In a search for high-magnetostrictive materials we have discovered in FeRh a large induced volume magnetostriction (≊0.82%) at and above room temperature. Thermal-expansion measurements performed on the ordered CsCl crystallographic structure of FeRh in the temperature range 250–800 K reveal Invar-like behavior at ${\mathit{T}}_{\mathit{c}}$=680 K associated with a paramagnetic-ferromagnetic second-order phase transition. At ${\mathit{T}}_{\mathrm{F}\mathrm{-}\mathrm{AF}}$=405 K, a large contraction of the lattice within the ferromagnetic (F) phase takes place through a first-order transformation resulting in a low-volume, low-temperature antiferromagnetic phase (AF) (anti-invar-like behavior). At moderate fields above room temperature and within the AF phase, we have found a giant value for the volume magnetostriction of ω=8.2×${10}^{\mathrm{-}3}$. These results constitute evidence for the existence of the theoretically predicted metastable F phase (high-volume state) within the AF phase which can be reached by an applied magnetic field. The present experiments offer additional perspectives on an old problem in magnetism and suggest potential applications of this alloy as a high-magnetostrictive material.

• Received 8 March 1994

DOI:https://doi.org/10.1103/PhysRevB.50.4196