We present a pressure-induced amorphization for pure and 0.5 mol. % Bi3+-doped Zn2GeO4 samples, measured by high pressure Raman spectroscopy and high resolution transmission electron microscopy. Pressure-induced conductivity switching phenomena were discovered for both samples at around ∼7.01 GPa and ∼11.11 GPa, respectively, which closely correlated with the crystalline-to-amorphous transformation. The detailed conduction mechanism and the defect reaction process at high pressure indicate that the application of pressure could efficiently manipulate the microstructure and electrical performance of rare-earth doped polycrystalline materials, and therefore holds great promise for numerous applications in the future.
References
1.
X.
Lü
, Q.
Hu
, W.
Yang
, L.
Bai
, H.
Sheng
, L.
Wang
, F.
Huang
, J.
Wen
, D. J.
Miller
, and Y.
Zhao
, J. Am. Chem. Soc.
135
, 13947
(2013
).2.
O.
Mishima
, L.
Calvert
, and E.
Whalley
, Nature
310
, 393
(1984
).3.
S. K.
Deb
, M.
Wilding
, M.
Somayazulu
, and P. F.
McMillan
, Nature
414
, 528
(2001
).4.
C.
Perottoni
and J.
Da Jornada
, Science
280
, 886
(1998
).5.
S. M.
Sharma
and S.
Sikka
, Prog. Mater. Sci.
40
, 1
(1996
).6.
L.
Lu
, J.
Chen
, and W.
Wang
, Appl. Phys. Lett.
103
, 123902
(2013
).7.
G.
Gao
and L.
Wondraczek
, J. Mater. Chem. C.
1
, 1952
(2013
).8.
L.
Sun
, Y.
Qi
, C.-J.
Jia
, Z.
Jin
, and W.
Fan
, Nanoscale
6
, 2649
(2014
).9.
L.
Pei
, Y.
Yang
, L.
Yang
, C.
Fan
, C.
Yuan
, and Q.-F.
Zhang
, Solid State Commun.
151
, 1036
(2011
).10.
F.
Bai
, Z.
Sun
, H.
Wu
, R. E.
Haddad
, E. N.
Coker
, J. Y.
Huang
, M. A.
Rodriguez
, and H.
Fan
, Nano Lett.
11
, 5196
(2011
).11.
F.
Bai
, H.
Wu
, R. E.
Haddad
, Z.
Sun
, S. K.
Schmitt
, V. R.
Skocypec
, and H.
Fan
, Chem. Commun.
46
, 4941
(2010
).12.
Y.
Tian
, T.
Busani
, G. H.
Uyeda
, K. E.
Martin
, F.
van Swol
, C. J.
Medforth
, G. A.
Montaño
, and J. A.
Shelnutt
, Chem. Commun.
48
, 4863
(2012
).13.
N. A.
Rakow
and K. S.
Suslick
, Nature
406
, 710
(2000
).14.
Z.
Quan
, Y.
Wang
, I.-T.
Bae
, W. S.
Loc
, C.
Wang
, Z.
Wang
, and J.
Fang
, Nano Lett.
11
, 5531
(2011
).15.
Z.
Quan
, Z.
Luo
, Y.
Wang
, H.
Xu
, C.
Wang
, Z.
Wang
, and J.
Fang
, Nano Lett.
13
, 3729
(2013
).16.
F.
Bai
, B.
Li
, K.
Bian
, R.
Haddad
, H.
Wu
, Z.
Wang
, and H.
Fan
, Adv. Mater.
28
, 1989
(2016
).17.
I Materials Data, JADE,
2015
.18.
H.
Mao
, J.
Xu
, and P.
Bell
, J. Geophys. Res.
91
, 4673
, doi: (1986
).19.
D.
Errandonea
, Y.
Meng
, M.
Somayazulu
, and D.
Häusermann
, Physica B: Condens. Matter
355
, 116
(2005
).20.
S.
Klotz
, J. C.
Chervin
, P.
Munsch
, and G.
Le Marchand
, J. Phys. D: Appl. Phys.
42
, 075413
(2009
).21.
M.
Li
, C.
Gao
, Y.
Ma
, Y.
Li
, X.
Li
, H.
Li
, J.
Liu
, A.
Hao
, C.
He
, and X.
Huang
, Rev. Sci. Instrum.
77
, 123902
(2006
).22.
L.
Dai
, H.
Li
, H.
Hu
, and S.
Shan
, J. Geophys. Res.
113
, B12
(2008
).23.
H.
Hu
, L.
Dai
, H.
Li
, K.
