Issue 0, 1982
From the journal:

Journal of the Chemical Society, Perkin Transactions 1

Reactions of organothallium compounds with diborane

Geoffrey M. Pickles,   Terence Spencer,   F. Gordon Thorpe,   Alicia D. Ayala  and  Julio C. Podestá  

Abstract

A number of organothallium(III) compounds of the type ArnTIX3-n have been treated with diborane in tetrahydrofuran. For X = OCOCF3 and n= 1 a transmetallation occurs to give organoboron intermediates which, on hydrolysis or oxidation, give arylboronic acids or phenols, respectively, in yields of ca. 70% Reasonable yields are also obtained when X = Cl or OCOCH3 and n= 2, but little or no transmetallation occurs when X = Cl or CN and n= 1.

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Article information

DOI
https://doi.org/10.1039/P19820002949
Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1982, 2949-2951

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Reactions of organothallium compounds with diborane

G. M. Pickles, T. Spencer, F. G. Thorpe, A. D. Ayala and J. C. Podestá, J. Chem. Soc., Perkin Trans. 1, 1982, 2949 DOI: 10.1039/P19820002949

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