Neutron diffraction study of RFe10V2Cx prepared by arc melting

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Published under licence by IOP Publishing Ltd
, , Citation Chin Lin et al 1995 J. Phys.: Condens. Matter 7 7293 DOI 10.1088/0953-8984/7/36/018

0953-8984/7/36/7293

Abstract

Samples of RFe10V2Cx with R=Y, Gd, Dy or Er were prepared by arc melting. X-ray diffraction and thermomagnetic analyses showed that interstitial carbides with the ThMn12 structure can be formed only for a small amount of C (x<or=0.3). The effects of C addition on lattice expansion and Curie temperature are much smaller in the carbides prepared by arc melting than in those prepared by gas-solid reaction. Neutron diffraction shows that the C atoms occupy the interstitial site in the structure.

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10.1088/0953-8984/7/36/018