximations to the local-field factors which are exact in the high-density limit. We derive sum rules which show that for large iw, the local-field factors possess maxima (in both q and iw) whose magnitudes are related to the pair-distribution function evaluated at zero separation. We introduce a parametrization scheme which incorporates these sum rules with the known compressibility, susceptibility, and third-moment sum rules. The local-field factors are then used to calculate the effective electron-electron interaction using the Vignale-Singwi formalism [Phys. Rev. B 32, 2156 (1985)]. It is found to be significantly larger than that predicted by Hubbard-type local-field factors for small to intermediate values of the wave vector and imaginary frequency.

  • Received 22 February 1994

DOI:https://doi.org/10.1103/PhysRevB.50.8170

©1994 American Physical Society

Authors & Affiliations

C. F. Richardson and N. W. Ashcroft

  • Laboratory of Atomic and Solid State Physics and Materials Science Center, Cornell University, Ithaca, New York 14853-2501

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Issue

Vol. 50, Iss. 12 — 15 September 1994

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