Hui
, and J.
Li
, Solid State Ionics
276
, 136
(2015
).24.
L.
Wu
, Y.
Sun
, G.-Z.
Zhang
, and C.-X.
Gao
, Mater. Lett.
129
, 68
(2014
).25.
L.
Wu
, L.
Dai
, H.
Li
, Y.-K.
Zhuang
, and K.
Liu
, J. Phys. D: Appl. Phys.
49
, 345102
(2016
).26.
L.
Dai
, L.
Wu
, H.
Li
, H.
Hu
, Y.
Zhuang
, and K.
Liu
, EPL
114
, 56003
(2016
).27.
J.
Sato
, H.
Kobayashi
, K.
Ikarashi
, N.
Saito
, H.
Nishiyama
, and Y.
Inoue
, J. Phys. Chem. B
108
, 4369
(2004
).28.
Z.
Liu
, X.
Jing
, and L.
Wang
, J. Electrochem. Soc.
154
, H500
(2007
).29.
V. B. R.
Boppana
, N. D.
Hould
, and R. F.
Lobo
, J. Solid State Chem.
184
, 1054
(2011
).30.
Y.
Zhao
, S.
Yang
, J.
Zhu
, G.
Ji
, and F.
Peng
, Solid State Ionics
274
, 12
(2015
).31.
32.
M.
Kruger
and R.
Jeanloz
, Science
249
, 647
(1990
).33.
S.
Yang
, F.
Peng
, W.
Li
, Q.
Hu
, X.
Yan
, L.
Lei
, X.
Li
, and D.
He
, Chin. Phys. B
25
, 076101
(2016
).34.
J.
Tse
, D.
Klug
, C.
Tulk
, I.
Swainson
, E.
Svensson
, C.-K.
Loong
, V.
Shpakov
, V.
Belosludov
, R.
Belosludov
, and Y.
Kawazoe
, Nature
400
, 647
(1999
).35.
R.
Hemley
, A.
Jephcoat
, H.
Mao
, L.
Ming
, and M.
Manghnani
, Nature
334
, 52
(1988
).36.
Q.
Williams
and R.
Jeanloz
, Nature
338
, 413
(1989
).37.
S.
Zhang
, Y.
Hu
, R.
Chen
, X.
Wang
, and Z.
Wang
, Opt. Mater.
36
, 1830
(2014
).38.
C.
Wu
, W.
Wu
, Y.
Gong
, B.
Dai
, S.
He
, and Y.
Huang
, Acta. Phys. Sin.
64
, 114213
(2015
).39.
M.
Shirpour
, R.
Merkle
, C.
Lin
, and J.
Maier
, Phys. Chem. Chem. Phys.
14
, 730
(2012
).40.
B. D.
Huey
and D. A.
Bonnell
, Solid State Ionics
131
, 51
(2000
).41.
M.
Shirpour
, B.
Rahmati
, W.
Sigle
, P. A.
van Aken
, R.
Merkle
, and J.
Maier
, J. Phys. Chem. C
116
, 2453
(2012
).42.
J.
Fleig
, S.
Rodewald
, and J.
Maier
, J. Appl. Phys.
87
, 2372
(2000
).43.
Y.
Ma
, M.
Eremets
, A. R.
Oganov
, Y.
Xie
, I.
Trojan
, S.
Medvedev
, A. O.
Lyakhov
, M.
Valle
, and V.
Prakapenka
, Nature
458
, 182
(2009
).44.
K.
Arai
, K.
Kumata
, K.
Kadota
, K.
Yamamoto
, H.
Namikawa
, and S.
Saito
, J. Non-Cryst. Solids
13
, 131
(1973
).45.
W. A.
Henderson
and S.
Passerini
, Electrochem. Commun.
5
, 575
(2003
).46.
J.-M.
Le Meins
, O.
Bohnke
, and G.
Courbion
, Solid State Ionics
111
, 67
(1998
).47.
M.
Tatsumisago
and A.
Hayashi
, Solid State Ionics
225
, 342
(2012
).48.
D.
Umeyama
, S.
Horike
, C.
Tassel
, H.
Kageyama
, Y.
Higo
, K.
Hagi
, N.
Ogiwara
, and S.
Kitagawa
, APL Mater.
2
, 124401
(2014
).49.
E.
Davis
and N.
Mott
, Philos. Mag.
22
, 0903
(1970
).50.
M.
Mott
, H.
Fritzsche
, and S.
Ovshinsky
, Phys. Rev. Lett.
22
, 1065
(1969
).© 2017 Author(s).
2017
Author(s)
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