Issue 0, 1983

Photochemical cyclisation of 3-N-(dialkylaminomethyl)imidazole-2,4-diones to 1,3,7-triazabicyclo[3.3.0]octanes

Abstract

Ultraviolet irradiation of N-3 Mannich bases derived from hydantoin or from 5,5-disubstituted hydantoins (imidazole-2,4-diones), provides an efficient route to 1,3,7-triazabicyclo[3.3.0]octane derivatives by photocyclisation to the C-4 carbonyl group.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1983, 531-533

Photochemical cyclisation of 3-N-(dialkylaminomethyl)imidazole-2,4-diones to 1,3,7-triazabicyclo[3.3.0]octanes

J. D. Coyle and L. R. B. Bryant, J. Chem. Soc., Perkin Trans. 1, 1983, 531 DOI: 10.1039/P19830000531

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