The two-photon decay mode of hydrogenic atoms from an arbitrary state ($n_1$, $l_1$, $m_1$) to an arbitrary state ($n_2$, $l_2$, $m_2$) is studied within the framework of nonrelativistic quantum mechanics. In the dipole approximation, these decay rates, which involve infinite summation over intermediate states, are derived exactly via a general second-order matrix element obtained by Kelsey and Macek and an implicit technique introduced by Dalgarno and Lewis. The results are expressed in terms of hypergeometric functions. For transitions $n_{1}s\to n_{2}s$, our results reduce to those of Klarsfeld whose starting point is the Coulomb Green's function. For transitions to the ground state, an alternative expression involving a simple one-dimensional integral is presented. The decay rate of the $2s$ metastable state of atomic hydrogen is calculated as an illustration of the method. The result, $\frac{1}{\tau }=8.2284\mathrm{}$ ${\sec }^{-1\mathrm{}}$, agrees with Klarsfeld. For transitions of $n_{1}s\to 1s$ and $n_{1}d\to 1s (n_1\ge 3)$, the transition rates exhibit interesting and unexpected structures. In particular, "zeros" are found in the two-photon emission spectrum indicating that two-photon emission is not possible at certain frequencies. Physically, these "zeros" are the result of destructive interference between the radiating dipole terms associated with the sum over intermediate states. In addition to the emission spectrum the expected coincidence signal between two detectors monitoring the two photons simultaneously emitted during a two-photon transition is calculated as a function of the angle between the detectors. The angular distribution for the $n_{1}d\to 1s$ transitions is shown to be significantly different from the $n_{1}s\to 1s$ transitions. Finally, a possible experiment is suggested to test the results presented in this paper.

• Received 9 December 1982

DOI:https://doi.org/10.1103/PhysRevA.30.1175