Transition state theory for ballistic electrons

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, , Citation B Eckhardt 1995 J. Phys. A: Math. Gen. 28 3469 DOI 10.1088/0305-4470/28/12/019

0305-4470/28/12/3469

Abstract

Transition state theory as developed for chemical reactions is transferred to ballistic electrons. The phase-space flux through the transition state is related to the conductance. Steps in the conductance follow from a semiclassical extension of this formula. Tunnelling corrections have to be included to yield the rounding of the steps. A magnetic field causes a sharpening of the steps and at finite temperature an additional broadening. The calculation also shed some light on the abilities and limitations of the semiclassical approach.

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10.1088/0305-4470/28/12/019