Abstract
Infrared reflectivity spectra were measured for a polycrystalline Mn sample. The internal phonon modes, i.e., the bending and stretching modes, of the Mn octahedra show significant frequency shifts near the Curie temperature . The frequency shifts of the internal phonon modes were found to have a linear relationship with the excess lattice expansion above , which deviates from a prediction of the Grüneisen law. A strong electron-phonon coupling and a crossover from small to large polaronic states are attributed to the observed frequency shifts.
- Received 14 December 1995
DOI:https://doi.org/10.1103/PhysRevLett.77.1877
©1996 American Physical Society