Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Some benzoylazo-complexes of rhenium halides with tertiary phosphines, and related compounds

J. Chatt,   J. R. Dilworth,   G. J. Leigh  and  V. D. Gupta  

Abstract

Oxotrichlorobis(triphenylphosphine)rhenium(V) reacts with monobenzoylhydrazine and dibenzoylhydrazine in benzene–ethanol in the presence of hydrochloric acid to give [N-benzoylhydrazido(3-)-O,N′]dichlorobis(triphenylphosphine)rhenium(V). The chelate ring is opened by a number of nucleophiles to give rhenium(III) benzoylazo-complexes. Certain tertiary and ditertiary phosphines react further in alcoholic solvents to yield rhenium(I) dinitrogen complexes. In the presence of a ketone [ReOCl3(PPh3)2] reacts with monobenzoylhydrazine to give a chelate complex derived from the ketone hydrazone.

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Article information

DOI
https://doi.org/10.1039/J19710002631
Article type
Paper

J. Chem. Soc. A, 1971, 2631-2639

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Some benzoylazo-complexes of rhenium halides with tertiary phosphines, and related compounds

J. Chatt, J. R. Dilworth, G. J. Leigh and V. D. Gupta, J. Chem. Soc. A, 1971, 2631 DOI: 10.1039/J19710002631

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