Based on first-principles calculations, we have investigated the magnetic properties of the first-row element-doped ZnS semiconductors. Calculations reveal that Be, B, and C dopants can induce magnetism while N cannot lead to spin polarization in ZnS. A possible explanation has been rationalized from the elements’ electronegativity and interaction between dopant and host atoms. The total magnetic moments are 2.00, 3.16, and $2.38{\mu }_{\text{B}}$ per $2\times 2\times 2$ supercell for Be, B, and C doping, respectively, and ferromagnetic coupling is generally observed in these cases. The ferromagnetism of Be-, B-, and C-doped ZnS can be explained by hole-mediated $s\text{−}p$ or $p\text{−}p$ interactions’ coupling mechanisms. The clustering effect was found to be present in Be-, B-, and C-doped ZnS but the degree is more obvious in the former two cases than in the latter case. Analysis revealed that C-doped ZnS displays better potential ferromagnetic behavior than Be- and B-doped ZnS due to its semimetallic characteristics.

• Received 21 May 2009

DOI:https://doi.org/10.1103/PhysRevB.80.115212