1+1 LIF Doppler profile functions of photofragments in the presence of v–J correlation are derived in a formalism of density matrix. Radon transforms which are imposed by the resonance condition of Doppler spectroscopy have been implemented exactly. Independent parameters which characterize the angular momentum polarizations of photofragments in a specific state on an expanding Newton sphere have been examined carefully to compare the present treatment with the bipolar moment formalism of Dixon [R. N. Dixon, J. Chem. Phys. 85, 1866 (1986)]. To extract information on speed distributions of photofragments from a combined, isotropic Doppler profile, the proper procedure to take the linear combination of experimental profiles from various detection geometries and rotational branches of transitions has been presented. For future analyses of Doppler spectroscopic measurements of photofragmentation processes, it is recommended that the Doppler profile function in the present framework should be utilized.
Skip Nav Destination
Article navigation
15 April 1999
Research Article|
April 15 1999
Laser induced fluorescence Doppler profiles of photofragments in the presence of v–J correlation: A density matrix formalism
Kuo-mei Chen;
Kuo-mei Chen
Department of Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan, Republic of China
Search for other works by this author on:
Cheng-chih Pei
Cheng-chih Pei
Institute of Nuclear Energy Research, Lung Tan, Taiwan, Republic of China
Search for other works by this author on:
J. Chem. Phys. 110, 7256–7263 (1999)
Article history
Received:
July 21 1998
Accepted:
January 22 1999
Citation
Kuo-mei Chen, Cheng-chih Pei; Laser induced fluorescence Doppler profiles of photofragments in the presence of v–J correlation: A density matrix formalism. J. Chem. Phys. 15 April 1999; 110 (15): 7256–7263. https://doi.org/10.1063/1.478669
Download citation file:
Sign in
Don't already have an account? Register
Sign In
You could not be signed in. Please check your credentials and make sure you have an active account and try again.
Sign in via your Institution
Sign in via your InstitutionPay-Per-View Access
$40.00
Citing articles via
CREST—A program for the exploration of low-energy molecular chemical space
Philipp Pracht, Stefan Grimme, et al.
GPAW: An open Python package for electronic structure calculations
Jens Jørgen Mortensen, Ask Hjorth Larsen, et al.
DeePMD-kit v2: A software package for deep potential models
Jinzhe Zeng, Duo Zhang, et al.