SCHEDULED MAINTENANCE
Stable crystalline tricarbonyl(indan-2-one)chromium(0)1 has been synthesised from relatively unstable indan-2-one by ketone protection, chromium complexation and ketone deprotection; addition of non-basic nucleophiles to the ketone of 1 and deprotonation/alkylation procedures proceed efficiently and stereoselectively to give good yields of diastereoisomerically pure products.
E. L. M. Cowton, S. E. Gibson (<em xmlns="http://www.rsc.org/schema/rscart38">née</em> Thomas), M. J. Schneider and M. H. Smith, J. Chem. Soc., Perkin Trans. 1, 1995, 2077 DOI: 10.1039/P19950002077
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