Abstract
"Anomalous" Mössbauer spectra characterized by the simultaneous presence of a pronouned central peak indicative of the paramagnetic state, and hyperfine structure characteristic of the ordered state, have been obtained in magnetically ordered compounds of iron close to their disordering temperature . We adduce evidence supporting the hypothesis that the spectra found near are the result of collective spin flips of small regions (volume ) of the material, corresponding to the onset of superparamagnetic effects as the temperature approaches from below. A good fit is obtained between experimental spectra of Fe, and the spectral shape computed using reasonable distributions of and . The measured effect of an applied magnetic field upon the spectra near is explained in terms of our model of "critical superparamagnetism." Finally, the relevance of our results to general measurements of critical phenomena is discussed.
- Received 16 July 1968
DOI:https://doi.org/10.1103/PhysRev.177.864
©1969 American Physical Society