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Synlett 1994; 1994(8): 607-608
DOI: 10.1055/s-1994-22943
DOI: 10.1055/s-1994-22943
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New Access to Conjugated Dien- and Enamides. Synthesis of Dehydropipernonaline, Pipernonaline and Related Biologically Active Amides
Further Information
Publication History
Publication Date:
18 September 2002 (online)
A new method for the synthesis of conjugated dien- and enamides by palladium-catalyzed coupling reaction of (E)-ß-bromoacrylamides with alkenyl- and alkylboronates is reported. This procedure provided some biologically active, naturally occurring unsaturated amides, such as dehydropipernonaline, pipernonaline and other related alkaloids, in one-pot.