Issue 2, 1994
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Iron(III)chloride oxidation of tricarbonyl(vinylketene)iron(0)-alkyne adducts

Stephen P. Saberi,   Matthew M. Salter,   Alexandra M. Z. Slawin,   Susan E. Thomas  and  David J. Williams  

Abstract

Oxidation of the adducts formed from tricarbonyl(vinylketene)iron(0) complexes and alkynes by iron(III) chloride in methanol/water leads to the replacement of the tricarbonyliron(0) unit with an oxygen atom derived from the water. This pathway to furan-3(2H)-ones requires the presence of an electron-withdrawing substituent on carbon-2 of the vinylketene–alkyne adduct. Data used to assign the structures of some of the vinylketene–alkyne adducts used in this study included an X-ray crystal structure analysis of the unusual lactone complex 5c.

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Article information

DOI
https://doi.org/10.1039/P19940000167
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1994, 167-171

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Iron(III)chloride oxidation of tricarbonyl(vinylketene)iron(0)-alkyne adducts

S. P. Saberi, M. M. Salter, A. M. Z. Slawin, S. E. Thomas and D. J. Williams, J. Chem. Soc., Perkin Trans. 1, 1994, 167 DOI: 10.1039/P19940000167

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