Abstract
It is shown that , the partial molal entropy of electrons in material , is given by , where is Faraday's constant and the absolute thermoelectric power of . This result depends on three propositions. (1) The Kelvin relations are valid for all thermoelectric materials. (2) Under isothermal conditions, the Peltier effect is truly reversible. (3) For a degenerate free-electron Fermi gas, the thermoelectric power is proportional to the entropy.
- Received 2 July 1984
DOI:https://doi.org/10.1103/PhysRevA.30.2843
©1984 American Physical Society