It is usually assumed that optically created carriers in a photoconductor rapidly thermalize to a Boltzmann distribution, regardless of the generation and recombination mechanisms. However, it can be shown that this distribution which is characteristic of thermodynamic equilibrium is incompatible with the requirements of steady state. A variational principle is introduced to find the steady-state distribution, which is found to approach the Maxwell-Boltzmann function in the limit of strong thermal scattering. Interband scattering is found to be potentially a strong thermalizing influence, in addition to the intraband scattering usually considered. For a simple model semiconductor, significant deviations from the Boltzmann distribution are found to be possible at temperatures below a few degrees Kelvin. This result is then discussed in connection with certain experiments on germanium.

• Received 15 April 1960

DOI:https://doi.org/10.1103/PhysRev.120.52